Thanks, Oscar. However, this problem would seem to pale in comparison to CO2 
acidification with an ocean input of about 8 GT (vs the stated MTs of SOX and 
NOx).  Also, probably dwarfed by SOx and NOx from land based generation. 
Speaking of seawater scrubbing, this is also commonly done at power plants (esp 
Asia) - good for air but very efficiently acidifies the ocean.  Solution - 
place limestone downstream of the gas/seawater contacting. You could do the 
same for ships if they were wiling to sacrifice some cargo tonnage for 
limestone.
Greg
________________________________
From: geoengineering@googlegroups.com [geoengineering@googlegroups.com] on 
behalf of Oscar Escobar [oscar2000esco...@gmail.com]
Sent: Wednesday, February 12, 2014 1:00 PM
To: geoengineering@googlegroups.com
Subject: [geo] Shipping emissions can lead to high local ocean acidification

Strong acids formed from shipping emissions can produce seasonal 'hot spots' of
ocean acidification, a recent study finds. These hot spots, in ocean areas 
close to
busy shipping lanes, could have negative effects on local marine ecology and
commercially farmed seafood species.

Shipping emissions can lead to high local
ocean acidification

Oceans have become more acidic since pre-industrial times. The average global 
ocean pH -
which decreases with increasing acidity - has dropped by 0.1 because the seas 
have
absorbed 30-40% of manmade CO2. However, it is not only CO2 that can acidify 
oceans.
Shipping emissions, a significant source of atmospheric pollution, annually 
release around
9.5 million metric tons of sulphur and 16.2 million metric tons of nitric 
oxides.

When dissolved in seawater, these pollutants are converted into the strong 
sulphuric and
nitric acids, adding to ocean acidification. Increasing acidity poses a threat 
to marine
ecosystems, harming species such as coral and algae, as well as commercial 
aquaculture
species, such as shellfish.

The researchers used state of the art computer modelling techniques and 
datasets to create
a high resolution simulation of global shipping emissions' effects on ocean 
acidity. The
simulation calculated the acidifying impacts of shipping sulphur and nitric 
oxide emissions on
a month by month basis, over one year. In addition to shipping-related 
influences on acidity,
the model also included many physical and environmental factors, such as ocean 
surface
water mixing and atmospheric effects.

The results agreed with previous studies of the average annual ocean 
acidification, but,
importantly, revealed significant differences between regions and seasons. Ocean
acidification was highest in the northern hemisphere, occurring in 'hot spots' 
close to coastal
areas and busy shipping lanes during the summer months. These 'hot spots' 
coincide with
peak activity of some biological processes, such as plankton blooms and fish 
hatching,
where they may cause greater harm. On a local scale, the acidification - a pH 
drop of
0.0015-0.0020 - was equal to CO2's global annual acidifying effects.

The model did not include some coastal ocean areas, such as the Mediterranean 
Sea, as
there were limitations in the oceanographic atlases used. However, 
acidification is likely to
be high in these areas given the heavy shipping traffic from ports.

International regulation is in place to reduce shipping atmospheric sulphur 
emissions
through the International Maritime Organization's Emission Control Areas (ECA), 
which are
in force in four ocean areas, including the Baltic and North Seas. One 
technology commonly
used to achieve ECA targets is 'seawater scrubbing', where exhaust pollutants 
are removed
using seawater.

This study drew on data from 2000 and 2002, prior to the enforcement of ECAs. 
However,
the researchers note that seawater scrubbing, without additional steps to 
neutralise the
acids that it produces, causes acidification in regions where biodiversity or 
commercial
aquaculture may be most negatively affected. These previously overlooked 
sources of ocean
acidification and policy impacts could be used to inform future discussions of 
controls
relating to shipping emissions or ocean acidification

The study:

Shipping contributes to ocean acidification
Ida-Maja Hassellöv et al DOI: 10.1002/grl.50521
http://onlinelibrary.wiley.com/doi/10.1002/grl.50521/full
http://onlinelibrary.wiley.com/doi/10.1002/grl.50521/abstract

Abstract

[1] The potential effect on surface water pH of emissions of SOX and NOX from 
global ship routes is assessed. The results indicate that regional pH 
reductions of the same order of magnitude as the CO2-driven acidification can 
occur in heavily trafficked waters. These findings have important consequences 
for ocean chemistry, since the sulfuric and nitric acids formed are strong 
acids in contrast to the weak carbonic acid formed by dissolution of CO2. Our 
results also provide background for discussion of expanded controls to mitigate 
acidification due to these shipping emissions.


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