Greg:

I don't know what you mean by saying that "this problem would seem to pale 
in comparison to CO2 acidification with an ocean input of about 8 GT (vs thand 
NOx).  Also, probably dwarfed by SOx and NOx from land based generation"

I think the point of the article is the *heightened **"local" and 
temporal*effects of shipping emissions, specially in coastal areas close to 
shipping 
routes.  Also, shipping SOx is estimated to be 16% of all global emissions (all 
inclusive I take it to be), perhaps *comparable to those of all road 
vehicles in the world*. 
The 16% figure from this study: Ship impacts on the marine atmosphere: 
insights into the contribution of shipping emissions to the properties of 
marine aerosol and clouds 
http://www.atmos-chem-phys.net/12/8439/2012/acp-12-8439-2012.pdf (Coggon et 
al.)

As to solutions:

Perhaps a change in fuel, coxed (pun intended) by regulation, would have a 
more immediate effect... “Thanks to decisions taken in London by the body 
that polices world shipping, this pollution could kill as many as a million 
more people in the coming decade – even though a simple change in the rules 
could stop it” Fred Pearce in "How 16 ships create as much pollution as all 
the cars in the world" (2009 DailyMail article) 
http://www.dailymail.co.uk/sciencetech/article-1229857/How-16-ships-create-pollution-cars-world.html
 

By the way, he also makes the point: *“The most staggering statistic of all 
is that just 16 of the world’s largest ships can produce as much 
lung-clogging sulphur pollution as all the world’s cars.” *I don't know how 
accurate this statistic is, but It does re-enforce the argument for the 
local and temporal ocean acidification effects of shipping emissions. 

Best regards,

Oscar E.











On Wednesday, February 12, 2014 6:14:13 PM UTC-5, Greg Rau wrote:
>
>  Thanks, Oscar. However,e stated MTs of SOX  this problem would seem to 
> pale in comparison to CO2 acidification with an ocean input of about 8 GT 
> (vs thand NOx).  Also, probably dwarfed by SOx and NOx from land based 
> generation. Speaking of seawater scrubbing, this is also commonly done at 
> power plants (esp Asia) - good for air but very efficiently acidifies the 
> ocean.  Solution - place limestone downstream of the gas/seawater 
> contacting. You could do the same for ships if they were wiling to 
> sacrifice some cargo tonnage for limestone.
> Greg  
>   ------------------------------
> *From:* [email protected] <javascript:> [
> [email protected] <javascript:>] on behalf of Oscar Escobar [
> [email protected] <javascript:>]
> *Sent:* Wednesday, February 12, 2014 1:00 PM
> *To:* [email protected] <javascript:>
> *Subject:* [geo] Shipping emissions can lead to high local ocean 
> acidification
>
>   Strong acids formed from shipping emissions can produce seasonal ‘hot 
> spots’ of 
> ocean acidification, a recent study finds. These hot spots, in ocean areas 
> close to 
> busy shipping lanes, could have negative effects on local marine ecology 
> and 
> commercially farmed seafood species. 
>   
> Shipping emissions can lead to high local 
> ocean acidification 
>  
> Oceans have become more acidic since pre-industrial times. The average 
> global ocean pH – 
> which decreases with increasing acidity – has dropped by 0.1 because the 
> seas have 
> absorbed 30-40% of manmade CO2. However, it is not only CO2 that can 
> acidify oceans. 
> Shipping emissions, a significant source of atmospheric pollution, 
> annually release around 
> 9.5 million metric tons of sulphur and 16.2 million metric tons of nitric 
> oxides. 
>  
> When dissolved in seawater, these pollutants are converted into the strong 
> sulphuric and 
> nitric acids, adding to ocean acidification. Increasing acidity poses a 
> threat to marine 
> ecosystems, harming species such as coral and algae, as well as commercial 
> aquaculture 
> species, such as shellfish. 
>  
> The researchers used state of the art computer modelling techniques and 
> datasets to create 
> a high resolution simulation of global shipping emissions’ effects on 
> ocean acidity. The 
> simulation calculated the acidifying impacts of shipping sulphur and 
> nitric oxide emissions on 
> a month by month basis, over one year. In addition to shipping-related 
> influences on acidity, 
> the model also included many physical and environmental factors, such as 
> ocean surface 
> water mixing and atmospheric effects. 
>  
> The results agreed with previous studies of the average annual ocean 
> acidification, but, 
> importantly, revealed significant differences between regions and seasons. 
> Ocean 
> acidification was highest in the northern hemisphere, occurring in ‘hot 
> spots’ close to coastal 
> areas and busy shipping lanes during the summer months. These ‘hot spots’ 
> coincide with 
> peak activity of some biological processes, such as plankton blooms and 
> fish hatching, 
> where they may cause greater harm. On a local scale, the acidification – a 
> pH drop of 
> 0.0015-0.0020 – was equal to CO2’s global annual acidifying effects. 
>  
> The model did not include some coastal ocean areas, such as the 
> Mediterranean Sea, as 
> there were limitations in the oceanographic atlases used. However, 
> acidification is likely to 
> be high in these areas given the heavy shipping traffic from ports. 
>  
> International regulation is in place to reduce shipping atmospheric 
> sulphur emissions 
> through the International Maritime Organization’s Emission Control Areas 
> (ECA), which are 
> in force in four ocean areas, including the Baltic and North Seas. One 
> technology commonly 
> used to achieve ECA targets is ‘seawater scrubbing’, where exhaust 
> pollutants are removed 
> using seawater. 
>  
> This study drew on data from 2000 and 2002, prior to the enforcement of 
> ECAs. However, 
> the researchers note that seawater scrubbing, without additional steps to 
> neutralise the 
> acids that it produces, causes acidification in regions where biodiversity 
> or commercial 
> aquaculture may be most negatively affected. These previously overlooked 
> sources of ocean 
> acidification and policy impacts could be used to inform future 
> discussions of controls 
> relating to shipping emissions or ocean acidification
>
>  The study:
>
>   *Shipping contributes to ocean acidification*
>  Ida-Maja Hassellöv et al DOI: 10.1002/grl.50521
>  
> http://onlinelibrary.wiley.com/doi/10.1002/grl.50521/full<http://www.google.com/url?q=http%3A%2F%2Fonlinelibrary.wiley.com%2Fdoi%2F10.1002%2Fgrl.50521%2Ffull&sa=D&sntz=1&usg=AFQjCNHJSxPMNe8CpfUrXOtZREvy7hx6jg>
>  http://onlinelibrary.wiley.com/doi/10.1002/grl.50521/abstract
>  
>   Abstract 
>  
> [1] The potential effect on surface water pH of emissions of SO*X* and NO
> *X* from global ship routes is assessed. The results indicate that 
> regional pH reductions of the same order of magnitude as the CO2-driven 
> acidification can occur in heavily trafficked waters. These findings have 
> important consequences for ocean chemistry, since the sulfuric and nitric 
> acids formed are strong acids in contrast to the weak carbonic acid formed 
> by dissolution of CO2. Our results also provide background for discussion 
> of expanded controls to mitigate acidification due to these shipping 
> emissions.
>   
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