Strange that some people prefer to stick with a model that is so obviously 
useless as a representation of reality, Olaf Schuiling

From: Schuiling, R.D. (Olaf)
Sent: dinsdag 27 januari 2015 10:04
To: '[email protected]'
Subject: RE: [geo] Energy Planning and Decarbonization Technology | The Energy 
Collective

Come on, Francesc, you can think too. Their model implicitly assumes that 
grains will never move on the beach, and that water will stay immobile during 
2000 years. Besides they assume the numbers for rates of weathering such as 
were established in clean laboratories without any biotic influences. This puts 
their model miles out of reality, and it is not anecdotes, we have looked at 
rates of reaction in flume experiments and in imitated surf, and they are 
several ORDERS OF MAGNITUDE  larger than what they assumed. Their assumption 
that silica crusts will form and make further dissolution impossible is 
completely nonsense. I have done many experiments with olivine grains in a 
moving medium, and NEVER had any problem of silica crusts forming. No doubt 
that their mathematics is correct, but their assumptions are from a completely 
unrealistic phantasy world, Olaf Schuiling

From: [email protected]<mailto:[email protected]> 
[mailto:[email protected]] On Behalf Of Francesc Montserrat
Sent: maandag 26 januari 2015 12:22
To: [email protected]<mailto:[email protected]>
Subject: Re: [geo] Energy Planning and Decarbonization Technology | The Energy 
Collective

As for now, Suzanne Hangx and Chris Spiers provided a working model, resulting 
in a set of (dissolution rate) values. Until the time that someone comes up 
with a better model and/or more accurate values, I think that the scientific 
method dictates we stick with the previous one.
You know I agree with you in principle, Olaf, but mentioning "just-so" 
anecdotes/facts/observations is not enough to discredit a model...fortunately. 
Most, if not all, models start with being a very strong abstraction of reality, 
only to be tuned as mechanistic knowledge of the process under investigation 
increases. Slowly, such models become the minimal adequate models (MAM) we 
normally use to explain and/or predict those processes.

Let's be scientific about it and come up with a better tuned model for olivine 
dissolution and relevant consequences in terms of carbonate system, carbon 
sequestration and downstream ecological impacts in natural waters, including 
seawater.

As for Andrew's questions on location of the mines etc., I think that Nils 
Moosdorf, Phil Renforth and Jens Hartmann have done a good job in their paper 
answering the primary questions 
(http://pubs.acs.org/doi/abs/10.1021/es4052022). As for coastal defense 
win-win: have a look at this (http://www.dezandmotor.nl/en-GB/), and then 
imagine one (partially) made up of olivine...but be careful to also imagine 
that the olivine in such a semi-natural structure releases concomitant amounts 
of silicate (conceivably causing massive diatom blooms, especially in the later 
months of the year when silicate is depleted in seawater) and considerable 
amounts of Nickel (of which we simply don't know what it does to the foodweb).

Cheers,
Francesc
On 26-01-15 10:33, Schuiling, R.D. (Olaf) wrote:
Well, you better forget the model of Hangx and Spiers, as it has no relation to 
reality. They forget that grains roll on the beach and collide and scour each 
other knocking off micron sized slivers, they use weathering rates obtained in 
clean laboratories under exclusion of biotic factors, and they assumed that 
waters of the sea do not move. I attach a rebuttal of it (Schuiling, R. (2014) 
Climate Change and CO2 Removal from the Atmosphere. Natural Science, 6, 
659-663. doi: 10.4236/ns.2014.69065<http://dx.doi.org/10.4236/ns.2014.69065>). 
A nice walk along the beach would have saved them a lot of wasted time.

From: [email protected]<mailto:[email protected]> 
[mailto:[email protected]] On Behalf Of Christoph Voelker
Sent: zondag 25 januari 2015 17:15
To: [email protected]<mailto:[email protected]>; 
[email protected]<mailto:[email protected]>
Subject: Re: [geo] Energy Planning and Decarbonization Technology | The Energy 
Collective

Well, firstly there has been the study of Hangx and Spiers (2009),

Hangx, S. J. T., & Spiers, C. J. (2009). Coastal spreading of olivine to 
control atmospheric CO2 concentrations: A critical analysis of viability. 
International Journal of Greenhouse Gas Control, 3(6), 757–767. 
doi:10.1016/j.ijggc.2009.07.001

who arrive at the conclusion

"The feasibility of the concept depends on the rate of olivine dissolution, the 
sequestration capacity of the dominant reaction, and its CO2 footprint. 
Kinetics calculations show that offsetting 30% of worldwide 1990 CO2 emissions 
by beach weathering means distributing of 5.0 Gt of olivine per year. For mean 
seawater temperatures of 15–25 8C, olivine sand (300 mm grain size) takes 
700–2100 years to reach the necessary steady state sequestration rate and is 
therefore of little practical value. To obtain useful, steady state CO2 uptake 
rates within 15–20 years requires grain sizes <10 mm. However, the preparation 
and movement of the required material poses major economic, infrastructural and 
public health questions. We conclude that coastal spreading of olivine is not a 
viable method of CO2 sequestration on the scale needed."

I am sure that Olaf Schuiling has a different viewpoint, especially on the 
kinetics, but what remains independent of the kinetics is that the total amount 
of olivine needed to get a sizeable reduction in pCO2 growth rate is on the 
order of a few Gt per year..

An estimate of how much silicate minerals are mined today (to get that into 
perspective) is available from

Phil Renforth et al. (2011) Silicate Production and Availability for Mineral 
Carbonation. Environ. Sci. Technol., 45, 2035–2041

And Moosdorf et al. have estimated the carbon dioxide efficiency, taking into 
account transportation etc:

Moosdorf, Renforth and Hartmann (2014) Carbon Dioxide Efficiency of Terrestrial 
Enhanced Weathering, Env Sci Technol. 48, 4809−4816

So there s already a lot around..

Cheers, Christoph

On 1/25/15 2:47 PM, Andrew Lockley wrote:

Someone needs to do a proper infrastructure study of olivine to more 
comprehensively rebut the "contraptionist" arguments of some in the CDR 
community.

Where are the mines?
How many railcars?
At what scale are the crushing machines?
Will we distribute to beaches with lorries, or shallow seas with ships (and let 
longshore drift do the work)?
What environmental monitoring spend is needed?
Can this be used for a coastal defence win win?
Etc.

A
On 25 Jan 2015 13:23, "Schuiling, R.D. (Olaf)" 
<[email protected]<mailto:[email protected]>> wrote:
Of course I support Andrew in this view, although chucking it into the sea is 
maybe a too simplistic view. My preference is to spread (coarse-grained, so 
little crushing energy spent) olivine on beaches, where the surf will crush 
them by grain collisions and by scraping them against each other. In a short 
while (in our experiments it took 10 days to see already a large effect, the 
water became opaque milky white from all the micron-sized slivers that were 
knocked off). A mixture of coarser and finer grit is more effective than a 
single grain size, as in society, the big ones crush the smaller ones. The surf 
is the biggest ballmill on earth, and it is free of charge! An extension of 
this method is to discharge them in shallow seas with strong bottom currents. 
There are many sea bottoms covered with pebbles, and there the same effects of 
crushing can be seen. To avoid misunderstanding, the sea will not become opaque 
white, slivers that form are washed away by  the next wave. Within those ten 
day experiments, we observed that many slivers had already been transformed to 
brucite, (Mg(OH)2, known to carbonate very fast, and the pH of the water had 
already been raised considerably. And yes, of course, it will take a lot of 
olivine, which is fortunately the most abundant mineral on earth, Olaf Schuiling

From: [email protected]<mailto:[email protected]> 
[mailto:[email protected]<mailto:[email protected]>]
 On Behalf Of Andrew Lockley
Sent: zaterdag 24 januari 2015 15:56
To: geoengineering
Subject: [geo] Energy Planning and Decarbonization Technology | The Energy 
Collective


Poster's note : none of this explains why there's any need for integration. 
Chucking olivine in the sea seems easier and cheaper than all.

http://theenergycollective.com/noahdeich/2183871/3-ways-carbon-removal-can-help-unlock-promise-all-above-energy-strategy

3 Ways Carbon Removal can Help Unlock the Promise of an All-of-the-Above Energy 
Strategy

January 24, 2015

“We can’t have an energy strategy for the last century that traps us in the 
past. We need an energy strategy for the future – an all-of-the-above strategy 
for the 21st century that develops every source of American-made energy.”– 
President Barack Obama, March 15, 2012

An all-of-the-above energy strategy holds great potential to make our energy 
system more secure, inexpensive, and environmentally-friendly. Today’s approach 
to all-of-the-above, however, is missing a key piece: carbon dioxide removal 
(“CDR”). Here’s three reasons why CDR is critical for the success of an 
all-of-the-above energy strategy:

1. CDR helps unite renewable energy and fossil fuel proponents to advance 
carbon capture and storage (“CCS”) projects. Many renewable energy advocates 
view CCS as an expensive excuse to enable business-as-usual fossil fuel 
emissions. But biomass energy with CCS (bio-CCS) projects are essentially 
“renewable CCS” (previously viewed as an oxymoron), and could be critical for 
drawing down atmospheric carbon levels in the future. As a result, fossil CCS 
projects could provide a pathway to “renewable CCS” projects in the future. 
Because of the similarities in the carbon capture technology for fossil and 
bioenergy power plants, installing capture technology on fossil power plants 
today could help reduce technology and regulatory risk for bio-CCS projects in 
the future. What’s more, bio-CCS projects can share the infrastructure for 
transporting and storing CO2 with fossil CCS installations. Creating such a 
pathway to bio-CCS should be feasible through regulations that increase carbon 
prices and/or biomass co-firing mandates slowly over time, and could help unite 
renewable energy and CCS proponents to develop policies that enable the 
development of cost-effective CCS technology.

2. CDR bolsters the environmental case for nuclear power by enabling it to be 
carbon “negative”: Many environmental advocates say that low-carbon benefits of 
nuclear power are outweighed by the other environmental and safety concerns of 
nuclear projects. The development of advanced nuclear projects paired with 
direct air capture (“DAC”) devices, however, could tip the scales in nuclear’s 
favor. DAC systems that utilize the heat produced from nuclear power plants can 
benefit from this “free” source of energy to potentially sequester CO2 directly 
from the atmosphere cost-effectively. The ability for nuclear + DAC to provide 
competitively-priced, carbon-negative energy could help convince nuclear 
power’s skeptics to support further investigation into developing safe and 
environmentally-friendly advanced nuclear systems.

3. CDR helps enable a cost-effective transition to a decarbonized economy: 
Today, environmental advocates claim that prolonged use of fossil fuels is 
mutually exclusive with preventing climate change, and fossil fuel advocates 
bash renewables as not ready for “prime time” — i.e. unable to deliver the 
economic/development benefits of inexpensive fossil energy. To resolve this 
logjam, indirect methods of decarbonization — such as a portfolio of low-cost 
CDR solutions — could enable fossil companies both to meet steep emission 
reduction targets and provide low-cost fossil energy until direct 
decarbonization through renewable energy systems become more cost-competitive 
(especially in difficult to decarbonize areas such as long-haul trucking and 
aviation).

Of course, discussion about the potential for CDR to enable an all-of-the-above 
energy strategy is moot unless we invest in developing a portfolio of CDR 
approaches. But if we do make this investment in CDR, an all-of-the-above 
energy strategy that delivers a diversified, low-cost, and low-carbon energy 
system stands a greater chance of becoming a reality.

Noah Deich

Noah Deich is a professional in the carbon removal field with six years of 
clean energy and sustainability consulting experience. Noah currently works 
part-time as a consultant for the Virgin Earth Challenge, is pursuing his MBA 
from the Haas School of Business at UC Berkeley, and writes a blog dedicated to 
carbon removal (carbonremoval.wordpress.com<http://carbonremoval.wordpress.com>)

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--

Christoph Voelker

Alfred Wegener Institute for Polar and Marine Research

Am Handelshafen 12

27570 Bremerhaven, Germany

e: [email protected]<mailto:[email protected]>

t: +49 471 4831 1848
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vriendelijke groeten / kind regards,

Dr. Francesc Montserrat

Department of Ecosystem Studies
Royal Netherlands Institute for Sea Research (NIOZ)

Korringaweg 7
4401 NT Yerseke
The Netherlands

Office:   +31 (0)113 577 462
Mobile:  +31 (0)6 2481 5595

[cid:[email protected]]

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