Re: [Biofuel] Purchasing a still for ethanol

2005-09-22 Thread Pieter Koole


 Maximum 96% by distillation, 192-proof, then it stops because of
 azeotropism. The boiling temperature of 96% ethanol is lower than
 that of pure ethanol. snip

With respect Keith, but if I'm not wrong, the boiling point of 96% is higher
than that of pure ethanol. At that percentage the boiling point of the last
bit of water is lower than 100° C, being exactly the same as that of 96%.
Am I wrong ?
Well, anyway not so important. We just cannot get it higher than 96% without
other tricks like tholuene or benzene.
BTW, tholuene isn't half as carcinogene as benzene, but I don't know if it
works with tholuene.

Greetings,
Pieter.




 Best wishes

 Keith

 PS: Sorry I got waylaid Manickh, I haven't forgotten you, I'll get
 back to what we were discussing as soon as I can. All best meanwhile,
 K.


 Only up to 170-180 proof which could be used for E85 cars. To get
 100% alcohol try extraction with castor oil of fermented liquor
 followed by simple distillation if castor oil does not dissolve any
 water. Please check this in JTF archives. If this does not work try
 azeotropic distillation of the 170 proof alcohol with  toluene in
 which case simple distillation would suffice to remove the water
 leaving more concentrated alcohol in the still. Take care and first
 check MSDS data whether toluene is carcinogenic.
 Manickh
 
 Bob [EMAIL PROTECTED] wrote:
 
 Where can I buy a still that can produce fuel grade ethanol (190 proof)?
 
 I have read that the charles 803 is a poor still and I have no
 access to anyone knowledgable enough to build a good enough still
 without accurate plans. I could possibly pay someone to build one
 if I knew exactly what to tell them to build.
 
 I have done google and JTF and searched this list but have come up
 with no one that operates a successful fuel still.
 
 Thanks
 Bob
 


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Re: [Biofuel] Morality test for you all

2005-09-18 Thread Pieter Koole
I would take a videocamara full color with zoom lens, wireless connected to
the internet.






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Re: [Biofuel] Deacidification

2005-09-08 Thread Pieter Koole
Hi Todd,

 There is a method of making biodiesel where all feedstock is converted 
 to soap, then chemically cracked to 100% FFAs and esterified to yield 
 ~100% biodiesel. But it's doubtful that you have the set up for 
 something that involved at any moderate scale.
 

What methode is that ?

Met  dank en vriendelijke groet,
Pieter Koole




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Re: [Biofuel] Deacidification

2005-09-08 Thread Pieter Koole
How stupid am I ??
When we remove the FFA's , we have only left the FFA's connected to a glyc
molecule.
Right so far ?
The next step we do with the single stage is, breaking the fatty acids of
the glyc molecule, which produces FFA's.
(Not) right so far ?
Next we connect a meth. molecule on top of the FFA's.
So why do we have to remove the FFA's at the first place ?

Met  dank en vriendelijke groet,
Pieter Koole

- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Wednesday, September 07, 2005 10:48 PM
Subject: Re: [Biofuel] Deacidification


 Hi Ian

 Hi Folks
 I have tried the deacidification method with good results in the
 test batch. However when I heat the oil to process it foams
 agressivly. I assume this is the water/lye reacting? It leaves a
 thick layer of fat/soap? which i skim off leaving good oil,
 titration of 1ml instead of 7mls. For want of a better phrase, is
 this normal?

 You probably got some soapstock along with the oil, but it doesn't
 seem to matter much. Skimming it off is the right thing to do with
 it. Did you try processing the deacidified oil yet?

 http://journeytoforever.org/biodiesel_make2.html#deacid
 Make your own biodiesel - page 2: Deacidifying WVO

 Best wishes

 Keith


 Cheers Ian


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Re: [Biofuel] Problems, problems, problems

2005-08-30 Thread Pieter Koole
Thanks Keith,
If the silicone is not what is gelling the BD, what else can it be ?
I still make BD from other suppliers without problems, but as soon as I mix
any oil from this particular adress in it, it turns hard. With hard I mean
as hard as butter in a fridge, so not jelly.
Ok, but IF it is caused by the silicone, what can we do ? Because we will
have to deal with this more and more in the future.
Thanks again.

 Dag Pieter

 Hello all,
 I found a new adres where I can collect quit a bit of good quality
 oil, well, that is what I thought.
 In this oil is added what we call E900 ( a european code ) which is
 dimethylpolysiloxaan, to avoid the oil from foaming when they bake
 their chips.
 From this oil I get one great big lump of solid stuff when I try to
 make BD from it.
 Can anyone please help me ?
 Of course I could go and look for another restaurant, but this E900
 is used more and more, so I will meet this problem more often in the
 future.
 E900 is a polymere from silicone : (C2H6OSi)n

 It's used here in Japan too, we did some research on it when we first
 came here. We've processed a lot of oil with silicone anti-foaming
 agent in it and it hasn't made any difference. It's a very small
 proportion in the oil though, I don't recall the exact figure. Maybe
 they use more in the EU, but I doubt that's what gelling your
 biodiesel.

 Best wishes

 Keith


 Met  dank en vriendelijke groet,
 Pieter Koole
 Netherlands


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Re: [Biofuel] Problems, problems, problems

2005-08-30 Thread Pieter Koole
No, I did not titrate, but made 9 batches of 20 ml in a tube, starting at 3½
gram / ltr of oil, next 4 grams per liter, 4½ grams/ltr etc. In this way I
have made a lot of BD now and it works fine.
There was no difference at all, they all turned hard and the color was like
coffee with milk.
The E900 so they call it, is added at a mixture of soja and palm oil or a
mixture of rapeseedoil and palm oil, at a rate of 3 ppm. There is nothing
else in it, so the manufacturer assured me.
When I try good oil from other restaurants, everything is fine, but as soon
as there is any oil from this man in it, I have the problems there.
Of course a solution would be to stop collecting oil from there, but many
restaurants use the same oil and they have the same scedule of renewing the
oil. They sell high quality chips and snacks and the last thing I expect is,
that they would use their oil too long.
So, I have no idea what is happening. Could it be something like polymeres ?
I don't know anything about polymeres, so maybe it's a stupid question.
Thanks all in advance.
Pieter.


Pieter, I agree with Kieth, it probably is not the anti-foaming agent
which is there in parts per million conc(?).  Have you titrated the
stuff? Maybe a very high free fatty acid content?  Or maybe it is all
saturated fat?  Another possibility is that something is extracted into
the cooking oil in significant quantities, which solidifies when it is
diluted with more oil?


Pieter Koole wrote:
 Thanks Keith,
 If the silicone is not what is gelling the BD, what else can it be ?
 I still make BD from other suppliers without problems, but as soon as I
mix
 any oil from this particular adress in it, it turns hard. With hard I
mean
 as hard as butter in a fridge, so not jelly.
 Ok, but IF it is caused by the silicone, what can we do ? Because we will
 have to deal with this more and more in the future.
 Thanks again.


Dag Pieter


Hello all,
I found a new adres where I can collect quit a bit of good quality
oil, well, that is what I thought.
In this oil is added what we call E900 ( a european code ) which is
dimethylpolysiloxaan, to avoid the oil from foaming when they bake
their chips.

From this oil I get one great big lump of solid stuff when I try to

make BD from it.
Can anyone please help me ?
Of course I could go and look for another restaurant, but this E900
is used more and more, so I will meet this problem more often in the
future.
E900 is a polymere from silicone : (C2H6OSi)n

It's used here in Japan too, we did some research on it when we first
came here. We've processed a lot of oil with silicone anti-foaming
agent in it and it hasn't made any difference. It's a very small
proportion in the oil though, I don't recall the exact figure. Maybe
they use more in the EU, but I doubt that's what gelling your
biodiesel.

Best wishes

Keith



Met  dank en vriendelijke groet,
Pieter Koole
Netherlands


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http://ozarker.org/bob

Science is what we have learned about how to keep
from fooling ourselves — Richard Feynman

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[Biofuel] Problems, problems, problems

2005-08-29 Thread Pieter Koole



Hello all,
I found a new adres where I can collect quit a bit 
of good quality oil, well, that is what I thought.
In this oil is added what we call E900 ( a european 
code ) which is dimethylpolysiloxaan, to avoid the oil from foaming when they 
bake their chips.
From this oil I get one great big lump of solid 
stuff when I try to make BD from it.
Can anyone please help me ?
Of course I could go and look for another 
restaurant, but this E900 is used more and more, so I will meet this problem 
more often in the future.
E900 is a polymere from silicone : 
(C2H6OSi)n

Met dank en vriendelijke groet,Pieter KooleNetherlands
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Re: [Biofuel] Lignin crop redidue breakdown

2005-08-19 Thread Pieter Koole




 My question is since 
composting does a good job of breaking down lignin, would it be possible to use 
composting as part of the ethanol creation process?

I can imagine that the micro organisms "eat" also 
the sugars, leaving nothing for you to ferment to sugar.

Greetings,
Pieter
Netherlands

  
  

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[Biofuel] Question on methoxide

2005-08-19 Thread Pieter Koole
Hi friends,
For some reason or another I made some horrible BD and started to doubt
about what I am doing.
So I decided to make a range of 12 bottles of sodiummethoxide, varying from
3½ to 9 grams of lye per liter.
After mixing each liter of methanol with exactly the amount of lye, I found
out that the first liter was almost still one liter, and the last liter was
app. 10% less, with every next bottle a little less than the one before.
If it would be the evaporation, every bottle would lose the same amount, so
it must have to do something with the reaction between methanol and lye.
Can anyone give me the answer on the question what is the chemical reaction
?
Or is there something else happening which I don't know ?

The next question is of course, do I need 200 ml of the mixture (so that
would be more concentrated than 200 ml methanol + for example 4 grams of
lye) ?

Met  dank en vriendelijke groet,
Pieter Koole




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Re: [Biofuel] emulsion wash test

2005-08-17 Thread Pieter Koole
With permission :
The whole discussion has nothing to do with emulsion wash test.

Met vriendelijke groet,
Pieter Koole



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Re: [Biofuel] RE: jelly and jellybiofuel

2005-08-12 Thread Pieter Koole
Velen bedankt, maar in een 3rde Wereld dorpje is wallpaperglue nie so
 maklik te vind, en jy kan dit ook nie maklik self maak van locally
 available renewable resources.

Veel dank, maar in een 3e wereld dorpje is behangplaksel niet zo makkelijk
te vinden en je kan dit ook niet makkelijk zelf maken van plaatselijk
herbruikbare materialen.
 
 Wanneer het jy al ooit erger Nederlands dan die gelesen?!! LOL! Maar
 miskien kan u dit verstaan...

Wanneer heb je zulk slecht Nederlands gelezen ? Maar misschien kun je dit
begrijpen.
 

Nee Keith, ik maak geen grapje. Sommige mensen op deze wereld denken dat
Nederland de hoofdstad van Denemarken is. Je moet al Nederlandstalig
opgegroeid zijn, anders is het erg moeilijk om de taal te leren.

Met vriendelijke groet,
Pieter Koole



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Re: [Biofuel] RE: jelly and jellybiofuel

2005-08-11 Thread Pieter Koole
Wauw !!
Somebody - and not JUST somebody - on this forum writing in real Dutch.
Very good Keith.

Met vriendelijke groet,
Pieter Koole

- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Thursday, August 11, 2005 9:38 AM
Subject: Re: [Biofuel] RE: jelly and jellybiofuel


Dag Pieter

Hello,
Sorry if I start talking about something you are not talking about, because
I did not follow this discussion, but I think I can make up that you try to
solidify ethanol.
You can do that very easy with wallpaperglue ( Carboxyl methyl cellulose ).
Just use ethanol in stead of water and make strong glue.

Velen bedankt, maar in een 3rde Wereld dorpje is wallpaperglue nie so
maklik te vind, en jy kan dit ook nie maklik self maak van locally
available renewable resources.

Wanneer het jy al ooit erger Nederlands dan die gelesen?!! LOL! Maar
miskien kan u dit verstaan...

Beste wense

Keith


Met vriendelijke groet,
Pieter Koole

- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Wednesday, August 10, 2005 5:24 PM
Subject: Re: [Biofuel] RE: jelly and jellybiofuel


 There is (apparently) more than one recipe for sterno.
 
 We had a thread going a while back that included a method: calcium
 acetate (egg shells and vinegar) with ethanol.

This is from a previous message on ethanol gel:


 Keith Addison wrote:
 
 Mix 11 grams of Calcium Acetate with 30 mg of water. Make sure all
 the Calcium Acetate is dissolved, this might take an hour of
 occasional stirring. Measure 10 mg of the solution. Slowly add 40 mg
 of ethanol. As you add the ethanol, the mixture should gel
 instantly. Pour off any remaining ethanol (a very small amount).
 Because the mixture gels instantly, you do not have to combine the
 two until you need to use it for cooking.
 
 I made some Calcium Acetate by neutralizing acetic acid with lime.
 Works well, gels immediately, burns very nicely, but it's not very
 stable, best to make it when you need it. This way, since it's
 bioduels in the Third World rural development setting that we're
 most interested in, everything required is probably available
 locally, or could be. Ethanol can be brewed on-site (and probably is
 already), even if it's not absolute; acetic acid can be brewed the
 same way, by aerating the mash, and agricultural lime is fairly
 ubiquitous.

Also, from Hoagy (chalk and vinegar, sunshine and moonshine):

Some other jelled gelled alcohol ideas --
   
Zen Gelled Alcohol Stoves - Sterno-like Stoves
Jelled/Gelled Alcohol
http://zenstoves.net/Sterno.htm
Extreme do it yourselfers can make their own gelled fuel
at home with alcohol and calcium acetate (C4H6CaO4).
Either methanol or ethanol can be used for fuel.
Calcium acetate (C4H6CaO4) can be purchased or made
by slowly dissolving calcium carbonate (eggshells or chalk)
in vinegar, filtering, and allowing to dry.
If you are new to chemistry take a look at
this high school science project page.
   
Chemical Reactions and Solid Fuel
   
  
http://www.montvilleschools.org/highschool/science/edorff/chemistry/fu
   elslab.htm
A solid camping fuel like Sternoô was discovered several years ago
when a group of campers forgot to pack fuel for their camp stove.
Because the area prohibited use of campfires, the campers needed to
use an alternative fuel source.  One of the campers made a gel
that they could use as a solid fuel.  To make this gel,
chalk was crushed and mixed with vinegar.  The resulting mixture
was filtered through a napkin and the liquid collected was
heated using a solar reflector.  Some rubbing alcohol
was poured into the solution to form a gel which burned.
  Step 1:  Reaction between chalk (calcium carbonate) and
  vinegar (acetic acid, dilute) to produce
  carbon dioxide, water and calcium acetate . . .
  Step 2:  Filtration of unreacted chalk from the mixture
  to leave a solution of calcium acetate in water . . .
  Step 3:  Removal of excess water from calcium acetate solution . .
.
  Step 4:  Mixing alcohol with calcium acetate to form fuel . . .
  Step 5:  Combustion of fuel produced . . .
  Step 6:  Evaluation of fuels produced . . . [more]
   
Baking Bread (And Other Recipes) With An Alcohol Stove
http://trailquest.net/baking.html
   
Cloudwalker's Homemade Alcohol Stove
http://www.cloudwalkersatpage.com/page014.html
   
The Gelled Alcohol Stove Fuel
- Calcium Acetate
http://wings.interfree.it/html/Gelalcohol.html



 Mike
 
 TarynToo [EMAIL PROTECTED] wrote:
 
 Isn't jelly solid ethanol Sterno fuel? Or is Sterno made with
 methanol?
 
 It's hard to imagine that there's any energy advantage to jellied fuels
 over woody plants for cooking purposes, I know that many third world
 areas have extreme shortages of cooking fuels or firewood, but it seems
 like that's

Re: [Biofuel] RE: jelly

2005-08-10 Thread Pieter Koole
Hi Todd,
Thanks for your answer.
I have never had any good results with acid/base reactions, so my question
is, can I also make BD from the FFA's with the single base reaction ?
Thanks again in advance.

Met  dank en vriendelijke groet,
Pieter Koole

- Original Message -
From: Appal Energy [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Wednesday, August 10, 2005 12:38 AM
Subject: Re: [Biofuel] RE: jelly


 Pieter,

 The broken soap is nothing more than free fatty acids, with a
 glycerol/alcohol/water/residual-acid layer beneath it and (if using
 potassium hydroxide as the original catalyst) solid fertilizer beneath
that.

 FFAs in their pure form are only slightly more viscous (hadly
 noticeable) than biodiesel and can be run in an indirect injection
 diesel as is or heated and run through a veg-oil converted system.

 Or, you can convert them to biodiesel with acid/base processing.

 Todd Swearingen

 Pieter Koole wrote:

 And what can you do with the broken soap ?
 Met  dank en vriendelijke groet,
 Pieter Koole
 
 - Original Message -
 From: Appal Energy [EMAIL PROTECTED]
 To: Biofuel@sustainablelists.org
 Sent: Monday, August 08, 2005 11:45 PM
 Subject: Re: [Biofuel] RE: jelly
 
 
 
 
 Derick,
 
 Still, treat a small sample with concentrated sufuric or phosphoric acid
 and observe.
 
 Todd Swearingen
 
 
 DERICK GIORCHINO wrote:
 
 
 
 Thanks for the response. I feel that I may not have explained that
there
 isn't a layer it's almost a solid mass. It is about 95 deg f outside
and
 
 
 if
 
 
 I turn the soda bottle on its side it slides inside the bottle as one
 
 
 lump
 
 
 retaining the shape of the bottom of the bottle. If I shake it hard it
 
 
 does
 
 
 brake up somewhat. Kind of like when the old super ball was broken.
 I feel that I now have super glop.
 
 -Original Message-
 From: [EMAIL PROTECTED]
 [mailto:[EMAIL PROTECTED] On Behalf Of Appal Energy
 Sent: Sunday, August 07, 2005 5:51 PM
 To: Biofuel@sustainablelists.org
 Subject: Re: [Biofuel] RE: jelly
 
 
 
 
 
 But is the jelly a typical sign of over dosing?
 I have a problem with disposing of the mess I
 have made if there is a way to salvage it.
 
 
 
 
 Take a small sample and see how much concentrated sulfuric or
phosphoric
 acid it takes to crack the soap portion of the top jelly layer.
 
 This is the same thing that is done with the glyc cocktail to recover
the
 free fatty acids.
 
 Todd Swearingen
 
 
 
 
 DERICK GIORCHINO wrote:
 
 
 
 
 
 Hi Keith More
 Thanks for you response.
 I tried the world famous chop stick titration technique. Wow what a
 difference in my titration  #.
 I did a 1 ltr test in a soda bottle, with excellent result almost
 
 
 
 
 instantly.
 
 
 
 
 But here is where I got into trouble.
 The next batch was 20 liters I had some methoxide mixed from a prior
 
 
 batch
 
 
 that was also a failure and I couldn't figure what to do with the
toxic
 
 
 mix
 
 
 so I tried to dilute it to 10 g.p. liter. I did my mixing of the 20
 
 
 liters.
 
 
 As it cooled it turned into what looks like lard. I felt that I may
have
 overdosed it. So I then took some test bottles and put 20% failure oil
 
 
 and
 
 
 75% fresh wvo set it in the sun to melt/ liquefy. (105 deg F) shook it
 
 
 hard
 
 
 also a 50/50 mix in the hot state it seamed to separate better 25/75
 
 
 than
 
 
 the 50/50 but as the sun went down and it cooled the 25/75 started to
 
 
 jell
 
 
 and the glycerol layer vanished but the 50/50 looked much better with
a
 glycerol layer jelled at the bottom. I m not asking for a fix. But is
 
 
 the
 
 
 jelly a typical sign of over dosing? I have a problem with disposing
of
 
 
 the
 
 
 mess I have made if there is a way to salvage it.
 
 -Original Message-
 From: [EMAIL PROTECTED]
 [mailto:[EMAIL PROTECTED] On Behalf Of Keith
Addison
 Sent: Tuesday, August 02, 2005 8:58 PM
 To: Biofuel@sustainablelists.org
 Subject: RE: [Biofuel] RE: Phenolphthalein solution
 
 Hi Derick
 
 
 
 
 
 
 
 May be there is some help for me out there. I have made lots and lots
 
 
 of
 
 
 test batches. Most of them bad not good. One border line. And one 15
 
 
 gal
 
 
 batch with fairly good results. I have used all the options given for
 titration in the J.T. Forever. Test strips work
 
 
 
 
 
 
 ... poorly, if at all, and are not recommended by JtF.
 
 
 
 
 
 
 
 but after introducing it to
 the mix I find if I need to add more solution the color will not
change
 
 
 so
 
 
 
 
 
 
 I
 
 
 
 
 
 
 need to add strip after strip as I add the solution accuracy is
 
 
 probably
 
 
 
 
 
 
 off
 
 
 
 
 
 
 by the time I get done P.H. meter a good one I found to be about the
 
 
 same
 
 
 
 
 
 
 pH meters work well, especially if it's a good one, you shouldn't be
 having problems.
 
 
 
 
 
 
 
 and I have used phenolphthalein and get excellent response but im no
 
 
 
 
 
 
 chemist
 
 Very few of us are.
 
 
 
 
 
 
 
 can anyone tell me how much phenolphthalein to use on the test I

Re: [Biofuel] RE: jelly and jellybiofuel

2005-08-10 Thread Pieter Koole
Hello,
Sorry if I start talking about something you are not talking about, because
I did not follow this discussion, but I think I can make up that you try to
solidify ethanol.
You can do that very easy with wallpaperglue ( Carboxyl methyl cellulose ).
Just use ethanol in stead of water and make strong glue.

Met vriendelijke groet,
Pieter Koole

- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Wednesday, August 10, 2005 5:24 PM
Subject: Re: [Biofuel] RE: jelly and jellybiofuel


There is (apparently) more than one recipe for sterno.

We had a thread going a while back that included a method: calcium
acetate (egg shells and vinegar) with ethanol.

This is from a previous message on ethanol gel:


Keith Addison wrote:

Mix 11 grams of Calcium Acetate with 30 mg of water. Make sure all
the Calcium Acetate is dissolved, this might take an hour of
occasional stirring. Measure 10 mg of the solution. Slowly add 40 mg
of ethanol. As you add the ethanol, the mixture should gel
instantly. Pour off any remaining ethanol (a very small amount).
Because the mixture gels instantly, you do not have to combine the
two until you need to use it for cooking.

I made some Calcium Acetate by neutralizing acetic acid with lime.
Works well, gels immediately, burns very nicely, but it's not very
stable, best to make it when you need it. This way, since it's
bioduels in the Third World rural development setting that we're
most interested in, everything required is probably available
locally, or could be. Ethanol can be brewed on-site (and probably is
already), even if it's not absolute; acetic acid can be brewed the
same way, by aerating the mash, and agricultural lime is fairly
ubiquitous.

Also, from Hoagy (chalk and vinegar, sunshine and moonshine):

   Some other jelled gelled alcohol ideas --
  
   Zen Gelled Alcohol Stoves - Sterno-like Stoves
   Jelled/Gelled Alcohol
   http://zenstoves.net/Sterno.htm
   Extreme do it yourselfers can make their own gelled fuel
   at home with alcohol and calcium acetate (C4H6CaO4).
   Either methanol or ethanol can be used for fuel.
   Calcium acetate (C4H6CaO4) can be purchased or made
   by slowly dissolving calcium carbonate (eggshells or chalk)
   in vinegar, filtering, and allowing to dry.
   If you are new to chemistry take a look at
   this high school science project page.
  
   Chemical Reactions and Solid Fuel
  
  http://www.montvilleschools.org/highschool/science/edorff/chemistry/fu
  elslab.htm
   A solid camping fuel like Sternoô was discovered several years ago
   when a group of campers forgot to pack fuel for their camp stove.
   Because the area prohibited use of campfires, the campers needed to
   use an alternative fuel source.  One of the campers made a gel
   that they could use as a solid fuel.  To make this gel,
   chalk was crushed and mixed with vinegar.  The resulting mixture
   was filtered through a napkin and the liquid collected was
   heated using a solar reflector.  Some rubbing alcohol
   was poured into the solution to form a gel which burned.
 Step 1:  Reaction between chalk (calcium carbonate) and
 vinegar (acetic acid, dilute) to produce
 carbon dioxide, water and calcium acetate . . .
 Step 2:  Filtration of unreacted chalk from the mixture
 to leave a solution of calcium acetate in water . . .
 Step 3:  Removal of excess water from calcium acetate solution . . .
 Step 4:  Mixing alcohol with calcium acetate to form fuel . . .
 Step 5:  Combustion of fuel produced . . .
 Step 6:  Evaluation of fuels produced . . . [more]
  
   Baking Bread (And Other Recipes) With An Alcohol Stove
   http://trailquest.net/baking.html
  
   Cloudwalker's Homemade Alcohol Stove
   http://www.cloudwalkersatpage.com/page014.html
  
   The Gelled Alcohol Stove Fuel
   - Calcium Acetate
   http://wings.interfree.it/html/Gelalcohol.html



Mike

TarynToo [EMAIL PROTECTED] wrote:

Isn't jelly solid ethanol Sterno fuel? Or is Sterno made with
methanol?

It's hard to imagine that there's any energy advantage to jellied fuels
over woody plants for cooking purposes, I know that many third world
areas have extreme shortages of cooking fuels or firewood, but it seems
like that's a distribution problem, more than a real shortage.

Using firewood doesn't necessarily mean deforestation as often
alleged, very often it means local forests are maintained instead.
Where there are shortages (very serious shortages on some places)
it's usually due more to other reasons. Indoor smoke pollution is
probably a bigger problem than energy efficiency, and indeed energy
efficiency itself usually boils down to making the best use of what
you've got rather than a matter of comparative btu's or whatever.

This bit of a previous message might be of interest:

  Not all the work with improved woodstoves is convincing. Often the
  target communities also aren't convinced. Some comparisons have found

Re: [Biofuel] RE: jelly

2005-08-09 Thread Pieter Koole
And what can you do with the broken soap ?
Met  dank en vriendelijke groet,
Pieter Koole

- Original Message -
From: Appal Energy [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Monday, August 08, 2005 11:45 PM
Subject: Re: [Biofuel] RE: jelly


 Derick,

 Still, treat a small sample with concentrated sufuric or phosphoric acid
 and observe.

 Todd Swearingen


 DERICK GIORCHINO wrote:

 Thanks for the response. I feel that I may not have explained that there
 isn't a layer it's almost a solid mass. It is about 95 deg f outside and
if
 I turn the soda bottle on its side it slides inside the bottle as one
lump
 retaining the shape of the bottom of the bottle. If I shake it hard it
does
 brake up somewhat. Kind of like when the old super ball was broken.
 I feel that I now have super glop.
 
 -Original Message-
 From: [EMAIL PROTECTED]
 [mailto:[EMAIL PROTECTED] On Behalf Of Appal Energy
 Sent: Sunday, August 07, 2005 5:51 PM
 To: Biofuel@sustainablelists.org
 Subject: Re: [Biofuel] RE: jelly
 
 
 
 But is the jelly a typical sign of over dosing?
 I have a problem with disposing of the mess I
 have made if there is a way to salvage it.
 
 
 
 Take a small sample and see how much concentrated sulfuric or phosphoric
 acid it takes to crack the soap portion of the top jelly layer.
 
 This is the same thing that is done with the glyc cocktail to recover the
 free fatty acids.
 
 Todd Swearingen
 
 
 
 
 DERICK GIORCHINO wrote:
 
 
 
 Hi Keith More
 Thanks for you response.
 I tried the world famous chop stick titration technique. Wow what a
 difference in my titration  #.
 I did a 1 ltr test in a soda bottle, with excellent result almost
 
 
 instantly.
 
 
 But here is where I got into trouble.
 The next batch was 20 liters I had some methoxide mixed from a prior
batch
 that was also a failure and I couldn't figure what to do with the toxic
mix
 so I tried to dilute it to 10 g.p. liter. I did my mixing of the 20
liters.
 As it cooled it turned into what looks like lard. I felt that I may have
 overdosed it. So I then took some test bottles and put 20% failure oil
and
 75% fresh wvo set it in the sun to melt/ liquefy. (105 deg F) shook it
hard
 also a 50/50 mix in the hot state it seamed to separate better 25/75
than
 the 50/50 but as the sun went down and it cooled the 25/75 started to
jell
 and the glycerol layer vanished but the 50/50 looked much better with a
 glycerol layer jelled at the bottom. I m not asking for a fix. But is
the
 jelly a typical sign of over dosing? I have a problem with disposing of
the
 mess I have made if there is a way to salvage it.
 
 -Original Message-
 From: [EMAIL PROTECTED]
 [mailto:[EMAIL PROTECTED] On Behalf Of Keith Addison
 Sent: Tuesday, August 02, 2005 8:58 PM
 To: Biofuel@sustainablelists.org
 Subject: RE: [Biofuel] RE: Phenolphthalein solution
 
 Hi Derick
 
 
 
 
 
 May be there is some help for me out there. I have made lots and lots
of
 test batches. Most of them bad not good. One border line. And one 15
gal
 batch with fairly good results. I have used all the options given for
 titration in the J.T. Forever. Test strips work
 
 
 
 
 ... poorly, if at all, and are not recommended by JtF.
 
 
 
 
 
 but after introducing it to
 the mix I find if I need to add more solution the color will not change
so
 
 
 
 
 I
 
 
 
 
 need to add strip after strip as I add the solution accuracy is
probably
 
 
 
 
 off
 
 
 
 
 by the time I get done P.H. meter a good one I found to be about the
same
 
 
 
 
 pH meters work well, especially if it's a good one, you shouldn't be
 having problems.
 
 
 
 
 
 and I have used phenolphthalein and get excellent response but im no
 
 
 
 
 chemist
 
 Very few of us are.
 
 
 
 
 
 can anyone tell me how much phenolphthalein to use on the test I have
been
 using 2 drops @ 1% phenolphthalein. The instructions from J.T.F say
use
 
 
 1%
 
 
 phenolphthalein solution (1.0w/v%). If you can please help. Thanks
Derick
 
 
 
 
 You say: The instructions from J.T.F say use 1% phenolphthalein
 solution (1.0w/v%).
 
 The instructions at JtF say: Add 2 drops of phenolphthalein solution.
 
 Dissolve 1 gm of lye in 1 litre of distilled water (0.1% w/v lye
 solution). In a smaller beaker, dissolve 1 ml of the cooled oil in 10
 ml of pure isopropyl alcohol. Warm the beaker gently by standing it
 in some hot water, stir until all the oil dissolves in the alcohol
 and turns clear. Add 2 drops of phenolphthalein solution. Using a
 graduated syringe, add 0.1% lye solution drop by drop to the
 oil-alcohol-phenolphthalein solution, stirring all the time, until
 the solution starts to turn pink and stays that way for 10 seconds.
 
 -- From: Biodiesel from waste oil
 http://journeytoforever.org/biodiesel_make.html#biodwvo
 
 See also:
 
 More about lye
 How much lye to use?
 Basic titration
 Better titration
 Accurate measurements
 pH meters
 Phenolphthalein
 pH meters vs phenolphthalein
 
 http://journeytoforever.org

Re: [Biofuel] Compost Update

2005-07-19 Thread Pieter Koole
Hello,
I would say, just put your compost on the surface. The rain as well as
little animals like worms will take it into the ground. This is also the way
it happens in natural forests.

Met vriendelijke groet,
Pieter Koole

- Original Message -
From: robert luis rabello [EMAIL PROTECTED]
To: biofuel@sustainablelists.org
Sent: Sunday, July 17, 2005 9:18 PM
Subject: [Biofuel] Compost Update


 We have a new neighbor, a friendly, English fellow who noticed that I
 was turning my compost pile this morning.  He came over, interested in
 my work, and asked several questions about composting.  We also talked
 about my garden, which is, apparently, a rather hot topic of
 discussion among the people who live around here . . .

 I think my current batch of compost is too wet.  After a couple of
 weeks in the bin, the bottom of the pile is dark brown, crumbly,
 smells like the forest floor and is crawling with worms and other
 small creatures.  However, many of the long fibers from plant roots
 and stalks haven't fully decomposed (no, I don't own a shredder!), and
 the middle of the pile looks too wet.  I've mixed in some dry material
 and put it back together, leaving it for the detritus creatures to handle.

 My questions with respect to all of this relates to digging compost
 in around my trees.  When we go about weeding, I've noticed that
 digging near the trees runs a high risk of damaging surface roots.
 How can I dig all of this compost around my trees without wrecking the
 root network?  Do I just pile the compost onto the surface and let it
 decompose further into the ground, or should I be less concerned about
 surface roots and dig the composted material into the soil around the
 drip line?  How far down should I be going?  Is this time of year the
 best time of year to be doing this, or should I save the compost for
 the fall?



 robert luis rabello
 The Edge of Justice
 Adventure for Your Mind
 http://www.authorhouse.com/BookStore/ItemDetail.aspx?bookid=9782

 Ranger Supercharger Project Page
 http://www.members.shaw.ca/rabello/



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Re: [Biofuel] Burning glycerol for heat / Acrolein

2005-07-19 Thread Pieter Koole



There is a safe way of using nitroglycerin, but I 
would say that nitroglycerine is not a toy. Don't play with it and leave the use 
of it to professionals.

Metvriendelijke groet,Pieter KooleOriginal Message - 


  From: 
  r 
  To: Biofuel@sustainablelists.org 
  
  Sent: Sunday, July 17, 2005 10:45 
PM
  Subject: Re: [Biofuel] Burning glycerol 
  for heat / Acrolein
  How about combining the glycerin with nitrogen to create 
  nitroglycerin? I know, nitrogen is explosive but so is hydrogen. 
  The engines in our vehicles are using what is called "explosion 
  propulsion". Exploding fuel pushes against pistons which are 
  linked to a shaft, which is linked to the transmission. There must be a 
  safe way to use nitroglycerin.[EMAIL PROTECTED] wrote: 
  
The chemical kinetics of fire is not understood very well. 
Smoking a cigarette will produce thousands of intermediate radicals, which 
will lead to thousands of end products, many of which are harmful. 
Altering temperature and other variables will lead to different end 
products. So unless you have empirical evidence on a specific 
substance, it's hard to know what is going to happen. I know people do 
burn it as a fuel, but I wouldn't recommend doing it in your kitchen, for 
instance.
R Del Bueno [EMAIL PROTECTED] 
wrote:
Hello 
  all,I am considering the use of my glycerol coproduct as a burner 
  fuel for process heat generation (indirect via boiler).My glycerol 
  generated while running 20% methanol is of very low viscosity (mostly 
  likely due to the excess methanol), and seems quite usable. This may 
  be more advantageous than recover when heating large batches.I 
  have been searching for emissions information on this, as I have heard 
  that toxic acrolein is produced.when glycerin is burnt at temps below 
  1800degF. (I have heard this about WVO/SVO usage as well).My 
  question is how much?...as acrolein is also produced burning gasoline, 
  diesel, and cigarettes.It seems that if the amount of acrolein 
  produced by burning the gylerol waste is LESS than the amount that 
  would be produced by burning the amount of petro diesel that is offset 
  by the biodiesel..then net amount of acrolein is still a reduction, 
  and hence acceptable.Any data out there?Any chemists out there 
  who may be able to calculate an approximation?Molecular formula C3H4O 
  (..that's little 3, little 
  4)-Rob..Info 
  on Acrolein:Acrolein is principally used as a chemical intermediate in 
  the production of acrylic acid and itsesters. Acrolein is used 
  directly as an aquatic herbicide and algicide in irrigation canals, as 
  amicrobiocide in oil wells, liquid hydrocarbon fuels, cooling-water 
  towers and water treatmentponds, and as a slimicide in the 
  manufacture of paper (IARC, 1985). Combustion of fossil 
  fuels,tobacco smoke, and pyrolyzed animal and vegetable fats 
  contribute to the environmentalprevalence of acrolein (IARC, 
  1985). Acrolein is a byproduct of fires and is one of several 
  acutetoxicants which firefighters must endure. It is also formed from 
  atmospheric reactions of 1,3-butadiene. The annual statewide 
  industrial emissions from facilities reporting under the AirToxics 
  Hot Spots Act in California based on the most recent inventory were 
  estimated to be54,565 pounds of acrolein (CARB, 
  2000).CHRONIC TOXICITY SUMMARYACROLEIN (2-propenal, 
  acraldehyde, allyl aldehyde, acryl aldehyde)CAS Registry Number: 
  107-02-8I. Chronic Toxicity SummaryInhalation reference 
  exposure level 0.06 mg/m3 (0.03 ppb)Critical effect(s) Histological 
  changes in nasal epithelium in ratsHazard index target(s) Respiratory 
  system; eyesII. Physical and Chemical Properties (HSDB, 
  1995)Description Colorless or yellow liquid with 
  piercing,disagreeable odorMolecular formula C3H4O (oops..thats 
  litte 3, little 4)Molecular weight 56.1 g/molDensity 0.843 g/cm3 @ 
  20°CBoiling point 53°CMelting point -88°CVapor pressure 220 
  torr @ 20°COdor threshold 160 ppb (370 mg/m3)(Amoore and Hautala, 
  1983)Solubility Soluble in ethanol, diethyl ether, and up to 20% w/v 
  in waterConversion factor 1 ppm = 2.3 mg/m3 @ 25° C 
  ___Biofuel 
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[Biofuel] To Andrew : Desalination

2005-06-28 Thread Pieter Koole
Hello,
I am interested in a desalination system as well. Can you provide me some
info on that ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands


- Original Message -
From: Andrew Lowe [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Monday, June 27, 2005 3:34 PM
Subject: Re: [Biofuel] Magnesol


 Chris Sommerfeld wrote:
  I manage a small biodiesel lab at a school here in the Bahamas.  We
  currently make about 250 gal a week.  Within the next month we plan to
  expand to make about 450 gal a week.  We are always looking for new ways
to
  improve our processing.  Currently we use bubble washing in the wash/dry
  stage.
 
  Water is very presious for us and I am intersted in using Magnesol
instead
  of water to purify our fuel.
 [snip]

 Just out of interest, why don't you build a small solar desalination
 system - besides the financial reasons, I thought the reason people when
 to the Bahama's was for sunshine!!! I'm sure Keith probably has
 squirreled away on JtoF plans for a low tech solar desalination system
 that would provide you with the water you need.

 If JtoF has nothing, get back to me, I know of a simple setup that
 could probably be made for a couple of hundred dollars.

 Regards,
 Andrew Lowe


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Re: [Biofuel] Reprocessing question

2005-06-28 Thread Pieter Koole



What do you mean by 90.5% KOH ? If the rest (9.5%) 
is water, that is where your problem is. With water, oil and KOH you have the 
right recepy to make soap.
Try to get the KOH or NaOH as pure as you can get 
it.
Succes.

Metvriendelijke groet,Pieter Koole


  - Original Message - 
  From: 
  Bill 
  Clark 
  To: Biofuel@sustainablelists.org 
  
  Sent: Monday, June 27, 2005 7:34 PM
  Subject: [Biofuel] Reprocessing 
  question
  
  Hi Keith and all,
  
  I made a 200 gallon batch of biodiesel last 
  Friday. I used 200 gallons of wvo, 40 gallons of methanol, and 16.5 lbs of 
  90.5% anhydrous KOH from a titration of 4.5 g/L. After draining off the 
  glycerine I took a 400 ml sample and performed a shake test.I got an emulsion. 
  I added a couple of grains of calcium chloride and a thimble of vinegar and 
  got perfect separation in about 10 minutes.
  
  As you know, I have addressed the question of 
  soft water in the wash and while the addition of calcium chloride and vinegar 
  have yet to produce a poor result, I am troubled by this initial emulsion 
  formation using plain water.
  
  Today I took 1 litre od the biodiesel and 
  reprocessed it. I used 200 ml of methanol and 5.4 grams of 90.5% KOH, 
  preheated the oil to 120 F and blended for 20 minutes. After 1 hour there was 
  no detectable settling of anything. The biodiesel remains in one phase that is 
  slightly darker than the original biodiesel and somewhat cloudy. 
  
  Does anyone think that I have a concern here or 
  am I just being paranoid?
  
  Thanks for any comments,
  
  Bill Clark
  
  

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Re: [Biofuel] Fw: Electronic PH meter

2005-06-19 Thread Pieter Koole
Hi,
Is phenolphtalein the same as phenol red ?

Met  dank en vriendelijke groet,
Pieter Koole

- Original Message -
From: bob allen [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Saturday, June 18, 2005 3:52 PM
Subject: Re: [Biofuel] Fw: Electronic PH meter


 Howdy Kieth and Willem, the issue of the use of a pH meter as opposed to
other methods for
 determination of the end point of a titration comes up from time to time.
It seems that many
 believe one really needs a pH meter.  I think not and here is why.
Although a pH meter may be more
 accurate if all the variables were tightly controlled, they're not.  How
accurately can one measure
 the 1 ml of oil? One maybe two significant digits?  If different oils have
different densities,
 (they do but small) then one should really adjust the volume of oil used
in the titration
 accordingly. Because density is a function of temperature, how accurately
does one know the
 temperature? How accurately can one prepare the titrant solution? How
accurately can one measure the
 titrant? Finally the titration is done in a nonaqueous heterogeneous
solution, hence pH isn't even
 strictly defined; pH being defined as minus the log of the hydrogen ion
concentration in water. If
 you heat the oil/isopropyl alcohol mix to get homogeneity, the hydrogen
ion concentration changes.
 (It is actually worse, it is the hydrogen ion activity, but that is
another matter.)


 Hence use of a pH meter to me is overkill.  What you get is a very precise
endpoint for a titration
 which is really fairly inaccurate, due to the aforementioned difficulties
in the volumetric
 measurements, temperature, etc.

 I use phenolphthalein to determine the endpoint.  It is quick, requires no
calibration, costs a heck
 of a lot less than a pH meter, and provides sufficient precision for the
measurement at hand.


  Hi Willem
 
  Hi all,
 
  I am slowly getting the parts together to construct a small biodiesel
  set-up
  (approx. 30 litres).
  When I told a friend recently avout my plans he gave me an electronic
PH
  meter, pen type. Accuracy is 1 decimal. He said this would replace the
  titration, but could give me no more info.
 
 
  It won't replace titration, you use it for titration. You can use
  phenolphthalein, or pH test strips, or a pH meter - whichever you use,
  titration involves measuring the pH. See:
 
  Basic titration
  Better titration
  pH meters
  Phenolphthalein
  http://journeytoforever.org/biodiesel_make2.html#titrate
 
  pH meters are best, IMO. You need to calibrate them often (get
  calibration fluid from a lab supply) and you have to look after them
  properly. There's a Technical tips link at the url above.
 
  Best wishes
 
  Keith
 
 
  Can anyone tell me if this is so and how I convert the reading to the
  amount
  of lye to be used?
 
  Best regards,
  Willem
 
 
 
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 --
 Bob Allen
 http://ozarker.org/bob

 Science is what we have learned about how to keep
 from fooling ourselves - Richard Feynman

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Re: [Biofuel] Fw: Electronic PH meter

2005-06-19 Thread Pieter Koole
Thanks Keith.

Pieter Koole

- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Sunday, June 19, 2005 2:05 PM
Subject: [Biofuel] Fw: Electronic PH meter


 Hello Pieter

 Hi,
 Is phenolphtalein the same as phenol red ?

 No.

 You've already got the link, below:

Basic titration
Better titration
pH meters
Phenolphthalein
http://journeytoforever.org/biodiesel_make2.html#titrate

 It says:

 Phenolphthalein is often confused with phenol red, obtained at
 pool supply stores and used for checking water. It's not the same
 thing, and phenol red won't really do for titrating WVO, its pH range
 isn't broad enough. It ranges from pH 6.8, at which point it's
 yellow, through orange, to a maximum of pH 8.2, red. For accurate
 titration you need to be able to measure pH 8.5.

 Phenolphthalein is colorless up to pH 8.3, then it turns pink
 (magenta), and red at its maximum of pH 10.4. When it stays pink for
 more than 10 seconds, it's measuring pH 8.5.

 With good-quality oil with low FFA levels you might just get away
 with using phenol red for titration, but for higher FFA levels it
 isn't accurate enough. Use 1% phenolphthalein solution (1.0w/v%).

 Why don't you read the whole page, Pieter? Both pages:

 http://journeytoforever.org/biodiesel_make.html
 Make your own biodiesel

 http://journeytoforever.org/biodiesel_make2.html
 Make your own biodiesel - page 2

 Keith


 Met  dank en vriendelijke groet,
 Pieter Koole
 
 - Original Message -
 From: bob allen bob at ozarker.org
 To: Biofuel at sustainablelists.org
 Sent: Saturday, June 18, 2005 3:52 PM
 Subject: Re: [Biofuel] Fw: Electronic PH meter
 
   Howdy Kieth and Willem, the issue of the use of a pH meter as opposed
to
 other methods for
   determination of the end point of a titration comes up from time to
time.
 It seems that many
   believe one really needs a pH meter.  I think not and here is why.
 Although a pH meter may be more
   accurate if all the variables were tightly controlled, they're not.
How
 accurately can one measure
   the 1 ml of oil? One maybe two significant digits?  If different oils
have
 different densities,
   (they do but small) then one should really adjust the volume of oil
used
 in the titration
   accordingly. Because density is a function of temperature, how
accurately
 does one know the
   temperature? How accurately can one prepare the titrant solution? How
 accurately can one measure the
   titrant? Finally the titration is done in a nonaqueous heterogeneous
 solution, hence pH isn't even
   strictly defined; pH being defined as minus the log of the hydrogen
ion
 concentration in water. If
   you heat the oil/isopropyl alcohol mix to get homogeneity, the
hydrogen
 ion concentration changes.
   (It is actually worse, it is the hydrogen ion activity, but that is
 another matter.)
  
  
   Hence use of a pH meter to me is overkill.  What you get is a very
precise
 endpoint for a titration
   which is really fairly inaccurate, due to the aforementioned
difficulties
 in the volumetric
   measurements, temperature, etc.
  
   I use phenolphthalein to determine the endpoint.  It is quick,
requires no
 calibration, costs a heck
   of a lot less than a pH meter, and provides sufficient precision for
the
 measurement at hand.
  
  
Hi Willem
   
Hi all,
   
I am slowly getting the parts together to construct a small
biodiesel
set-up
(approx. 30 litres).
When I told a friend recently avout my plans he gave me an
electronic
 PH
meter, pen type. Accuracy is 1 decimal. He said this would replace
the
titration, but could give me no more info.
   
   
It won't replace titration, you use it for titration. You can use
phenolphthalein, or pH test strips, or a pH meter - whichever you
use,
titration involves measuring the pH. See:
   
Basic titration
Better titration
pH meters
Phenolphthalein
http://journeytoforever.org/biodiesel_make2.html#titrate
   
pH meters are best, IMO. You need to calibrate them often (get
calibration fluid from a lab supply) and you have to look after them
properly. There's a Technical tips link at the url above.
   
Best wishes
   
Keith
   
   
Can anyone tell me if this is so and how I convert the reading to
the
amount
of lye to be used?
   
Best regards,
Willem
   


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Re: [Biofuel] Dewatering WVO with vacuum and heat

2005-05-15 Thread Pieter Koole

Thank you, I'll have a look round.

Met  dank en vriendelijke groet,
Pieter Koole

- Original Message - 
From: des [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Saturday, May 14, 2005 1:36 PM
Subject: Re: [Biofuel] Dewatering WVO with vacuum and heat


 Pieter Koole wrote:
 
 Where does one find a vacuumpump ?
 
 Met  dank en vriendelijke groet,
 Pieter Koole
   
 
 They are used regularly in garages that work on airconditioning systems 
 in cars, also used in home airconditioning systems, refrigerators, 
 freezers...  They are used to remove water from the refrigerant systems 
 during repairs.  I've seen them on eBay.
 
 doug swanson
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Re: [Biofuel] Dewatering WVO with vacuum and heat

2005-05-15 Thread Pieter Koole

Thank you.
Does anyone know how much vacuum is created by a fridge pump ?
I would think that if you can create enough vacuum , maybe with another type
of pump, it should be possible to distill water out of oil, or make =90%
ethanol at room temperature.


Met  dank en vriendelijke groet,
Pieter Koole

- Original Message -
From: [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Sunday, May 15, 2005 1:23 AM
Subject: Re: [Biofuel] Dewatering WVO with vacuum and heat


You can find one from an old fridge...
The compressor. Black thingie...
Mine cort me about 3$ at the junk yard.

You can use it for sucking and pumping...

Teoman
-- original message --
Subject: Re: [Biofuel] Dewatering WVO with vacuum and heat
From: Pieter Koole [EMAIL PROTECTED]
Date: 14th May 2005 9:41:42

Where does one find a vacuumpump ?

Met  dank en vriendelijke groet,
Pieter Koole

- Original Message -
From: R Del Bueno [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Saturday, May 14, 2005 2:15 AM
Subject: Re: [Biofuel] Dewatering WVO with vacuum and heat


 So today I hooked up a water heater as a dewatering/vacuum boiler.
 The 40 gallon electric water heater held 26 of vacuum all afternoon.

 Will post details of actual dewatering soon.
 -Rob

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Re: [Biofuel] Dewatering WVO with vacuum and heat

2005-05-14 Thread Pieter Koole

Where does one find a vacuumpump ?

Met  dank en vriendelijke groet,
Pieter Koole

- Original Message - 
From: R Del Bueno [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Saturday, May 14, 2005 2:15 AM
Subject: Re: [Biofuel] Dewatering WVO with vacuum and heat


 So today I hooked up a water heater as a dewatering/vacuum boiler.
 The 40 gallon electric water heater held 26 of vacuum all afternoon.
 
 Will post details of actual dewatering soon.
 -Rob
 
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Re: [Biofuel] Dewatering WVO with vacuum and heat

2005-05-13 Thread Pieter Koole

Vapor pressure at 140 F for water is 150 mm Hg or equiv of 24 in vacuum but
you will need to go

Isn't the normal atmospheric pressure 76 mm HG ??
If yes, I don't understand what is written above.
If no, I also don't understand.
Is it possible to give a little explanation ? (because I have been thinking
on this subject also ).
Is there a table or so, where one can find at what pressures water boils ?



Pieter Koole
Netherlands

- Original Message -
From: [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Thursday, May 12, 2005 11:48 PM
Subject: Re: [Biofuel] Dewatering WVO with vacuum and heat







Rob,  I think a water heater will stand the vacuum easily since it is at the
most 15 PSI compression on the steel, compared to 150 or more in tension
when in normal use.  Not sure it will save energy.  Vapor pressure at 140 F
for water is 150 mm Hg or equiv of 24 in vacuum but you will need to go
lower  to get the water to burst into foamy bubbles. (or higher temp)
Probably will be easier on the oil, than doing it at atmospheric
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Re: [Biofuel] Dewatering WVO with vacuum and heat

2005-05-13 Thread Pieter Koole

 Normal atmospheric pressure is 760 mm or 76 cm or 30 inches.   150 mm is
about 150/760 atmospheres absolute.
 24'Vacuum is 30 minus (150mm/25.4mm/in)

 Handbook of chemistry and physics, crc publishing or probably many places
on the net.

 google vapor pressure of water.



Of course. I new that. Stupid me !
Sorry.

Pieter Koole



- Original Message -
From: [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Friday, May 13, 2005 3:24 AM
Subject: Re: [Biofuel] Dewatering WVO with vacuum and heat






 Normal atmospheric pressure is 760 mm or 76 cm or 30 inches.   150 mm is
about 150/760 atmospheres absolute.
 24'Vacuum is 30 minus (150mm/25.4mm/in)

 Handbook of chemistry and physics, crc publishing or probably many places
on the net.

 google vapor pressure of water.



   Pieter Koole
   [EMAIL PROTECTED] To:  [EMAIL PROTECTED]
   t.nlcc:
   Sent by: Subject: Re: [Biofuel]
Dewatering WVO with vacuum and heat
   biofuel-bounces@
   wwia.org


   05/12/2005 04:26
   PM
   Please respond
   to biofuel




 Vapor pressure at 140 F for water is 150 mm Hg or equiv of 24 in vacuum
but
 you will need to go

 Isn't the normal atmospheric pressure 76 mm HG ??
 If yes, I don't understand what is written above.
 If no, I also don't understand.
 Is it possible to give a little explanation ? (because I have been
thinking
 on this subject also ).
 Is there a table or so, where one can find at what pressures water boils ?



 Pieter Koole
 Netherlands

 - Original Message -
 From: [EMAIL PROTECTED]
 To: [EMAIL PROTECTED]
 Sent: Thursday, May 12, 2005 11:48 PM
 Subject: Re: [Biofuel] Dewatering WVO with vacuum and heat







 Rob,  I think a water heater will stand the vacuum easily since it is at
the
 most 15 PSI compression on the steel, compared to 150 or more in tension
 when in normal use.  Not sure it will save energy.  Vapor pressure at 140
F
 for water is 150 mm Hg or equiv of 24 in vacuum but you will need to go
 lower  to get the water to burst into foamy bubbles. (or higher temp)
 Probably will be easier on the oil, than doing it at atmospheric
 pressure.___
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Re: [Biofuel] Stir vs Pump Processing

2005-05-11 Thread Pieter Koole

Hi Ken,
My experience with pump mixing is ok, but I think you bring more oxygin in
the mixture with pump mixing when you let the incoming stream (so coming
from the pump) which I did, above the top of the mixture. That causes a
layer of high oxygin glycerin(?) floating on top of the BD. This
glycerin - I am not sure wheather it is glycerin - is loss of product.
Whith mixing or pumping, I would think the energy use is about the same. At
this moment I use the electromotor of my previous pump as a stirring motor.
Maybe the place where to put your mixing device is important to make sure
you are not only moving around the whole lot, but realy to a proper mixing.
I found that puting the spoon(?) on about one-third from the edge.

Sorry about my probably terrible English at the moment. I have been speaking
German all day, which is also not my mother's language.

Met  dank en vriendelijke groet,
Pieter Koole

- Original Message -
From: Ken Dunn [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Tuesday, May 10, 2005 1:13 PM
Subject: [Biofuel] Stir vs Pump Processing


 Hi all,

 I'm trying to determine which method, stirring or pumping, will consume
 less elctricity before I make my processor.  Obviously, it depends on
 the equipment employed but, in theory.  It sounds like reaction
 times are shorter with stirring than with pump mixing.  Likewise, from
 what I read, it appears that stirring provides a more reliable
 reaction.  It also seems like more people use pumps to mix their brew
 but, it also appears that there are more problems with pumping than with
 stirring -  maybe this is a miscalculation on my part, though.  And
 maybe it is just an indication that most everyone uses pump hence the
 greater trouble available to be found.

 Thanks in advance,
 Ken
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Re: [Biofuel] Questions about ethanol

2005-05-09 Thread Pieter Koole

Thank you.
No, I don't mean methanol. I mean ethanol, fermented out of the sugars from
cellulose is build up.
When you break cellulose, you get sugars as far as I understand.
Tomorrow I have some more time to write down the details so far.

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

- Original Message -
From: Dean Thomas [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Sunday, May 08, 2005 3:01 PM
Subject: Re: [Biofuel] Questions about ethanol


 Hi Pieter,

 Sorry I could be mistaken there is always something new to learn but do
 you mean methanol instead of ethanol. Methanol is otherwise known as
 wood alcohol and a small amount is formed during on the grain
 fermentation during the making of alcohol (Ethanol) beverages the Grain
 husks being the wood part. Not noing any better or of it is even
 possible I would imagine that the only alcohol able to be formed from
 sawdust could be methanol.
 To make ethanol you ferment sugars.
 To work out the Ethanol content of ethanol/water mix, at any local
 home-brew shop you can purchase hydrometers. Beer/wine hydrometers are
 good up to 20% Spirit hydrometers are good up to 100% about the best you
 can hope for at home is 95-96%.

 Dean.

 Pieter Koole wrote:

 Hi all,
 I would like to give it another try to make ethanol from sawdust or other
 cellulose materials.
 In the past I have tried Sawdust ethanol production which I read
somewhere
 I think on JTF, but didn't succeed.
 Well, IF I succeed this time, how can I now the % of ethanol and water ?
 I have zeolite, so I should be able to dry the ethanol. Can I measure the
 gravity to be sure enough I have 100% ethanol ?
 Would zeolite also adsorbe the alcohol ? If yes, what to do ? Drying the
 zeolite would cause loss of ethanol.or ??
 Any advice on making ethanol from sawdust or newspapers would be very
 welcome.
 
 Another - maybe stupid - question :
 Sometimes I read snip in the messages. What does that mean ?
 
 Met  dank en vriendelijke groet,
 Pieter Koole
 Netherlands
 
 
 
 
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Re: [Biofuel] A nice experience

2005-05-08 Thread Pieter Koole

Thanks for your answer.
What other problems can it cause, exept for a bad start on cold mornings ?
I used 40 liters of phosphoric acid on 1000 liters of glop.
Of course first I made some mini batches to find out wether it would work
and figured out that I needed about 40 liters of 75% of acid.

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands
- Original Message -
From: Kenneth Kron (CEO) [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Saturday, May 07, 2005 4:28 PM
Subject: Re: [Biofuel] A nice experience


 That's right Pieter, the phosphoric acid cracked the soap back into
 FFA's.  In small quantities it wont hurt anything in large quantities it
 will hurt something.  In the netherlands your primary problem is
 probably that FFA's will drive up you jell point on you wont be able to
 start your car on a cold morning.

 If you knew how much phosphoric you used you could guess *at the FFA
 content of your fuel *of FFA's your running on.  If you acid treated the
 glycerin and knew how much FFA's you got out of that you'd have another
 guess the FFA content of your fuel.

 kk

 Pieter Koole wrote:

 Some time ago I wrote about my mistake, to not boil off the water out of
 wvo, so I finished up with a lump of soap, glop or whatever we can call
it.
 Alltogether it was 1000 liters. Now I decided to try to break the soap
with
 phosphoric acit (75%) and let it sit for several weeks. The soap was
cracked
 and I was lucky to siphon from the top just over 700 liters of BD. I have
 been driving on it, without any problems.
 Maybe someone out there can do something with this information.
 I have been thinking that I might be driving on FFA's at the moment in
stead
 of BD, but it works.
 
 Met vriendelijke groet,
 Pieter Koole
 Netherlands.
 
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 --
 Kenneth Kron
 President Bay Area Biofuel
 http://www.bayareabiofuel.com/
 [EMAIL PROTECTED]
 Phone: 415-867-8067
 What you can do, or dream you can do, begin it!
 Boldness has genius, power and magic in it.
 Johann Wolfgang von Goethe http://en.wikipedia.org/wiki/Faust.


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Re: [Biofuel] A nice experience

2005-05-08 Thread Pieter Koole

I don't know much about viscosity. How can I measure it ? What should be the
viscosity of BD ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands
- Original Message -
From: Ken Provost [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Sunday, May 08, 2005 1:05 AM
Subject: Re: [Biofuel] A nice experience


 on 5/7/05 9:00 AM, Pedro Ordonez at [EMAIL PROTECTED] wrote:



  This is a question I've had for a while now. If the purpose of making
  Biodiesel is to lower the viscosity of the oil, what would happen if we
used
  just free fatty acids? Why won't that work?
 
 


 Have you checked the viscosity of FFA (take oleic acid as an example)?
 The stuff I've made felt like about 28 centistokes :-) Thinner than oil
 to be sure, but not thin enough.

 -K

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[Biofuel] Questions about ethanol

2005-05-08 Thread Pieter Koole

Hi all,
I would like to give it another try to make ethanol from sawdust or other
cellulose materials.
In the past I have tried Sawdust ethanol production which I read somewhere
I think on JTF, but didn't succeed.
Well, IF I succeed this time, how can I now the % of ethanol and water ?
I have zeolite, so I should be able to dry the ethanol. Can I measure the
gravity to be sure enough I have 100% ethanol ?
Would zeolite also adsorbe the alcohol ? If yes, what to do ? Drying the
zeolite would cause loss of ethanol.or ??
Any advice on making ethanol from sawdust or newspapers would be very
welcome.

Another - maybe stupid - question :
Sometimes I read snip in the messages. What does that mean ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands




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[Biofuel] Question about BD

2005-05-08 Thread Pieter Koole

Hello all,
Maybe a silly question, but I cannot figure out how it works really.
As far as I understand, veg.oil exists out of a glycerol + 3 fatty acids,
like a head with 3 legs.
During the BD proces, we break off the legs, using NaOH, and connect a
methanol molecule on each leg.
When we break off the legs, I would think we have free legs, so free fatty
acids.
What mistakes do I make when I think this is how it works ?
So, if this is how it works (which is prob. not the case), why do we worry
about free fatty acids ? I would say that we only would need less lye,
because the legs are already lose.

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands




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[Biofuel] A nice experience

2005-05-07 Thread Pieter Koole

Some time ago I wrote about my mistake, to not boil off the water out of
wvo, so I finished up with a lump of soap, glop or whatever we can call it.
Alltogether it was 1000 liters. Now I decided to try to break the soap with
phosphoric acit (75%) and let it sit for several weeks. The soap was cracked
and I was lucky to siphon from the top just over 700 liters of BD. I have
been driving on it, without any problems.
Maybe someone out there can do something with this information.
I have been thinking that I might be driving on FFA's at the moment in stead
of BD, but it works.

Met vriendelijke groet,
Pieter Koole
Netherlands.

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Re: [Biofuel] pore size of a paper coffee filter

2005-05-03 Thread Pieter Koole

Yes, they have the good filtration properties for BD, but the manufacturer
does not guarantee anything.

Met vriendelijke groet,
Pieter Koole
: [Biofuel] pore size of a paper coffee filter


 Hi Everyone,

 I was wondering if any list member has an idea of the pore size of a paper
coffee filter. I use these to filter out larger particles in my BD before
going to final filtration.

 As always any suggestions, guidence, advice, or critisisms all welcome.

 Respectfully,
 Gregg Davidson

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Re: [Biofuel] hydrogen fire place

2005-04-26 Thread Pieter Koole

Hi Greg,
If I where you, I would be a little more carefull, telling people that try
to find environmentle friendly ways of heating their house, that what they
say is a joke.
Making H2 costs energy, but as long as you can make H2 from a free source,
like the sun is, what is the problem ? Even if the yield would only be 5%,
you still catch these 5% in stead of letting it go.
By the way, I didn't know the bridge in San Francisco was yours.

Met vriendelijke groet,
Pieter Koole
Netherlands

- Original Message -
From: Greg Harbican [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Monday, April 25, 2005 4:46 PM
Subject: Re: [Biofuel] hydrogen fire place


 And how much more energy is going to be wasted, generating all the
necessary
 H2?

 What a joke.

 If anyone want to buy the fireplace, I want to know, I have a bridge to
sell
 them, in San Francisco CA.

 Greg H.


 - Original Message -
 From: Alt.EnergyNetwork [EMAIL PROTECTED]
 To: [EMAIL PROTECTED]
 Sent: Monday, April 25, 2005 03:02
 Subject: [Biofuel] hydrogen fire place


 
 
  Hi all,
  This is interesting - a hydrogen fireplace. Uses standard
  electrolysis of water.
  You still have to use electricity for it to work so it is definately
  not free heat but it doesn't need any venting so it can be easily
 installed.
  Company states output at around 31,000 btu's.
  It is a pretty simple idea so I expect it won't be long before quite
  a few clones will be available.
  Certainly doesn't help solve the energy crisis though it will burn
  clean and has the option of adding the oxygen to the room air.
 
  The world's first hydrogen-burning fireplace launches next generation
  of hearth products
 
  http://www.heatnglo.com/news/pressrelease.asp?id=33
 
 
 
  Get your daily alternative energy news
 
  http://groups.yahoo.com/group/next_generation_grid
 
   news  resources  forums
 
  http://groups.yahoo.com/group/tomorrow-energy
 
 
 
  Alternative Energy Politics
 
  http://groups.yahoo.com/group/Alternative_Energy_Politics/
 
 
  Alternate Energy Resource Network
1000+ news sources resources
   updated daily
  http://www.alternate-energy.net
 
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[Biofuel] To Jan Lieuwe Bolding

2005-04-19 Thread Pieter Koole

Hoi Jan,
Can you tell me where you bought the stuff in Ittervoort to get the BD
winterresistant to 15¡ C below zero ?

Met  dank en vriendelijke groet,
Pieter Koole
Struiken 3
5993 NA Maasbree
077 - 465 1533
06 - 1339 1428
[EMAIL PROTECTED]


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- Original Message -
From: Jan Lieuwe Bolding [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Sunday, April 10, 2005 1:25 PM
Subject: Re: [Biofuel] Sunflower Oil


 At the moment I use used frying oil, but the main problem is that this
 already starts to solidify at about 15 ¡C.

 I have had a can of Sunflower Oil standing outside during the winter and
It
 staid liquid even at temperatures at -15 ¡C.

 I also hope to produce a BD that I can also use during winter time.


 With kind regards,



 Jan Lieuwe Bolding
 The Netherlands
 - Original Message -
 From: Ken Provost [EMAIL PROTECTED]
 To: [EMAIL PROTECTED]
 Sent: Friday, April 08, 2005 10:07 PM
 Subject: Re: [Biofuel] Sunflower Oil


 
  On Apr 8, 2005, at 10:47 AM, Jan Lieuwe Bolding wrote:
 
   Has anyone experience with Straight Sunflower Oil to produce
BioDiesel?
  
  
 
  I bought my oilseed ram press from Tanzania largely for sunflower
  and safflower (tho it does a fine job on flax and yellow mustard as
  well).
  They all make fine biodiesel. Did you have some specific concerns?
  Really almost any seed oil will make excellent fuel.
 
  -K
 
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Re: [Biofuel] wind powered water pumps

2005-03-26 Thread Pieter Koole

Hello Kim.
I live in the Netherlands and as you perhaps know, our country is below
sealevel. In the past we won land from the North Sea.
At ECN in Petten (Energie Centrum Nederland) they can surely provide you
with information, or they at least know where you can get it.
Succes.

Met vriendelijke groet,
Pieter Koole
Netherlands
- Original Message -
From: Kim  Garth Travis [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Wednesday, March 23, 2005 5:17 PM
Subject: [Biofuel] wind powered water pumps


 Greetings,
 I have been through all my reference books, etc. and I can not find any
 information on wind powered water pumps.  Does any one have the directions
 for building one?  What are they capable of and other such information
will
 be appreciated.
 Bright Blessings,
 Kim

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Re: [Biofuel] wind powered water pumps

2005-03-26 Thread Pieter Koole

Sorry, I forgot :
You can find ECN on the internet.
Probably it is www.ECN.nl

Pieter Koole

- Original Message -
From: Kim  Garth Travis [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Wednesday, March 23, 2005 5:17 PM
Subject: [Biofuel] wind powered water pumps


 Greetings,
 I have been through all my reference books, etc. and I can not find any
 information on wind powered water pumps.  Does any one have the directions
 for building one?  What are they capable of and other such information
will
 be appreciated.
 Bright Blessings,
 Kim

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Re: [Biofuel] freezer test

2005-03-07 Thread Pieter Koole

Thank you for doing this test.
I just wanted to do the same sort of test.
By the way, does anybody know why the additives which are used for petro
diesel are no good for use in BD ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

: Brent S [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Sunday, March 06, 2005 4:22 PM
Subject: [Biofuel] freezer test


 I just did a test with some winter diesel and bio diesel blends. I did a
 50%, 33%, and a 20% blend. At -20c the 50% got thick but didn't solidify
or
 sepparate, and the other two were ok.

 Are these results consistant with what is expected from a good home brew
 fuel?

 Brent
 Saskatchewan Canada

 91 GMC 6.2


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Re: [Biofuel] freezer test

2005-03-07 Thread Pieter Koole

What do you mean with Howes ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

- Original Message -
From: John Wilson [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Monday, March 07, 2005 7:08 PM
Subject: [Biofuel] freezer test


 I just did a test with some winter diesel and bio diesel blends. I did a
 50%, 33%, and a 20% blend. At -20c the 50% got thick but didn't solidify
or
 sepparate, and the other two were ok.

 (reply)
 Try adding a little of Howes diesel tret it works great with WVO but
haven't
 tried adding  Howes to Bio.
 Yours truly
 John Wilson
 Goldens
 ***
 Wilsonia Farm Kennel Preserve

 Email: [EMAIL PROTECTED]
 Ph-Fax (902)665-2386)

 Web: http://www3.ns.sympatico.ca/goldens/new.htm
 Pups: http://www3.ns.sympatico.ca/goldens/pup.htm
 Politics: http://www3.ns.sympatico.ca/goldens/elect.htm
   http://www3.ns.sympatico.ca/goldens/c68.htm


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 After 9:00 it is okey to kill everyone.



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[Biofuel] Could this be an idea ?

2005-03-02 Thread Pieter Koole

Hi all.
Some days ago I wrote about a failure batch (water and / or soap in it).
I have been reading about making soap and found that when soap is made,
sometimes they boil the fresh soap with a saturated NaCl solution, which
separates the soap from the rest (what rest ? I don't know).
I tried to boil a sample of BD with a solution as said and so far the BD
looks to become some clearer.

Does anyone know if this salt would solube (or solve ? How does one say that
?) in the BD ?
I can imagion that this would not be very pleasant for the fuelsystem of the
engine.

By the way, I have tried it with different amounts of water with salt,
varying from just salt and no water, to the same amount of water as BD, with
the maximum amount of salt solved in it.
If wanted, I'll keep you informed.

Met vriendelijke groet,
Pieter Koole
Netherlands

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Re: [Biofuel] Question

2005-02-23 Thread Pieter Koole

Thank you.

Met  dank en vriendelijke groet,
Pieter Koole

- Original Message -
From: Paddy O'Reilly [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Tuesday, February 22, 2005 6:56 PM
Subject: Re: [Biofuel] Question


 Pieter,

 The word you are looking for could be Angstrom which is one tenth of a
 nanometer. It is used mainly in chemistry and sometimes in electronics.

 Paddy.

 Pieter Koole wrote:

 Hello dear all,
 Can anyone tell me how to find out what is glycerin, soap or solid BD ?
 Recently I made a few batches of BD from a very poor quality WVO.( about
one
 I already wrote; it was with water in it, which was of course my
mistake ).
 At the moment it is winter in Holland and the temp is around zero ¡ C.
 The BD turns to a mixture of solid and liquid and I don't know what is
 what. When I filter it and put the liquid part in the tank, it is ok, but
 the solid part is about half of the whole lot. I don't realy trust this
part
 enough to put in my tank in the summer, because it might be glyc or even
 soap or a mixture of the both (even mixed with solid BD ).
 Any help or advice would be very welcome.
 
  Something about the mistake I made : I made BD in a tank where there was
 some water in. The BD did not get clear, but like coffee with milk. I
washed
 a one liter sample about 20 times now, and it is getting coffee with even
 more milk. The water at the bottom is clear now, but I am getting a
little
 less BD after every time I washed it. Do you think I should turn the
whole
 lot into soap, or is there any other solution thinkable ( I can imagion
 something with zeolite, but still I have not found any place where I can
buy
 this stuff ( as far as I know I would need 3  )).
 By the way,  is an old fashioned something (what is the word ?).
 These days it is written as 1.10 » meter, where a is -10 in this case.
 
 
 Met vriendelijke groet,
 Pieter Koole
 Netherlands.
 
 
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[Biofuel] Question

2005-02-22 Thread Pieter Koole

Hello dear all,
Can anyone tell me how to find out what is glycerin, soap or solid BD ?
Recently I made a few batches of BD from a very poor quality WVO.( about one
I already wrote; it was with water in it, which was of course my mistake ).
At the moment it is winter in Holland and the temp is around zero ¡ C.
The BD turns to a mixture of solid and liquid and I don't know what is
what. When I filter it and put the liquid part in the tank, it is ok, but
the solid part is about half of the whole lot. I don't realy trust this part
enough to put in my tank in the summer, because it might be glyc or even
soap or a mixture of the both (even mixed with solid BD ).
Any help or advice would be very welcome.

 Something about the mistake I made : I made BD in a tank where there was
some water in. The BD did not get clear, but like coffee with milk. I washed
a one liter sample about 20 times now, and it is getting coffee with even
more milk. The water at the bottom is clear now, but I am getting a little
less BD after every time I washed it. Do you think I should turn the whole
lot into soap, or is there any other solution thinkable ( I can imagion
something with zeolite, but still I have not found any place where I can buy
this stuff ( as far as I know I would need 3  )).
By the way,  is an old fashioned something (what is the word ?).
These days it is written as 1.10 » meter, where a is -10 in this case.


Met vriendelijke groet,
Pieter Koole
Netherlands.


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Re: [Biofuel] WVO in central heating burners

2005-02-21 Thread Pieter Koole

Thank you.

Met vriendelijke groet,
Pieter Koole

- Original Message -
From: Simon Fowler [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Sunday, February 20, 2005 11:26 AM
Subject: Re: [Biofuel] WVO in central heating burners


Your  draaibank is nearly the same in German. Near enough to understand
anyway. Just for the record, we call it a Drehbank, or lathe in English.

Simon

Message: 4
Date: Sat, 19 Feb 2005 15:28:39 +0100
From: Pieter Koole [EMAIL PROTECTED]
Subject: Re: [Biofuel] WVO in central heating burners
To: [EMAIL PROTECTED]
Message-ID: [EMAIL PROTECTED]
Content-Type: text/plain; charset=iso-8859-1

Yes, I did the same.
Use stainless steel and your problems will be gone forever.
You can maybe make them by yourself on what we call a draaibank ( I really
don't know the English or German word).
Stainless steel lasts forever.

Met vriendelijke groet,
Pieter Koole

- Original Message -
From: Andreas W Ohnsorge [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Friday, February 18, 2005 12:38 PM
Subject: [Biofuel] WVO in central heating burners


 Currently I am running my central heating on WVO in a modified Mannesman
 (blue) burner. Modified because the material used in the nozzle, the
 filter and in the pre-heater (sintered bronze, brass) oxidizes over time
 and cloggs the nozzle.

 Because of these problems I have been speaking to several experts from the
 nozzle / pump / burner producers and they told me that I should get rid of
 all devices that contain copper in any form (means: housings of filters,
 valves, pipes,...) which I am currently doing.

 In addition their comment was that in some of their long term experiments
 even iron seemed to corrode under the influence of the organic acids of
 vegetable oil.

 Does anyone out there has any knowledge where to get the proper equipment
 that is suitable for such an operation (means heat resitant up to 120 -
 150 degrees Celsius, resistant against organic acids, works with pressures
 of about 20 - 30 bar - and: is not too expensive)?

 I would really appreciate a discussion about experiences in this area...

 Regards

 Andreas

 P.S: I am living in Germany


 Abraham-Lincoln-Park 1
 65189 Wiesbaden
 Germany
 Phone: +49.611.142.22608
 Fax: +49.611.142.980028
 Mobile: +49 172 - 8 43 30 32
 e-Mail: [EMAIL PROTECTED]
 Internet:

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[Biofuel] To Hans from Belgium

2005-02-20 Thread Pieter Koole

Hoi Hans,
Hier zijn mijn gegevens.
Ik ben momenteel met wat grotere plannen bezig.
Misschien kan ik je daarover bellen ?

Met vriendelijke groet,
Pieter Koole
Struiken 3
5993 NA Maasbree
Netherlands
077 - 465 1533
06 - 1339 1428
[EMAIL PROTECTED]




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Re: [Biofuel] Soap aerated concrete

2005-02-20 Thread Pieter Koole

What is Perlite ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

- Original Message -
From: Martin K [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Friday, February 18, 2005 11:46 PM
Subject: Re: [Biofuel] Soap  aerated concrete




 Keith Addison wrote:
  Hi Martin
 
  Hi Keith et al,
  I used Perlite mixed with refractory cement in my aluminum casting
  furnace. The walls saw temperatures surpassing 2000F, it was working
  well. The mixture was 50/50, and the perlite is very light-weight,
  reducing the overall mass of the structure.
  --
  Martin K
 
 
  Perlite gives very similar results to rice husk ash. Michael Allen and I
  discussed Perlite in this context when I made that page on rice husk
  ash. You used the same ratio of cement as I do with RHA, after trying it
  20 different ways in tests.
 
  Regards
 
  Keith
 

 I wouldn't mind using RHA for such a thing, but I don't think I'm within
 1000 miles of a rice field.


 --
 Martin K
 http://wwia.org/sgroup/biofuel/
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[Biofuel] Please, who can give me advise

2005-02-19 Thread Pieter Koole

Hello,
As usual, some days ago I made 1000 liters of BD.
I always boil off the water, and so I did this time.
After that, I pumped it in a big tank and made BD as I always do.
This time, however, there has probably been some water in the tank. I must 
admit that I didn't check.
Now the BD is a bit milky, well, not quit as white as milk, but like coffee 
with some milk in it and not clear at all. No way you can look through it.
I tried to boil off the water ( just a sample of one liter BD ), but the whole 
sample turned to gel.
Does anyone have a good solution for this ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands


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Re: [Biofuel] WVO in central heating burners

2005-02-19 Thread Pieter Koole

Yes, I did the same.
Use stainless steel and your problems will be gone forever.
You can maybe make them by yourself on what we call a draaibank ( I really
don't know the English or German word).
Stainless steel lasts forever.

Met vriendelijke groet,
Pieter Koole

- Original Message -
From: Andreas W Ohnsorge [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Friday, February 18, 2005 12:38 PM
Subject: [Biofuel] WVO in central heating burners


 Currently I am running my central heating on WVO in a modified Mannesman
 (blue) burner. Modified because the material used in the nozzle, the
 filter and in the pre-heater (sintered bronze, brass) oxidizes over time
 and cloggs the nozzle.

 Because of these problems I have been speaking to several experts from the
 nozzle / pump / burner producers and they told me that I should get rid of
 all devices that contain copper in any form (means: housings of filters,
 valves, pipes,...) which I am currently doing.

 In addition their comment was that in some of their long term experiments
 even iron seemed to corrode under the influence of the organic acids of
 vegetable oil.

 Does anyone out there has any knowledge where to get the proper equipment
 that is suitable for such an operation (means heat resitant up to 120 -
 150 degrees Celsius, resistant against organic acids, works with pressures
 of about 20 - 30 bar - and: is not too expensive)?

 I would really appreciate a discussion about experiences in this area...

 Regards

 Andreas

 P.S: I am living in Germany


 Abraham-Lincoln-Park 1
 65189 Wiesbaden
 Germany
 Phone: +49.611.142.22608
 Fax: +49.611.142.980028
 Mobile: +49 172 - 8 43 30 32
 e-Mail: [EMAIL PROTECTED]
 Internet:

 Experience Results. Experience CSC.


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 Keith Addison keith
 @journeytoforever.org
 Sent by: biofuel-bounces
 17.02.2005 21:34
 Please respond to biofuel

 To: [EMAIL PROTECTED]
 cc:
 Subject:Re: [Biofuel] Transesterification versus
 solvent/filtering methods


 Hello Chris

 Been having a look over www.bio-power.co.uk. The process they are
 using is based on adding solvents and filtering  settling the oils
 into a product suitable for road fuel. The process seems to produce
 little waste and uses no dangerous chemicals. What are your views on
 this method as oppose to transesterification? This method does at
 first glance have its appeals but I am wondering about possible
 disadvantages.

 Hm, yes. John Nicholson's operation. This is what it says about it at
 our website:

 ... A variation on this theme is adding a solvent to the veg oil to
 lower the viscosity -- usually 3% white spirit (a.k.a. mineral
 turpentine, Stoddard solvent, turpentine substitute). This raised a
 lot of interest after it was publicized on a British TV program --
 just add a spoonful. It also raised a lot of scepticism:
 'experimental' at best was the view of experienced SVO'ers, and
 steer well clear unless you have a 5-cyl IDI Mercedes (in which
 case you don't even need the white spirit). We agree. Work on blends
 of SVO with other solvents, such as butanol and ethanol, is still
 experimental. By all means go ahead and experiment, but there are no
 guarantees.
 http://journeytoforever.org/biodiesel_make.html#1mixing

 The experienced SVO'ers were Biofuel list members, and some of them
 were much ruder than that about it.

 I haven't followed it closely (not very interested), but we do get a
 lot of input and feedbck and I think if there'd been some
 revolutionary development I'd probably have heard of it.

 However, have a look at Darren's site, which will have a more
 thorough and up-to-date treatment of it:

 Vegetable Oil as a Fuel by Darren Hill -- book-length online
 report, mainly UK-based: The Diesel Engine, Theory of Vegetable Oil
 Use as a Fuel, Engine suitability, Heating the Oil, Biodiesel, Micro
 Emulsions and Blends, Vegetable Oil Engine Design, Vegetable Oil
 Furnaces and Heaters, Oil Types and Filtering, Taxation, Implications
 of Vegetable Oil Fuel Use, Sources. Darren welcomes contributions
 from users.
 http://www.vegburner.co.uk/report.html

 Best wishes

 Keith

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Re: [Biofuel] Transesterification versus solvent/filtering methods

2005-02-18 Thread Pieter Koole

Hi all,
I noticed on the page www.bio-power.co.uk that all the bleu, underlinded
words make the impression it is a very commercial institute. All sorts of
words like join us, how to become a member etc. but I didn't read
anything about the process from which we can learn.

Met vriendelijke groet,
Pieter
Netherlands
- Original Message -
From: Chris Bennett [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Thursday, February 17, 2005 8:02 PM
Subject: [Biofuel] Transesterification versus solvent/filtering methods


 Been having a look over www.bio-power.co.uk. The process they are using
 is based on adding solvents and filtering  settling the oils into a
 product suitable for road fuel. The process seems to produce little
 waste and uses no dangerous chemicals. What are your views on this
 method as oppose to transesterification? This method does at first
 glance have its appeals but I am wondering about possible disadvantages.
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[Biofuel] Soap

2005-02-13 Thread Pieter Koole

Hi all,
The more I read the messages about soap making, the more I realize that I
don't understand the principle of soap making.
Can anybody tell me (or give a link) what exactly is saponification ? Do
only the FFA's saponify, or the total oil ?
If this saponification is well known, why isn't it possible to find out how
much lye is needed in an unknown oil (mixture) like WVO ? If somebody ever
found out
how much lye one needs to saponify (is that the right word ?) for example
olive oil, how did he or she do that ? Can't we replicate that method with a
mixture of used oils ?
Mike wrote that coconut oil could dry out the skin if used to much. Why does
it do that ? What happens ? Why doesn't olive oil do that ? Somewhere I also
read, that glycerin moisturizes the skin, but if one would use to much in
soap, it would work the other way round and dry out the skin. Why is that ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

- Original Message -
From: Anti-Fossil [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Saturday, February 12, 2005 3:52 AM
Subject: Re: [Biofuel] Glycerine soap making


 I have been making my own soap for about 14 years now.  The only real
 secret that I have found in regards to fantastic foaming action of your
 soaps is the inclusion of coconut oil (c.o.) in your recipe.  I am aware
 that a few of the more popular websites, and even books written on the
 subject, warn against using too high a percentage of c.o. because of its
 drying effects on the skin.  However, I keep the percentage of c.o. in my
 soap between 20% and 40%, and haven't had any problems with excessively
dry
 skin.  Common sense must also come in to play of course.  If you start
with
 dry skin, you would definitely want to stay on lower end of those
 percentages with c.o., and increase the hydrating oils like olive, and
 settle for less foaming soap.

 AntiFossil
 Mike Krafka USA


 - Original Message -
 From: Phillip Wolfe [EMAIL PROTECTED]
 To: [EMAIL PROTECTED]
 Sent: Friday, February 11, 2005 12:21 PM
 Subject: Re: [Biofuel] Glycerine soap making


  Dear Legal Eagle,
 
  There is an industrial and commercial method of using
  refined glycerin for the manufacturing of natural
  soaps and detergents (and the harsher soaps too).
 
  As JFT advocates, there is a personal quest too -
  making your own stuff.
 
  In the industrial and commercial world there is a
  worldwide glut of glcyerin! compared to a couple
  years ago. I've been following this recently.
 
  But on the personal level, me thinks the idea of
  making homegrown soaps is pretty neat.
 
  It can be Family get together like making ice cream!
 
  Take care and good luck!
 
  --- Legal Eagle [EMAIL PROTECTED] wrote:
 
   What to do with the copious amounts of glycerine by
   product ? We can follow
   through with the seperation of the components an get
   a close to pure
   glycerine, providing we have a market for it, or we
   can use it to make soap.
   JtF has a few good articles on that too.
   http://journeytoforever.org/biodiesel_glycerin.html
   I am in the process of experiementing with a couple
   recipes that, I hope,
   will give a fairly decent usable product. I have
   used some as a body soap
   and it works great, however very little foamong
   action and that is a problem
   in most circles, so I am trying three diffenrent
   approaches.
   1) 100ml water with 10gr NaOH per liter of glycerine
   by product
   2) 150ml water with 15gr NaOH per liter of glycerine
   by product
   30 200ml water with 20gr NaOH per liter of glycerine
   by product
  
   Firstly the methanol must be removed/recovered by
   raising the temps above
   65C (148.5F) and then the NaOH disolved into a
   little more than warm water.
   Once the glycerine has cooled a bit, to about 43C
   (110F) then mix in the
   water/NaOH while stirring for about a minute or two.
   Pour into a mold and
   let settle. How long will be subject of another post
   when I have it figured
   out :-)
   The first one has had two weeks to settle out
   anything that was going to do
   that and it did. Some gelatenous substance caked a
   portion of the hardened
   glycerine and had to be scrapped off, but the result
   was still solid bars.
   The second and third recipes are yet to be finished
   however they already
   show more potential, primarily the third which began
   solidifying almost
   immediately and shows good promise.
   I shall keep you posted as to the success/failure of
   this as we go along. No
   sense throwing away a perfectly good product if it
   can be used eh? I am
   determined that it will.
   Luc
  
  
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Re: [Biofuel] Glycerine soap making

2005-02-12 Thread Pieter Koole

Hi,
Thanks for writing some about making soap from the glycerin by-product.
You write about 10 grams (or more)  of NaOH per liter of glyc.
How or what do you count the already used amount of NaOH during the BD
proces, which we find back in the by-product ?


Met  dank en vriendelijke groet,
Pieter Koole
Netherlands.

- Original Message -
From: Legal Eagle [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Friday, February 11, 2005 7:08 PM
Subject: [Biofuel] Glycerine soap making


 What to do with the copious amounts of glycerine by product ? We can
follow
 through with the seperation of the components an get a close to pure
 glycerine, providing we have a market for it, or we can use it to make
soap.
 JtF has a few good articles on that too.
 http://journeytoforever.org/biodiesel_glycerin.html
 I am in the process of experiementing with a couple recipes that, I hope,
 will give a fairly decent usable product. I have used some as a body soap
 and it works great, however very little foamong action and that is a
problem
 in most circles, so I am trying three diffenrent approaches.
 1) 100ml water with 10gr NaOH per liter of glycerine by product
 2) 150ml water with 15gr NaOH per liter of glycerine by product
 30 200ml water with 20gr NaOH per liter of glycerine by product

 Firstly the methanol must be removed/recovered by raising the temps above
 65C (148.5F) and then the NaOH disolved into a little more than warm
water.
 Once the glycerine has cooled a bit, to about 43C (110F) then mix in the
 water/NaOH while stirring for about a minute or two. Pour into a mold and
 let settle. How long will be subject of another post when I have it
figured
 out :-)
 The first one has had two weeks to settle out anything that was going to
do
 that and it did. Some gelatenous substance caked a portion of the hardened
 glycerine and had to be scrapped off, but the result was still solid bars.
 The second and third recipes are yet to be finished however they already
 show more potential, primarily the third which began solidifying almost
 immediately and shows good promise.
 I shall keep you posted as to the success/failure of this as we go along.
No
 sense throwing away a perfectly good product if it can be used eh? I am
 determined that it will.
 Luc


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Re: [Biofuel] Biodiesel additives

2005-02-05 Thread Pieter Koole

Thank you for sending the link.
On my system I did find it and also another one.
First I probably could not find it, because it is not called Wintron CX30,
but Wintron XC30.
I have found two different companies that sell it. Both in England. One
sells it for 40 and one sells it for 19 pounds per liter.

Met  dank en vriendelijke groet,
Pieter Koole

- Original Message -
From: Legal Eagle [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Friday, February 04, 2005 4:32 PM
Subject: Re: [Biofuel] Biodiesel additives


 G'day Pieter;
 http://www.biofuelsystems.com/uk2shop-2.htm However when I just tried
 thelink it was down. Hope they are still tehre.
 Luc
 - Original Message -
 From: Pieter Koole [EMAIL PROTECTED]
 To: [EMAIL PROTECTED]
 Sent: Friday, February 04, 2005 9:49 AM
 Subject: Re: [Biofuel] Biodiesel additives


  Hello,
  Can you tell me where I could buy this Wintron CX-30 out here in Holland
?
  Thanks in advance.
 
  Met  dank en vriendelijke groet,
  Pieter Koole
  Netherlands.
 

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Re: [Biofuel] Biodiesel additives

2005-02-04 Thread Pieter Koole

Hello,
Can you tell me where I could buy this Wintron CX-30 out here in Holland ?
Thanks in advance.

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands.

- Original Message -
From: Legal Eagle [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Thursday, February 03, 2005 11:38 PM
Subject: Re: [Biofuel] Biodiesel additives


 G'day Jan;
 From my understanding, Lubrizol works very well for the purpose it is
 intended for and that is B20 blend. It works primarily on the dino end,
not
 the BD end.
 I am a bit scetchy about all the details and it could be a bit higher % on
 the BD side although I am certain that it is of littole value on B100.A
 consideration to keep in mind. Wintron CX-30 on the other hand was
 formulated especially FOR biodiesel and is reputed to do just fine on B100
 down to -10C and the answer I got when I sent them an emai lwas that they
 were working on a formula that could in effect be winter friendly on B100
 down to -20/-25C. (hopes and anticipation I am sure)
 Luc
 Luc
 - Original Message -
 From: Jan Lieuwe Bolding [EMAIL PROTECTED]
 To: [EMAIL PROTECTED]
 Sent: Tuesday, February 01, 2005 5:00 PM
 Subject: Re: [Biofuel] Biodiesel additives


  Try to find a Lubrizol dealer or contact biofuelsystems in Britain.
 
 
  JLB
  - Original Message -
  From: Nuno Alegria - MT Energia [EMAIL PROTECTED]
  To: [EMAIL PROTECTED]
  Sent: Tuesday, February 01, 2005 6:46 PM
  Subject: [Biofuel] Biodiesel additives
 
 
  Hi
 
  Does anyone knows any additives for use with biodiesel to low CFPP in
  winter? Where can we buy it in Europe?
 
  Thanks,
 
 
  --
  Nuno Alegria
 
 
 
 
 
 
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Re: [Biofuel] New bio dieseler

2005-01-28 Thread Pieter Koole

Where do you live ?

Met vriendelijke groet,
Pieter Koole
Netherlands



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Re: [Biofuel] biodiesel in belgium; www.biofuel.be

2004-12-11 Thread Pieter Koole

Hi Sam,
You can write an e-mail to me to deliver in Holland ( or talk about it
anyway ).

Met vriendelijke groet,
Pieter Koole
[EMAIL PROTECTED]


The information contained in this message (including attachments) is
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- Original Message -
From: Sam Critchley [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Thursday, December 09, 2004 6:10 PM
Subject: Re: [Biofuel] biodiesel in belgium; www.biofuel.be



 Hi,

 You don't happen to deliver biodiesel (smaller quantities - say 300L) in
the Netherlands do you? Or know someone who does?

 Does anyone know of something like a European Association of Biofuels
Producers?

 Thanks,


 Sam



 On Wed,  8 Dec 2004 10:44:47 +0100, [EMAIL PROTECTED] wrote:

  Dear all
 
  Belgium doesn't make it easy for Biodiesel,
 
  Even though we ratified the European wish to introduce 5,75 % biofuel in
all
  transport fuel by 2010, Belgium regulation does not help biodiesel
companies as
  they do in Germany, France and other European countries.
 
  Belgium is still not clear how they are going to take the fiscal tax out
of
  Biofuel. This represents in Belgium more that 55% tax on fuel.
 
  However one company believe in Biodiesel in Belgium
 
  Biofuel.be ; www.biofuel.be
 
  On one hand they deal with the Farmers and the rapeseed stock exchange
to manage
  having a rapeseed production sufficient, stable in order to have they
own
  Belgian Biodiesel. On the other hand they are dealing with the Petrol
  Companies, Public and private transportation companies to make sure
Biodiesel
  gets integrated in they own production or in they fleet.
 
  Soon Biofuel.be will soon create his fist Belgian biodiesel Pilot Plant
 
  Regards
 
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Re: [Biofuel] winterizing

2004-12-11 Thread Pieter Koole

Thanks Keith, I didn't seem to read the artikle properly.
And next times I won't send the below message with my mail.

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

From: Keith Addison [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Thursday, December 09, 2004 7:55 PM
Subject: Re: [Biofuel] winterizing


 Hi all,
 Trying to keep driving on BD this winter, I followed up the advise to
heat
 up the BD ( I did it to 55¡ C ) and cool it down to below zero ( -3¡ C ).
 After that, I would siphon off the BD and let the solid on the bottom
to
 use during the summer.
 I got some solid stuff, but it looks like cottonwool floating (or
sinking)
 all through the fluid. How do I separate the solid from the liquid ? Or
did
 I do something wrong ?

 We advise doing that to the WVO, not the biodiesel:

 To make WVO biodiesel for winter, heat the oil first, then cool it
 to near 0 deg C (32 deg F); the saturated fats will crystallise out
 and sink to the bottom. Use the clear oil off the top to make winter
 biodiesel, keep the stuff at the bottom for summer. But even this
 winterized biodiesel still won't go much below -5 deg C (23 deg F)
 without gelling.
 http://journeytoforever.org/biodiesel_winter.html
 Biodiesel in winter: Journey to Forever

 Anyway, if you give it time the solid stuff should settle and then
 you can syphon  liquid biodiesel from the top.

 Met  dank en vriendelijke groet,
 Pieter Koole
 Netherlands.

 By the way, Pieter:

 The information contained in this message (including attachments) is
 confidential, and is intended for the addressee(s)
 only.  If you have received this message in error please delete it and
 notify the originator immediately.  The unauthorized use, disclosure,
 copying or alteration of this message is strictly forbidden. We will not
be
 liable for direct, special, indirect or
 consequential damages arising from alteration of the contents of this
 message by a third party or in case of electronic communications as a
result
 of any virus being passed on.

 This is known as Bogus Legalistic Boilerplate, not welcome on
 mailing lists - for one thing, it wastes lots of bandwidth when it
 goes to 3,000-odd list members every time you send a message. Please
 see:

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 Mailing and Posting Etiquette

 Thankyou.

 Best wishes

 Keith

 snip

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Re: [Biofuel] winterizing

2004-12-09 Thread Pieter Koole

Hi all,
Trying to keep driving on BD this winter, I followed up the advise to heat
up the BD ( I did it to 55¡ C ) and cool it down to below zero ( -3¡ C ).
After that, I would siphon off the BD and let the solid on the bottom to
use during the summer.
I got some solid stuff, but it looks like cottonwool floating (or sinking)
all through the fluid. How do I separate the solid from the liquid ? Or did
I do something wrong ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands.

The information contained in this message (including attachments) is
confidential, and is intended for the addressee(s)
only.  If you have received this message in error please delete it and
notify the originator immediately.  The unauthorized use, disclosure,
copying or alteration of this message is strictly forbidden. We will not be
liable for direct, special, indirect or
consequential damages arising from alteration of the contents of this
message by a third party or in case of electronic communications as a result
of any virus being passed on.


- Original Message -
From: MH [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Wednesday, December 08, 2004 10:52 AM
Subject: Re: [Biofuel] winterizing


 Maybe this will help --

  diethyl ether
  http://ptcl.chem.ox.ac.uk/MSDS/DI/diethyl_ether.html


   Tim,
   The internet page gives an error : 404 Page not found.
  
   Met vriendelijke groet,
   Pieter Koole
   Netherlands


   - Original Message -
  
   Hello All,
  
   I don't know about diethyl ether being used as an
   aid for winterizing biodiesel, but the
   precautionary warning on handling is worth some
   review. The link below is an MSDS on it.
  
   http://ptcl.chem.ox.ac.uk/MSDS/DI/diethyl_ether.ht
   ml
  
   Best wishes,
   Tim


A precautionary note for those who are
considering the use of diethyl
ether as a winterizing agent:
   
Be sure to add the following caveat:  Remember
that diethyl ether is
highly flammable, and was used as an anesthetic
in surgery.  Be sure to
chill it before measuring, and work in a well
ventilated areageorge
   
Best wishes,
Peggy


  Do you have any reliable data to offer on this Peggy? How does it
  perform? Quite a lot of people are working on biodiesel winterisers,
  including some very competent people, from my discussions with some
  of them I'd say they've tried all the potential quick fixes.
 
  Best wishes
 
  Keith
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Re: [Biofuel] winterizing

2004-12-09 Thread Pieter Koole

Ok,
Thank you.

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands


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- Original Message -
From: Tim Ferguson [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Wednesday, December 08, 2004 3:14 PM
Subject: RE: [Biofuel] winterizing


 Pieter,

 Sorry about the 404 error. My email editor was truncating and it snipped
the ml off of the html. I have corrected the editor and
 provided the link again below.
 http://ptcl.chem.ox.ac.uk/MSDS/DI/diethyl_ether.html

 Best wishes,
 Tim

 -Original Message-
 From: [EMAIL PROTECTED] [mailto:[EMAIL PROTECTED]
 Behalf Of Pieter Koole
 Sent: Tuesday, December 07, 2004 3:58 PM
 To: [EMAIL PROTECTED]
 Subject: Re: [Biofuel] winterizing


 Tim,
 The internet page gives an error : 404 Page not found.

 Met vriendelijke groet,
 Pieter Koole
 Netherlands


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 confidential, and is intended for the addressee(s)
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 notify the originator immediately.  The unauthorized use, disclosure,
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 of any virus being passed on.


 - Original Message -
 From: Tim Ferguson [EMAIL PROTECTED]
 To: [EMAIL PROTECTED]
 Sent: Tuesday, December 07, 2004 8:52 PM
 Subject: RE: [Biofuel] winterizing


  Hello All,
 
  I don't know about diethyl ether being used as an
  aid for winterizing biodiesel, but the
  precautionary warning on handling is worth some
  review. The link below is an MSDS on it.
 
  http://ptcl.chem.ox.ac.uk/MSDS/DI/diethyl_ether.ht
  ml
 
  Best wishes,
  Tim
 
  -Original Message-
  From: [EMAIL PROTECTED]
  [mailto:[EMAIL PROTECTED]
  Behalf Of Keith Addison
  Sent: Tuesday, December 07, 2004 12:20 PM
  To: [EMAIL PROTECTED]
  Subject: Re: [Biofuel] winterizing
 
 
  A precautionary note for those who are
  considering the use of diethyl
  ether as a winterizing agent:
  
  Be sure to add the following caveat:  Remember
  that diethyl ether is
  highly flammable, and was used as an anesthetic
  in surgery.  Be sure to
  chill it before measuring, and work in a well
  ventilated areageorge
 
  Do you have any reliable data to offer on this
  Peggy? How does it
  perform? Quite a lot of people are working on
  biodiesel winterisers,
  including some very competent people, from my
  discussions with some
  of them I'd say they've tried all the potential
  quick fixes.
 
  Best wishes
 
  Keith
 
 
 
  
  Best wishes,
  Peggy
 
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Re: [Biofuel] winterizing

2004-12-08 Thread Pieter Koole

Tim,
The internet page gives an error : 404 Page not found.

Met vriendelijke groet,
Pieter Koole
Netherlands


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confidential, and is intended for the addressee(s)
only.  If you have received this message in error please delete it and
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- Original Message -
From: Tim Ferguson [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Tuesday, December 07, 2004 8:52 PM
Subject: RE: [Biofuel] winterizing


 Hello All,

 I don't know about diethyl ether being used as an
 aid for winterizing biodiesel, but the
 precautionary warning on handling is worth some
 review. The link below is an MSDS on it.

 http://ptcl.chem.ox.ac.uk/MSDS/DI/diethyl_ether.ht
 ml

 Best wishes,
 Tim

 -Original Message-
 From: [EMAIL PROTECTED]
 [mailto:[EMAIL PROTECTED]
 Behalf Of Keith Addison
 Sent: Tuesday, December 07, 2004 12:20 PM
 To: [EMAIL PROTECTED]
 Subject: Re: [Biofuel] winterizing


 A precautionary note for those who are
 considering the use of diethyl
 ether as a winterizing agent:
 
 Be sure to add the following caveat:  Remember
 that diethyl ether is
 highly flammable, and was used as an anesthetic
 in surgery.  Be sure to
 chill it before measuring, and work in a well
 ventilated areageorge

 Do you have any reliable data to offer on this
 Peggy? How does it
 perform? Quite a lot of people are working on
 biodiesel winterisers,
 including some very competent people, from my
 discussions with some
 of them I'd say they've tried all the potential
 quick fixes.

 Best wishes

 Keith



 
 Best wishes,
 Peggy

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Re: [Biofuel] centrifuging To Jan Lieuwe

2004-11-17 Thread Pieter Koole

Hoi Jan,
Weet jij waar zo'n centrifuge te koop is en evt. prijsindicatie ?

Met  dank en vriendelijke groet,
Pieter Koole


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- Original Message -
From: Jan Lieuwe Bolding [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Tuesday, November 16, 2004 9:50 PM
Subject: Re: [Biofuel] centrifuging


 I know small centrifuges were used on farms over here in the Netherlands
to
 make cheese and butter etc., maybe this is a entry.


 Jan Lieuwe Bolding
 - Original Message -
 From: Robert Del Bueno [EMAIL PROTECTED]
 To: [EMAIL PROTECTED]
 Sent: Sunday, November 14, 2004 11:22 PM
 Subject: [Biofuel] centrifuging


  Does anyone out there use a small continuous-flow centrifuge at all?
  I have been thinking for a while that one could probably do well for
  cleaning up waste oil. Spin out particulates and water with no
filtration
  medium.
  I have seen oil/water separators, and other centrifugal devices, like
 those
  used to clean cutting/cooling fluids down to 1 micronand seems like
a
  good way to clean SVO.
  The only drawback seems to be finding on that is small.
  Any thoughts?
 
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Re: [biofuel] Chemichal Drying

2004-08-31 Thread Pieter Koole

I just ordered some zeolite, which can be used over and over to dry
products. The water bonds to the zeolite because it is bipolair, while oil
isn't.
You can dry the zeolite and use it again.
I'll keep you informed about my experiments.

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

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- Original Message -
From: Teoman Naskali [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Tuesday, August 31, 2004 3:52 PM
Subject: [biofuel] Chemichal Drying


 A good chemist friend told me that calcium oxide (Cao) could be used to
 dry WVO and methanol.

 I searched the archives for this but couldn't find a satisfactory
 answer.

 Can anyone help?

 I was thinking on filling a water filter with the stuff and adding it in
 line with the pump.


 Thanks,
 Teoman





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[biofuel] Fool proof 2 stage question

2004-08-10 Thread Pieter Koole

Hello all.
During the last couple of months I have collected WVO and fat from different
sources. Now I know the very good quality of the oil I have collected
before, from one adress. It must have been almost SVO.
Trying to make BD, I had to go back to the start with the single stage base
method, and even with that method I cannot get it right. My car rides on it,
but the BD is not clear at all and when I whas it say 4 times, the water
turns out clear, but the BD gets worse and worse. I would think there is a
lot of soap in it, but I do not know how to avoid this. Titration is done
with a very good expensive pH meter and also with pH paper.
Now I am trying the foolproof method, but that also doesn't work.
I must admit I panic a little, because I don't know what to do now.
Can anyone help ?
I would like to know a bit more about the chemical background of the
foolproof method.

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands.

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- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, August 07, 2004 8:57 PM
Subject: RE: [biofuel] 2 stage method questions


 Hello Teoman

 Sorry, just trying to avoid purchansing titration equipment. And get a
 good unerstanding of the processes before I start anything.

 If you read the previous messages I referred you to on this, you'd
 see those two statements are incompatible.

 Anyway, how much would titration equipment cost you? Or how little
 rather? You'll get it all back and more on what you save with your
 first tankful. False economy.

  I just got access to a highschool lab, if I bring my own chemicals and
 wash after I have used the equipment.

 Good, so start at the beginning then, single-stage base with virgin
 oil, small test batches:

 Where do I start?
 http://journeytoforever.org/biodiesel_make.html#start

 I also had bought some isopropanol (%99 pure) with the phosphoric acid.
 
 Can and should I titrate larger quatities of wvo, should I mix them??

 If you're going to process the mixture, sure, why not? On the other
 hand, if something goes wrong and it's caused by oil from one source
 and not the others it won't be very easy to discover the problem.
 You'll have to go back to the beginning, titrate the oil from each
 bach separately, and do small test batches with each.

 Say I collect 10L each from three different sources, can I mix them and
 then titrate? Or do I have to titrate them separately?
 
 What about the denser white fat at the bottom?

 Depends what it is, tallow, hydrogenated, gunk. And whether you plan
 to use the fuel in summer or winter. See:

 http://journeytoforever.org/biodiesel_winter.html
 Biodiesel in winter

 Can I collect say one ton of wvo and then titrate it?

 Yes, but you're unlikely to be doing that before you've made your
 first one-litre test batches with virgin oil. It's often said that
 making biodiesel doesn't lend itself well to theorising - just do it.
 Focus on doing it properly and learning as much as you can. Be
 thorough. The more effort and care you put into doing it well and
 developing good practices in the beginning the better off you'll be
 later, it really pays off. When you have some hands-on experience
 your forward planning and theorising will make a lot more sense.

 Best wishes

 Keith Addison


 Previous:

 Teoman
 
 Please see this recent message (two days ago) on why you should not
 be using the Foolproof method until you have a lot more experience.
 It says so after all, right at the top of the page. You don't
 believe it, or what?
 
 http://infoarchive.net/sgroup/biofuel/37345/
 
 In fact I'll post it all again, in the hopes that maybe at long
 long last somebody might take just a little notice and save
 themselves a whole bunch of trouble, and also us:
 
 Please see:
 
 http://infoarchive.net/sgroup/BIOFUEL/37310/1/
 
 Please read all six of the messages in the thread, including this:
 
 The two-stage processes are not the place to start making biodiesel.
 It says right at the top of the page: NOTE: The two-stage biodiesel
 processes are advanced methods, not for novices -- learn the basics
 thoroughly first. The single-stage base method is the place to start.
 Start here.
 
 Here being here - single stage, with new oil:
 Where do I start?
 http://journeytoforever.org/biodiesel_make.html#start
 
 There was some discussion about this at the list recently, please see
 these two previous posts

Re: [biofuel] From Sludge Oil to BD

2004-08-09 Thread Pieter Koole

To avoid accidents, using a drill to prepare your methoxide, you could cover
your drill with a clamp (is that the right english word ? ) cloth or towel.
Be carefull please.

Vriendelijke groet,
Pieter Koole
Netherlands



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- Original Message -
From: bioveging [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, August 08, 2004 2:12 AM
Subject: [biofuel] From Sludge Oil to BD


 Well, I have completed my first batch other than a small test batch.
 It was done with horrible oil, titrated to 10gr/liter and the batch
 started life as a 20 liter batch and is now about a 15-16 liter
 batch, maybe a little less. Loads of by-product which I will turn
 into a degreasing soap, I hope.
 After washing and allowing to settle a pumped it through a couple of
 filters and it is now drying until the next time I need to fuel
 the Benz, at which point in it goes.
 The tank used is the one I have set up as a pre-heat tank with an
 immersion heater welded into the side of it and I did the methoxide
 mix in an out-of-doors concept (as I didn't have a cover for it)
 using a drill and paint stirrer and then after draining the
 glycerine I then washed it using the same stirrer and about 30%
 water to BD ratio.
 The next batch will be an 80 liter batch using my newly built
 reactor/wash tank unit and this one is 100% closed (except for the
 wash tank)to fumes escaping and therefore much safer than the open
 can concept.
 Had I not been able to do the methoxide mix literally outside then I
 would not have done it until able to securely close off the fume
 potential, nor do I foresee doing it that way again as a spark from
 the drill motor and, well, 

 L.





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Re: [biofuel] Why is the pH of pure water 7.0 ??

2004-08-09 Thread Pieter Koole

A little bit difficult to explain in english, but I'll give it a try.
pH means potential of H+ ions.
In pure water you will find this balance :
H2O + H2O  OH- + H3O+
, where the balance is very much on the left side, but a little bit of
protolyse is measured in pure water.

At 25¡ C one will measure 1.0 x 10-7 [OH-] and of course also 1.0 x 10-7
[H3O+]
When you take the negative logarithm of 10-7 (10 exponent -7) you find 7 and
that is what we call pH = 7.

So when for example [OH-] goes to 1.0 x 10-5, the other one [H3O+] has to go
to 1.0 x 10-9

H3O+ is often called H+. In this case pH = 9.
When H+ is 1.0 x 10-9 ( pH = 9 and pOH = 5 ) your solution is more basic.

I hope you can understand my terrible english.

Vriendelijke groet,
Pieter Koole
Netherlands



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- Original Message -
From: Guag Meister [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, August 08, 2004 3:29 PM
Subject: [biofuel] Why is the pH of pure water 7.0 ??


 Hi all list members ;

 While we are on the subject of pH,  can anyone give me
 a reasonable explanation as to why the pH of pure
 water is 7.0??  And I don't mean because it is in the
 middle of the range.

 Peter G.
 Thailand

 --- bioveging [EMAIL PROTECTED] wrote:

  And THAT is one of great benefits of this list, the
  mountainous
  combined experience of it's members !
  Thank you very much for your answer as it helps me a
  great deal
  knowing that I was not having a twilight zone
  moment with my PH
  meter. Yes, mine does have the little adjustment
  knobs and I have
  purchased two seperate solutions, one a PH-7 and the
  other a PH-10
  and will be doing the calibration today so I can
  properly titrate my
  WVO for the next batch.
 
  L.
 
  --- In biofuel@yahoogroups.com, Guag Meister
  [EMAIL PROTECTED]
  wrote:
   Hi L ;
  
   pH meters go out of calibration VERY easily.  The
  bulb
   which senses the pH is very delicate.  It can be
   easily affected by strong acids or bases,
  particularly
   if these solutions are allowed to dry on the bulb.
 
   Long periods of exposure to air (in other words,
   drying out) is not a good thing either for the
  bulb.
  
   More expensive meters have calibration buttons to
   compensate for this.  With these better meters,
  you
   buy some calibrated solutions and then regularly
   adjust the meter to read the correct value.
  
   If you are using a cheap meter which does not have
   calibration, here are some tips  for longest life
  :
  
   1) These cheap meters are not designed for strong
   acids and bases, so don't use in strong acids or
   bases.
   2) Rinse the bulb well with neutral water after
  every
   reading.
   3) When not in use, store in a manner such that
  the
   bulb is in a pH 7.0 buffer solution. This can be
   readily purchased from a lab supply company, and
  not
   expensive.
   4) Check calibration with pH standard solutions.
  If
   your meter is off a little, you can mentally
   compensate, but this is not a true calibration.
  To do
   a true calibration you need two points to
  establish
   slope and offset.
  
   Hope this helps..
  
   Peter G.
   Thailand
  
  
   --- bioveging [EMAIL PROTECTED] wrote:
  
My PH meter seems to be out of whack. Does this
happen on any kind
of regular basis?
The new WVO I have is clearly better than the
other lot I did and
it is titrating even worse than the 10gr/liter
  batch
and I do not
think this is possible so I acquired some PH
solution from the
aquarium store (one a 7 and another one a 10)
  and
haven't tested
them yet, although I was wondering if anyone
  else
has had trouble
with PH meters going out of sink.
I checked two seperate lots of WVO, both better
  than
the sludge I
did my 20 liter with, and they BOTH titrated
  higher
than 10gr/liter
so something is amiss I am sure.
I plan on checking my PH meter ASAP and will
  post
any results, but
in the mean time any comments?
   
L.
   
   
   
  
  
  
  
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 Biofuels list

Re: [biofuel] Lumpy BD

2004-07-27 Thread Pieter Koole

Hello all,
My last batches of BD were ok, but there whas more than 30% glyc at the end.
Any idea what can cause that ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands
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- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Monday, July 26, 2004 8:01 PM
Subject: Re: [biofuel] Lumpy BD


 Good day;
 
 I made a test batch of 20 liters the other day and when I checked
 it for quality using the method described at journeytoforever
 http://journeytoforever.org/biodiesel_vehicle.html#quality it
 returned good fuel with clear and distinct seperation of unwashed
 fuel in less than 30 seconds.
 The problem is that when I poured out the BD into a bucket (as the
 glycerine had solidified at the bottom of the drum)it was lumpy,
 as if gelatine clumps were floating around in it.
 Is this due to the temp having dropped off during processing or
 perhaps incomplete reaction even though the quality test came back
 positive ?
 
 Any input ?

 Wash it and see. Let it settle first though, then decant it carefully
 into the wash vessel.

 Sorry if you've already gone ahead in the meantime. If so, please let
 us know the result.

 By the way, if you use KOH instead of NaOH the glycerine cocktail
 won't solidify, which you might find an advantage. Your processor's
 closed, no? - ie, unopenable. I'm sure you know this, but I'll say it
 anyway... Closed is usually taken to mean closed during processing
 so no fumes escape. Two types - those with lids and those with no
 lids, or sealed. We've no experience of sealed processors, but it
 seems to me it'd make solidified glyc more of a nuisance. Either way
 it'll be a nuisance if it gunks up the plumbing at the bottom of the
 tank.

 Best wishes

 Keith


 Thanks
 
 L.




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Re: [biofuel] SVO in diesel engines

2004-07-27 Thread Pieter Koole

Why would you produce extra oxygen ?
Wouldn't a simple turbo (compressor) give any result ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

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- Original Message -
From: Robert Williams [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Monday, July 26, 2004 10:03 AM
Subject: [biofuel] SVO in diesel engines


 We are using a static medium sized diesel generating set fueled by waste
 vegetable oil, tallow and virgin rapeseed oil to produce electricity and
 provide space heating in a small commercial development. To obtain
 reliable combustion the engine is started on diesel oil and switched to
 SVO after reaching temperature. The combustion air is also modified by
 increasing the proportion of oxygen, which elevates the temperature in
 the chamber ensuring complete combustion of the bio-fuel.

 The system works reliably but the cost of generating oxygen is high.
 Does anyone have experience of running un-modified diesels on SVO and
 does any manufacturer warranty their engine for use with SVO?

 Many thanks

 Robert




 [Non-text portions of this message have been removed]





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Re: [biofuel] Electricity from WVO and Rapeseed

2004-07-25 Thread Pieter Koole

This is what I have been doing since the last 7 years.

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

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- Original Message -
From: rob crowley [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, July 23, 2004 7:02 PM
Subject: [biofuel] Electricity from WVO and Rapeseed


 I heard an interesting story on the BBC World Service Europe Today
 program broadcast on July 23.  They interviewed a spokesperson from a
 British company with a patented technology to generate electrical power
 from rapeseed oil and WVO.

 The process involves virgin oil and waste vegetable oil.  The rapeseed
 is pressed to extract the virgin oil for fuel. Then the soild remains
 from the pressing is mixed with waste vegetable oil and burned in a
 turbine.  In this way, the entire rapeseed is used to generate
 electricity.

 According to the interview, the technology could produce electricity for
 one thousand homes for one year using crops planted in an area of 1
 square mile (2.5 sq km).  Based on the rapeseed crops planted in the UK
 now, there is enough to supply five percent of the UK power needs.

 The article did not appear on their web site, but perhaps it will be
 available later at:
 http://www.bbc.co.uk/worldservice/europe/europetoday/index.shtml

 best regards,
  rob








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Re: [biofuel] centrifuges

2004-07-15 Thread Pieter Koole

So what is the price ?
I live in Holland.

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

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- Original Message -
From: Philip S. Okey [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Wednesday, July 14, 2004 6:30 PM
Subject: [biofuel] centrifuges


 hello all..

 I noticed that there have been a couple of posts about people wanting used
centrifuges,
 I have a extra Veronesi 650gpm, that is roughly set up to extract the
glycerine phase
 from the triglycerides  biodiesel during transesterfication so that the
reaction will go to completion,
 but could easily be set up for separating the wash water from the finished
biodiesl.
 which is what my other one is being set up for.
 we got a new alpha laval for the in process separations so we will not be
needing this one,
 (changing the plant design again...)
 if any of you are trying to get a larger batch plant set up, and have
about the same budget constraints as me,
 this one is available.and the price is negotiable..

 Phil Okey
 Innovative Energy  Solvents LLC
 Indianpolis, IN 46227

 317-513-7002









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Re: [biofuel] Zeolites

2004-07-12 Thread Pieter Koole

Thanks a lot.
Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

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- Original Message -
From: Martin Klingensmith [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Monday, July 12, 2004 4:02 AM
Subject: Re: [biofuel] Zeolites




 Pieter Koole wrote:
  Hello all,
  Can anyone tell me where I can buy zeolites to dry alcohol ?
  Could I use zeolites to dry the WVO, and re-use it ?
 
  Met  dank en vriendelijke groet,
  Pieter Koole
  Netherlands

 Hello Pieter,
 Zeolites have been extensively researched on the Biofuel and Distillers
 lists for drying alcohol. Try these searches:

http://infoarchive.net/sgroup/biofuel/index.php?keywords=alcohol+dryinglis
t=BIOFUEL

http://infoarchive.net/sgroup/biofuel/index.php?keywords=ethanol+dryinglis
t=BIOFUEL

http://infoarchive.net/sgroup/biofuel/index.php?keywords=zeolitelist=BIOFU
EL

http://infoarchive.net/sgroup/biofuel/index.php?keywords=alcohol+dryinglis
t=DISTILLERS

http://infoarchive.net/sgroup/biofuel/index.php?keywords=zeolitelist=DISTI
LLERS

 --
 --
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 http://infoarchive.net/
 http://nnytech.net/



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Re: [biofuel] Zeolites

2004-07-10 Thread Pieter Koole

Hello all,
Can anyone tell me where I can buy zeolites to dry alcohol ?
Could I use zeolites to dry the WVO, and re-use it ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

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- Original Message -
From: tallex2002 [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, July 09, 2004 6:14 PM
Subject: [biofuel] Zeolites



 Hi all,

 This material has useful applications for biofuel production as well.


 Zeolites in Solar Energy Applications

 http://www.eere.energy.gov/consumerinfo/factsheets/ba3.html





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 http://groups.yahoo.com/group/next_generation_grid/

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Re: [biofuel] Westfalia Centrifuge for sale - Pieter

2004-07-09 Thread Pieter Koole

Sorry, I don't understand what price you mean ?
How much would it be in  ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

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- Original Message -
From: [EMAIL PROTECTED] [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, July 08, 2004 10:11 AM
Subject: Re: [biofuel] Westfalia Centrifuge for sale - Pieter


 Pieter

 Around the 4-5k mark.

 Mark





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[biofuel] Used motor oil

2004-07-08 Thread Pieter Koole

Hi all,
Does anyone know if it is possible to make diesel fuel out of used motor oil
?
I know this is not environmental friendly, but it is there anyway, so why
not use it as a fuel ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

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- Original Message -
From: [EMAIL PROTECTED] [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Monday, July 05, 2004 10:42 AM
Subject: Re: [biofuel] Westfalia Centrifuge for sale - Pieter


 Pieter

 Sorry for the delay.

 The centrifuge is a Westfalia marine oil
 centrifuge with 1-phase 230V and 415V 3-phase
 motors, stainless steel disc stack.

 What are you offering?





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Re: [biofuel] Westfalia Centrifuge for sale

2004-07-07 Thread Pieter Koole

No, it is not a BD factory. In fact we produce a kind of soap (not glycerin
soap).

Met  dank en vriendelijke groet,
Netherlands

The information contained in this message (including attachments) is
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- Original Message -
From: pieter van eeten [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Monday, July 05, 2004 9:27 AM
Subject: Re: [biofuel] Westfalia Centrifuge for sale


 Hi Pieter,

 Got in tough with Breustedt last friday they ave me the name of their
local
 distributors near Eindhoven so now I can finally start my first batch!

 Thanks for the help.

 You factory is a BD factory?


 From: Pieter Koole [EMAIL PROTECTED]
 Reply-To: biofuel@yahoogroups.com
 To: biofuel@yahoogroups.com
 Subject: Re: [biofuel] Westfalia Centrifuge for sale
 Date: Fri, 02 Jul 2004 21:13:15 +0200
 
 The number is 06 2049 38 58 (Jan de Jong).
 Mention my name if you wish, and maybe you'll even get it a little
cheaper.
 I have a small factory and Jan is my supplier.
 
 Met  dank en vriendelijke groet,
 Pieter Koole
 
 
 The information contained in this message (including attachments) is
 confidential, and is intended for the addressee(s)
 only.  If you have received this message in error please delete it and
 notify the originator immediately.  The unauthorized use, disclosure,
 copying or alteration of this message is strictly forbidden. We will not
be
 liable for direct, special, indirect or
 consequential damages arising from alteration of the contents of this
 message by a third party or in case of electronic communications as a
 result
 of any virus being passed on.
 
 
 - Original Message -
 From: pieter van eeten [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Friday, July 02, 2004 10:13 AM
 Subject: Re: [biofuel] Westfalia Centrifuge for sale
 
 
   Eindhoven, do they sell wholesale at Breustedt or also smaller
batches,
 seem
   more appropriate to start small with my first batch.
  
   Have you been making BD for a while?
  
  
   From: Pieter Koole [EMAIL PROTECTED]
   Reply-To: biofuel@yahoogroups.com
   To: biofuel@yahoogroups.com
   Subject: Re: [biofuel] Westfalia Centrifuge for sale
   Date: Fri, 02 Jul 2004 09:50:28 +0200
   
   Hi Pieter,
   Where do you live ?
   My supplier is Breustedt in Apeldoorn
   
   Met  dank en vriendelijke groet,
   Pieter Koole
   Netherlands
   
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   of any virus being passed on.
   
   
   - Original Message -
   From: pieter van eeten [EMAIL PROTECTED]
   To: biofuel@yahoogroups.com
   Sent: Friday, July 02, 2004 7:19 AM
   Subject: Re: [biofuel] Westfalia Centrifuge for sale
   
   
 Hi Pieter,

 Seems I found a fellow Dutch guy around, something bound to happen
 of
 course.

 Pieter I recently became interested in Biodiesel and want to start
   producing
 it or at least give it my best shot.

 However, it seems I cannot get hold of decent lye (or NaOH) would
 you
   mind
 telling me where your supplier has hidden himself? Or where else I
 might
   be
 able to find good Lye?

 Grtz,
 Pieter van Eeten


 From: Pieter Koole [EMAIL PROTECTED]
 Reply-To: biofuel@yahoogroups.com
 To: biofuel@yahoogroups.com
 Subject: Re: [biofuel] Westfalia Centrifuge for sale
 Date: Thu, 01 Jul 2004 18:19:10 +0200
 
 Yes.
 What is the price ?
 
 Met  dank en vriendelijke groet,
 Pieter Koole
 Netherlands.
 
 The information contained in this message (including attachments)
 is
 confidential, and is intended for the addressee(s)
 only.  If you have received this message in error please delete
it
 and
 notify the originator immediately.  The unauthorized use,
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 copying or alteration of this message is strictly forbidden. We
 will
   not
   be
 liable for direct, special, indirect or
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 this
 message by a third party or in case

Re: [biofuel] Westfalia Centrifuge for sale - Pieter

2004-07-07 Thread Pieter Koole

I have no idea
You ask and I'll think

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

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- Original Message -
From: [EMAIL PROTECTED] [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Monday, July 05, 2004 10:42 AM
Subject: Re: [biofuel] Westfalia Centrifuge for sale - Pieter


 Pieter

 Sorry for the delay.

 The centrifuge is a Westfalia marine oil
 centrifuge with 1-phase 230V and 415V 3-phase
 motors, stainless steel disc stack.

 What are you offering?





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Re: [biofuel] Westfalia Centrifuge for sale

2004-07-02 Thread Pieter Koole

Hi Pieter,
Where do you live ?
My supplier is Breustedt in Apeldoorn

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

The information contained in this message (including attachments) is
confidential, and is intended for the addressee(s)
only.  If you have received this message in error please delete it and
notify the originator immediately.  The unauthorized use, disclosure,
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liable for direct, special, indirect or
consequential damages arising from alteration of the contents of this
message by a third party or in case of electronic communications as a result
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- Original Message -
From: pieter van eeten [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, July 02, 2004 7:19 AM
Subject: Re: [biofuel] Westfalia Centrifuge for sale


 Hi Pieter,

 Seems I found a fellow Dutch guy around, something bound to happen of
 course.

 Pieter I recently became interested in Biodiesel and want to start
producing
 it or at least give it my best shot.

 However, it seems I cannot get hold of decent lye (or NaOH) would you mind
 telling me where your supplier has hidden himself? Or where else I might
be
 able to find good Lye?

 Grtz,
 Pieter van Eeten


 From: Pieter Koole [EMAIL PROTECTED]
 Reply-To: biofuel@yahoogroups.com
 To: biofuel@yahoogroups.com
 Subject: Re: [biofuel] Westfalia Centrifuge for sale
 Date: Thu, 01 Jul 2004 18:19:10 +0200
 
 Yes.
 What is the price ?
 
 Met  dank en vriendelijke groet,
 Pieter Koole
 Netherlands.
 
 The information contained in this message (including attachments) is
 confidential, and is intended for the addressee(s)
 only.  If you have received this message in error please delete it and
 notify the originator immediately.  The unauthorized use, disclosure,
 copying or alteration of this message is strictly forbidden. We will not
be
 liable for direct, special, indirect or
 consequential damages arising from alteration of the contents of this
 message by a third party or in case of electronic communications as a
 result
 of any virus being passed on.
 
 
 - Original Message -
 From: [EMAIL PROTECTED] [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Thursday, July 01, 2004 5:56 PM
 Subject: [biofuel] Westfalia Centrifuge for sale
 
 
   Hi
  
   I have a Westfalia centrifugal separator for
   sale. Its rated to approx. 900L per hr, has a
   single phase and 3-phase motor. I imported it
   from the states for a bio-diesel pilot plant. Is
   any one interested?
  
   Mark
   07963 651609
  
  
  
  
  
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 Messenger - so many all-new ways to express yourself
 http://uk.messenger.yahoo.com
  
  
  
  
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Re: [biofuel] Westfalia Centrifuge for sale

2004-07-02 Thread Pieter Koole

I make lots of it since several years.
At Breustedt you can buy 25 kg bags or more.

Met  dank en vriendelijke groet,
Pieter Koole



The information contained in this message (including attachments) is
confidential, and is intended for the addressee(s)
only.  If you have received this message in error please delete it and
notify the originator immediately.  The unauthorized use, disclosure,
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- Original Message -
From: pieter van eeten [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, July 02, 2004 10:13 AM
Subject: Re: [biofuel] Westfalia Centrifuge for sale


 Eindhoven, do they sell wholesale at Breustedt or also smaller batches,
seem
 more appropriate to start small with my first batch.

 Have you been making BD for a while?


 From: Pieter Koole [EMAIL PROTECTED]
 Reply-To: biofuel@yahoogroups.com
 To: biofuel@yahoogroups.com
 Subject: Re: [biofuel] Westfalia Centrifuge for sale
 Date: Fri, 02 Jul 2004 09:50:28 +0200
 
 Hi Pieter,
 Where do you live ?
 My supplier is Breustedt in Apeldoorn
 
 Met  dank en vriendelijke groet,
 Pieter Koole
 Netherlands
 
 The information contained in this message (including attachments) is
 confidential, and is intended for the addressee(s)
 only.  If you have received this message in error please delete it and
 notify the originator immediately.  The unauthorized use, disclosure,
 copying or alteration of this message is strictly forbidden. We will not
be
 liable for direct, special, indirect or
 consequential damages arising from alteration of the contents of this
 message by a third party or in case of electronic communications as a
 result
 of any virus being passed on.
 
 
 - Original Message -
 From: pieter van eeten [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Friday, July 02, 2004 7:19 AM
 Subject: Re: [biofuel] Westfalia Centrifuge for sale
 
 
   Hi Pieter,
  
   Seems I found a fellow Dutch guy around, something bound to happen of
   course.
  
   Pieter I recently became interested in Biodiesel and want to start
 producing
   it or at least give it my best shot.
  
   However, it seems I cannot get hold of decent lye (or NaOH) would you
 mind
   telling me where your supplier has hidden himself? Or where else I
might
 be
   able to find good Lye?
  
   Grtz,
   Pieter van Eeten
  
  
   From: Pieter Koole [EMAIL PROTECTED]
   Reply-To: biofuel@yahoogroups.com
   To: biofuel@yahoogroups.com
   Subject: Re: [biofuel] Westfalia Centrifuge for sale
   Date: Thu, 01 Jul 2004 18:19:10 +0200
   
   Yes.
   What is the price ?
   
   Met  dank en vriendelijke groet,
   Pieter Koole
   Netherlands.
   
   The information contained in this message (including attachments) is
   confidential, and is intended for the addressee(s)
   only.  If you have received this message in error please delete it
and
   notify the originator immediately.  The unauthorized use, disclosure,
   copying or alteration of this message is strictly forbidden. We will
 not
 be
   liable for direct, special, indirect or
   consequential damages arising from alteration of the contents of this
   message by a third party or in case of electronic communications as a
   result
   of any virus being passed on.
   
   
   - Original Message -
   From: [EMAIL PROTECTED] [EMAIL PROTECTED]
   To: biofuel@yahoogroups.com
   Sent: Thursday, July 01, 2004 5:56 PM
   Subject: [biofuel] Westfalia Centrifuge for sale
   
   
 Hi

 I have a Westfalia centrifugal separator for
 sale. Its rated to approx. 900L per hr, has a
 single phase and 3-phase motor. I imported it
 from the states for a bio-diesel pilot plant. Is
 any one interested?

 Mark
 07963 651609





 ___ALL-NEW
   Yahoo!
   Messenger - so many all-new ways to express yourself
   http://uk.messenger.yahoo.com




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 http

Re: [biofuel] Westfalia Centrifuge for sale

2004-07-02 Thread Pieter Koole

The number is 06 2049 38 58 (Jan de Jong).
Mention my name if you wish, and maybe you'll even get it a little cheaper.
I have a small factory and Jan is my supplier.

Met  dank en vriendelijke groet,
Pieter Koole


The information contained in this message (including attachments) is
confidential, and is intended for the addressee(s)
only.  If you have received this message in error please delete it and
notify the originator immediately.  The unauthorized use, disclosure,
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liable for direct, special, indirect or
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message by a third party or in case of electronic communications as a result
of any virus being passed on.


- Original Message -
From: pieter van eeten [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, July 02, 2004 10:13 AM
Subject: Re: [biofuel] Westfalia Centrifuge for sale


 Eindhoven, do they sell wholesale at Breustedt or also smaller batches,
seem
 more appropriate to start small with my first batch.

 Have you been making BD for a while?


 From: Pieter Koole [EMAIL PROTECTED]
 Reply-To: biofuel@yahoogroups.com
 To: biofuel@yahoogroups.com
 Subject: Re: [biofuel] Westfalia Centrifuge for sale
 Date: Fri, 02 Jul 2004 09:50:28 +0200
 
 Hi Pieter,
 Where do you live ?
 My supplier is Breustedt in Apeldoorn
 
 Met  dank en vriendelijke groet,
 Pieter Koole
 Netherlands
 
 The information contained in this message (including attachments) is
 confidential, and is intended for the addressee(s)
 only.  If you have received this message in error please delete it and
 notify the originator immediately.  The unauthorized use, disclosure,
 copying or alteration of this message is strictly forbidden. We will not
be
 liable for direct, special, indirect or
 consequential damages arising from alteration of the contents of this
 message by a third party or in case of electronic communications as a
 result
 of any virus being passed on.
 
 
 - Original Message -
 From: pieter van eeten [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Friday, July 02, 2004 7:19 AM
 Subject: Re: [biofuel] Westfalia Centrifuge for sale
 
 
   Hi Pieter,
  
   Seems I found a fellow Dutch guy around, something bound to happen of
   course.
  
   Pieter I recently became interested in Biodiesel and want to start
 producing
   it or at least give it my best shot.
  
   However, it seems I cannot get hold of decent lye (or NaOH) would you
 mind
   telling me where your supplier has hidden himself? Or where else I
might
 be
   able to find good Lye?
  
   Grtz,
   Pieter van Eeten
  
  
   From: Pieter Koole [EMAIL PROTECTED]
   Reply-To: biofuel@yahoogroups.com
   To: biofuel@yahoogroups.com
   Subject: Re: [biofuel] Westfalia Centrifuge for sale
   Date: Thu, 01 Jul 2004 18:19:10 +0200
   
   Yes.
   What is the price ?
   
   Met  dank en vriendelijke groet,
   Pieter Koole
   Netherlands.
   
   The information contained in this message (including attachments) is
   confidential, and is intended for the addressee(s)
   only.  If you have received this message in error please delete it
and
   notify the originator immediately.  The unauthorized use, disclosure,
   copying or alteration of this message is strictly forbidden. We will
 not
 be
   liable for direct, special, indirect or
   consequential damages arising from alteration of the contents of this
   message by a third party or in case of electronic communications as a
   result
   of any virus being passed on.
   
   
   - Original Message -
   From: [EMAIL PROTECTED] [EMAIL PROTECTED]
   To: biofuel@yahoogroups.com
   Sent: Thursday, July 01, 2004 5:56 PM
   Subject: [biofuel] Westfalia Centrifuge for sale
   
   
 Hi

 I have a Westfalia centrifugal separator for
 sale. Its rated to approx. 900L per hr, has a
 single phase and 3-phase motor. I imported it
 from the states for a bio-diesel pilot plant. Is
 any one interested?

 Mark
 07963 651609





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   Messenger - so many all-new ways to express yourself
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Re: [biofuel] Westfalia Centrifuge for sale

2004-07-01 Thread Pieter Koole

Yes.
What is the price ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands.

The information contained in this message (including attachments) is
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- Original Message -
From: [EMAIL PROTECTED] [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, July 01, 2004 5:56 PM
Subject: [biofuel] Westfalia Centrifuge for sale


 Hi

 I have a Westfalia centrifugal separator for
 sale. Its rated to approx. 900L per hr, has a
 single phase and 3-phase motor. I imported it
 from the states for a bio-diesel pilot plant. Is
 any one interested?

 Mark
 07963 651609





 ___ALL-NEW Yahoo!
Messenger - so many all-new ways to express yourself
http://uk.messenger.yahoo.com




 Biofuel at Journey to Forever:
 http://journeytoforever.org/biofuel.html

 Biofuels list archives:
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[biofuel] question

2004-06-26 Thread Pieter Koole

Hi all,
Today some chinees man from a restaurant brought me 1000 liters of WVO.
It smells like hell, because it has been in a container for months.
Can I still make BD from this stuff ?

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

The information contained in this message (including attachments) is
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- Original Message -
From: nick_75au [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, June 25, 2004 2:11 PM
Subject: [biofuel] Centrifugal seperator for biodiesel


 Hi,
 I posted to the 100% ethanol post about centrifugal processor not
 being able to seperate water from ethanol, yahoo started bouncing my
 messages for the second time in as many weeks so i never saw the
 replys, general opinion is a seperator wont work.
 Anyway I want to  throw some thoughts out into the breeze about
 using the seperator to remove the glycyrine and FFA out of the
 reacted biodiesel. I worked in the navy where we used 4 small
 seperators, two for removing contaminants and water out of main
 engine sump oil and the other two removed water and solids from
 diesel fuel. As we know to seperate the glycerine and FFA out of the
 fuel once it is reacted it is left to settle overnight and the FFA
 and glycerine settles to the bottom by gravity. Well a centrifugal
 seperator ( if I can I will post a picture in the photos section
 showing a seperator cross section) achieves the same result by
 rotating a stack of conical disks at around 10,000 rpm. the heavy
 component is forced to the outside and is discharged to a port, the
 fuel passes up the center and is discharged to a second port. any
 dirt is traped on the disks and in the bowl. The advantage of this
 is that it happens in minutes not hours or days. The seperators I
 delt with were the smallest model and they could process 100 litres
 per minute.  Another feature that is interesting is that for the
 centrifuges water could actualy be introduced into the oil or diesel
 to assist in seperating water and contaminant from the product, I
 bring this up because It may be a way to wash the biodiesel at the
 same time as removing the glycerine however I think this may not
 work as all the procceses on the JTF site wash after seperating,
 Have I missed someting regarding this?.
  So now I have given this wonderful info and you all rush out to
 find
 seperators then find they are too big, too costly and difficult to
 find unless you work in a shipyard, I did some looking around and I
 believe that the humble cream seperator might just do the trick, a
 perfect size for a home biodieseler, hand driven and works on
 exactly the same principal. Some experimentation will be required as
 to speed it
 is spun and it may require some modification I dont know until I or
 someone can post some results.
 I havent made any biodiesel yet and when I do I am definitly going
 to try this out, If any one is willing to give it a go now I would
 love to here about it and will be able to sort out any problems
 on-line.

 Best Regards
 Nick





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Re: [biofuel] Re: Algae farming for oil $

2004-06-14 Thread Pieter Koole

Hi Marc.
I have 3000 square meters of land ( in american terms this is nothing, I
know, but we live in Holland ).
How much oil could the algea produce yearly. Not in theory, but practical.
What would I need in terms of heating , ventilation etc ?
I would be very very pleased with any useble information.

( Sorry about my English. I have never learned english at school. I chose
French and German ).

Met  dank en vriendelijke groet,
Pieter Koole
Netherlands

The information contained in this message (including attachments) is
confidential, and is intended for the addressee(s)
only.  If you have received this message in error please delete it and
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- Original Message -
From: Marc Orion Cardoso [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, June 12, 2004 5:21 PM
Subject: [biofuel] Re: Algae farming for oil $


 --
  Dear pieter,
  we have perhaps the only ,and certainly, the most comprehensive
 manual on growing algae. $180.00 U.S.. this manual is for the serious
 person doing due dillegance into the feasability and technology of
 algaeculture.It covers growing rechniques for various lipid (oil)
 producing algae as well as growing Tilapia fish which are used to
 provide nutrients for the algae as well as a highly profitable value
 added product. see our website for data relating to the closed loop
 ecosystems in which we grow the algae and tilapia fish in a mutually
 symbiotic  relationship. surprisnigly,  the algae manual is our
 biggest selling manual despite the cost. for more on our manuals go
 to the product description page on our website just google for
 ecogenics or go to www dabney.com/ecogenics/ for more on our
 technologies.
  Marc







 - In biofuel@yahoogroups.com, Pieter Koole [EMAIL PROTECTED] wrote:
  Hi all,
  Can anyone give me some more information about growing algae ?
  Met  dank en vriendelijke groet,
  Pieter Koole
  Netherlands
 
  The information contained in this message (including attachments) is
  confidential, and is intended for the addressee(s)
  only.  If you have received this message in error please delete it
 and
  notify the originator immediately.  The unauthorized use,
 disclosure,
  copying or alteration of this message is strictly forbidden. We
 will not be
  liable for direct, special, indirect or
  consequential damages arising from alteration of the contents of
 this
  message by a third party or in case of electronic communications as
 a result
  of any virus being passed on.
 
 
  - Original Message -
  From: Marc Orion Cardoso [EMAIL PROTECTED]
  To: biofuel@yahoogroups.com
  Sent: Saturday, June 12, 2004 12:55 AM
  Subject: [biofuel] Re: Algae farming for oil $
 
 
   --
 we have been growing various species for years under a wide
 variety
   of climatic conditions...now we are  developing separation and
   processing technology we  do not have cost figures as of yet that
 are
   definitive.
Marc
  
  
  
  
  
  
  
  
  
  
   - In biofuel@yahoogroups.com, John Woolsey [EMAIL PROTECTED]
 wrote:
Okay here is a question:
What would the price of the oil be for Algae farmed oil?
Someone here said they had been doing this stuff for years.
What is your price for various quantities?
Is it cheaper than Soy oil etc?
   
 - bfn - JAW
  
  
  
  
  
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   http://journeytoforever.org/biofuel.html
  
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[biofuel] FFA / Glycerin separation

2004-06-07 Thread Pieter Koole

Hi all,
Again I have had some troubles with my health, so I haven't been around for
a while.
But as we say in Holland Weeds aren't killed.
I have done as written below and do not understand a thing of it.
Who can help ?

I took 800 liters of used oil, which is used for a day or two to bake fish
in at 180¡ C.
I titratet 4 ml so that brings me to 7.5 grams of NaOH per liter = 6 kg NaOH
The NaOH was dissolved completely in 96 kg methanol ( 120 liters ).
This was mixed using a strong pump with the oil during 1 hour, ( which I
boiled first to 120¡ C to make sure there whas no trace of water in the oil.
I filtered the hot oil and let it cool down to about 30¡ C).
I think I have made BD now. I usually make BD with different amounts of
NaOH, because I used to get the oil from somebody else.
Anyway, separation occured and the s.g. of the BD is 0,860 which is not too
bad, I would think.
Now I took 525 grams of the bottom layer ( I did not perform the whashing
process at all, so there cannot be any water ).
Then I mixed this with 34 ml phosphoric acid (75%).
After a short time separation occured :
A light sherry / goldish toplayer , a bit darker than sunflower oil, which
is, I guess 80% of the total lot.
A complete black middle layer, which is maybe 5% of the lot
A bottomlayer which has the color off coffee with milk, which is about 10%
of the lot.

This is not the result I expected.
I realize I have asked this before and at that time I did not manage to
seperate FFA and glycerin ( maybe I did, but not knowing what the glycerin
or the FFA whas ).

So, what did I produce and what can I do whith it ?


Met  dank en vriendelijke groet,
Pieter Koole



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only.  If you have received this message in error please delete it and
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- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, May 21, 2004 3:22 PM
Subject: Re: [biofuel] Phenolphthalein


 OK, here's the thing. I can get it in all it's wonderful forms, but
 that doesn't help me as I don't know which one will work for
 titration, so that is where the wonderfully helpful people here will
 steer me right,please.
 It comes as:
 1)Reagent powder
 2).5% alcohol solution
 3)1% alcohol solution
 The question is: which one?
 I want to measure it up to the PH meter as I think that that may be
 the weak link in my titration.
 
 Thoughts? Guidance? Ideas?
 
 Many thanks or TA! (as the Aussies/Brits say)
 
 Luc

 Previous message:

 - Original Message -
 From: biobenz
   The chem supply house I am dealing with offers the Phenolphthalein
   in a pre-mixed alcohol solution at 1%. Would this work as well or
   better than the do-it-yourself method ?
 
 Biobenz,
 If you are unable to get 95% ethanol or don't want to go to the trouble
of
 making up the phenolphthalein solution yourself, the premixed solution
would
 be a great idea. It would also be neutralalised in manufacture. Would
indeed
 work just as well as or better.
 
 Regards  Paul Gobert.

 1% Phenolphthalein solution
 (1.0w/v%)

 Keith




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Re: [biofuel] Re: oil from algae...

2004-04-27 Thread Pieter Koole

I am interested as well.

Met vriendelijke groet,
Pieter Koole
Netherlands.



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only.  If you have received this message in error please delete it and
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- Original Message -
From: wwschnabel [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Tuesday, April 27, 2004 4:42 AM
Subject: Re: [biofuel] Re: oil from algae...


 I asked a while ago if anyone had any info on Oil from algae.

 What I would like to do is an experiment.

 Does anyone have any info on how exactly to extract the oil from algae?
Could I do it in a home lab?

 Thanks,

 Bill

 [Non-text portions of this message have been removed]





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Re: [biofuel] Re: Pieter and the Foolproof method

2004-04-09 Thread Pieter Koole


- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Wednesday, April 07, 2004 6:07 PM
Subject: [biofuel] Re: Pieter and the Foolproof method


 Hello Pieter

 Hi Keith,
 The heating was done with 2 liters in stead of 700 liters, so I could
reach
 70¡ C.
 Why boil it off ?
 Because I wanted to start over again and not end up using half a liter of
 methanol per liter of veg oil.

 If you decide to do the rest of it maybe use a bit less rather than
 boiling it off - most of the excess will end up in the glycerine
 cocktail anyway.

 The fact that I made a big amount at once, was a great big mistake. I
made
 this mistake, because I read this methode as being a methode without any
 chance of failing.
 I agitated it as I always do, with a pump. The inlet of the pump at the
 bottom of the container and the outlet at the top.
 Concerning the time : I did it exactly as Aleks writes, but with 12 hours
at
 least I mean settling time.

 Sorry, can I get this straight? So this is wrong, what you told me
previously?

 For how long did you process each stage?
 At least 12 hours.
You are right. I processed each stage for the time Aleks advises. The
settling time took 12 hours at least.

 How long did it settle in between?
 At least 12 hours.

 Best

 Keith


 - Original Message -
 From: Keith Addison [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Monday, April 05, 2004 9:35 PM
 Subject: Pieter and the Foolproof method - was Re: [biofuel] cold weather
 and biodiesel
 
 
   Hello Pieter
  
   I wonder what this had to do with cold weather and biodiesel?
  
   Never mind...
  
   Hi all,
   As some of you allready know, I have tried the foolproof methode
without
   succes.
   The result was a coffee like murky stuff with methanol floating on
top
 off
   this slurry.
   What I did to save the lot :
   I boiled off the methanol at 70¡ C.
   After that, I made new sodium methoxide ( I think 200 ml methanol and
4
   grams of lye per liter of the residu ) and made BD as I am used to.
   The result was still not cristal clear, but now I heated the lot
again
 and
   became a beautifull golden liquid. Spec. grafity 0.865 grams per
liter.
   Now my question : During the last heating ( so not when cooling
down ) a
   fair bit of clear gel appeared. It has the structure of melted
chewing
 gum.
   A bit like silicone kit ( is that an english word ? ).
   The residu is still cristal clear with spec. graf 0.865.
   Does anyone know what that could be ?
   
   Groeten,
   Pieter
  
   Once again you puzzle me. Especially I'm puzzled that you boiled off
   the methanol you said was left on top - at 70 deg C, though
   previously you couldn't get the temp higher than 35 deg C for the
   second stage of the process. How did you manage it? And why boil if
   off at all, if you were going to add more methanol anyway to
   reprocess it?
  
   Anyway, previously you said: I have tried to do it exactly as Aleks
   Kac writes on the site. That still left me with a bunch of
   questions, and I did get some answers from you, but also more
   questions, and now more questions again.
  
   Aleks says this, right up near the top: Whenever you're trying a new
   method, it's always a good idea to make small test batches of a liter
   or less first to familiarize yourself with the process before moving
   on to bigger batches.
  
   We also say that, lots of times, at the Journey to Forever site and
   here. So do other people say that, and I must say it seems obvious. I
   asked you:
  
   How much oil did you use - was this a small test batch? I hope so.
  
   You told me: No, stupid enough it was 700 liters.
  
   :-(
  
From your first message, you also said you couldn't get the
   second-stage heat higher than 35 deg C (95F), though it should be 55C
   (131F). So I also asked you:
  
   How did you heat it and how did you agitate it?
  
   You told me you'd used the central heating of your house, but the oil
   was in a 1000-liter container and did not get hotter than 35 deg C.
   But you didn't say how you agitated it.
  
   Aleks says agitate the first stage at 35 deg C for one hour, then
   agitate for a further hour without heating, settle, and second-stage
   processing is 1.5-2.5 hours.
  
   You told me you'd processed each stage for at least 12 hours, with at
   least 12 hours settling in between. I wonder how you translated those
   processing times into at least 12 hours each?  You added: As I said,
   I did it exactly the way Aleks writes, but it seems chaotic.
  
   We tell people the two-stage methods are not for novices for good
   reason. Some people still take no notice though, and then we get
   messages like this:
  
   Hi  I have 2 45gal drums. There joined together with hoses valves. I
   boiled down 400 ml of battery acid to a brown thick acid to 100ml. I
   have 60 Liters of cooking fat.I heated it and water went to bottom
   of container before I dipped out 

Re: Pieter and the Foolproof method - was Re: [biofuel] cold weather and biodiesel

2004-04-07 Thread Pieter Koole

Hi Keith,
The heating was done with 2 liters in stead of 700 liters, so I could reach
70¡ C.
Why boil it off ?
Because I wanted to start over again and not end up using half a liter of
methanol per liter of veg oil.

The fact that I made a big amount at once, was a great big mistake. I made
this mistake, because I read this methode as being a methode without any
chance of failing.
I agitated it as I always do, with a pump. The inlet of the pump at the
bottom of the container and the outlet at the top.
Concerning the time : I did it exactly as Aleks writes, but with 12 hours at
least I mean settling time.

- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Monday, April 05, 2004 9:35 PM
Subject: Pieter and the Foolproof method - was Re: [biofuel] cold weather
and biodiesel


 Hello Pieter

 I wonder what this had to do with cold weather and biodiesel?

 Never mind...

 Hi all,
 As some of you allready know, I have tried the foolproof methode without
 succes.
 The result was a coffee like murky stuff with methanol floating on top
off
 this slurry.
 What I did to save the lot :
 I boiled off the methanol at 70¡ C.
 After that, I made new sodium methoxide ( I think 200 ml methanol and 4
 grams of lye per liter of the residu ) and made BD as I am used to.
 The result was still not cristal clear, but now I heated the lot again
and
 became a beautifull golden liquid. Spec. grafity 0.865 grams per liter.
 Now my question : During the last heating ( so not when cooling down ) a
 fair bit of clear gel appeared. It has the structure of melted chewing
gum.
 A bit like silicone kit ( is that an english word ? ).
 The residu is still cristal clear with spec. graf 0.865.
 Does anyone know what that could be ?
 
 Groeten,
 Pieter

 Once again you puzzle me. Especially I'm puzzled that you boiled off
 the methanol you said was left on top - at 70 deg C, though
 previously you couldn't get the temp higher than 35 deg C for the
 second stage of the process. How did you manage it? And why boil if
 off at all, if you were going to add more methanol anyway to
 reprocess it?

 Anyway, previously you said: I have tried to do it exactly as Aleks
 Kac writes on the site. That still left me with a bunch of
 questions, and I did get some answers from you, but also more
 questions, and now more questions again.

 Aleks says this, right up near the top: Whenever you're trying a new
 method, it's always a good idea to make small test batches of a liter
 or less first to familiarize yourself with the process before moving
 on to bigger batches.

 We also say that, lots of times, at the Journey to Forever site and
 here. So do other people say that, and I must say it seems obvious. I
 asked you:

 How much oil did you use - was this a small test batch? I hope so.

 You told me: No, stupid enough it was 700 liters.

 :-(

  From your first message, you also said you couldn't get the
 second-stage heat higher than 35 deg C (95F), though it should be 55C
 (131F). So I also asked you:

 How did you heat it and how did you agitate it?

 You told me you'd used the central heating of your house, but the oil
 was in a 1000-liter container and did not get hotter than 35 deg C.
 But you didn't say how you agitated it.

 Aleks says agitate the first stage at 35 deg C for one hour, then
 agitate for a further hour without heating, settle, and second-stage
 processing is 1.5-2.5 hours.

 You told me you'd processed each stage for at least 12 hours, with at
 least 12 hours settling in between. I wonder how you translated those
 processing times into at least 12 hours each?  You added: As I said,
 I did it exactly the way Aleks writes, but it seems chaotic.

 We tell people the two-stage methods are not for novices for good
 reason. Some people still take no notice though, and then we get
 messages like this:

 Hi  I have 2 45gal drums. There joined together with hoses valves. I
 boiled down 400 ml of battery acid to a brown thick acid to 100ml. I
 have 60 Liters of cooking fat.I heated it and water went to bottom
 of container before I dipped out 60 liters.I took it up to 35 C  and
 but in 4.8 liters of menthol mixed with washer pump for 5-6 min then
 added 100 ml acid.I went inside for 3/4 of hr and when I came back
 out the fuse had blown. I ran out of time and it mixed for maybe 1/2
 hr afterwords.(Had to go away..)My friend didn't look after it like
 he said..So what Im asking is what do I do..Im reheating it now but
 the menthol is getting away..will I carry on with next step or
 circulate it more...Thanks

 And then you get people who say it doesn't work. LOL! It didn't
 have a hope in hell of working. Another one wrote a really demanding
 letter (telling me to telephone him in Texas or something)
 complaining about it - he hadn't even tried it, nor ever made
 biodiesel of any kind, from what I could make out, but he said It
 won't work, quite angrily... Sheesh! Some other guy said he'd had an
 

Re: [biofuel] cold weather and biodiesel

2004-04-04 Thread Pieter Koole

Hi all,
As some of you allready know, I have tried the foolproof methode without
succes.
The result was a coffee like murky stuff with methanol floating on top off
this slurry.
What I did to save the lot :
I boiled off the methanol at 70¡ C.
After that, I made new sodium methoxide ( I think 200 ml methanol and 4
grams of lye per liter of the residu ) and made BD as I am used to.
The result was still not cristal clear, but now I heated the lot again and
became a beautifull golden liquid. Spec. grafity 0.865 grams per liter.
Now my question : During the last heating ( so not when cooling down ) a
fair bit of clear gel appeared. It has the structure of melted chewing gum.
A bit like silicone kit ( is that an english word ? ).
The residu is still cristal clear with spec. graf 0.865.
Does anyone know what that could be ?

Groeten,
Pieter

- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, April 03, 2004 10:08 PM
Subject: Re: [biofuel] cold weather and biodiesel


 Hello Mark

 How did you handle the cold weather over the winter with your
 biodiesel? Do you use additives or mix with diesel?
 
 I've just made my first batch of biodiesel and found it has a cloud
 point
 of around 30 degrees F. It gets down to -20 degrees F in the winter
 in
 Upstate NY so I'm wondering how others handle the cold.

 Additives might handle it, if it's a really good additive
 specifically formulated for biodiesel, but probably you'll need more
 than that. See:
 Biodiesel in winter
 http://journeytoforever.org/biodiesel_winter.html

 Best

 Keith




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Re: [biofuel] micro-organisms in oil

2004-04-02 Thread Pieter Koole

I don't know at all, but I can imagine that if you would recover the
methanol just before you use the BD, it would keep the micro -organisms
quiet for so long.

Groeten,
Pieter.

- Original Message -
From: Yves vd Hoeven [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, April 02, 2004 10:21 AM
Subject: [biofuel] micro-organisms in oil


 When the temperature is warm enough micro-organisms can start to develop
in
 mineral oil, especially in WVO I guess. Now that spring/summer is coming I
 wonder, is there a substance that can safely be added to the WVO to
prevent
 this, or doesn't it matter.

 Yves.




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[biofuel] Can I please get some help ?

2004-03-28 Thread Pieter Koole

Hi all.
Yesterday and today I made my first batch of BD using the foolproof method.
Neither in the acid stage, nor in the second stage any separation occured.
The methanol is floating on the top and the whole lot looks like coffee with
too much milk in it.
At the bottom I find some salt, which is probably NaOH.
The oil I used is a very good quality, almost SVO.
What have I done wrong ?
I couln't get the temperature higher than 35¡ C.
I have tried to do it exactly as Aleks Kac writes on the site.

Groeten,
Pieter
Netherlands.




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Re: [biofuel] floating draw-off

2004-03-02 Thread Pieter Koole

x-charset ISO-8859-1I use a lump of wood and it works pretty well.

Met vriendelijke groeten,
Pieter Koole
Netherlands

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- Original Message -
From: Alan Petrillo [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Tuesday, March 02, 2004 8:39 AM
Subject: Re: [biofuel] floating draw-off


 [EMAIL PROTECTED] wrote:

  I have built several floating draw offs, and I'm not sure which is best.
For
  the float, one can use polyethylene foam, not styrofoam!, or a sealed
air
  container, such as a PVC pipe with capped ends. Use a good weight on the
float to
  keep it immersed in the liquid. For the hose, I recommend one of those
  pre-coiled poly garden hoses, so it follows the fluctuating level
without being
  pulled off to the side. I also use a guide rod down through the coil to
keep things
  on the level. If you can figure a flexible joint that can stand a
suction,
  perhaps you could post it here. I can't find one that is flexible
enough.

 I haven't used any such thing for BD, but a floating pickup is often
 used for jet fuel in aviation fuel farms.  The trick is to have the
 pickup tube extend a bit below the float.  That way as the float changes
 aspect to the surface of the fuel the pickup doesn't suck air.  The
 aviation setups usually have stops so that the pickup leaves the last 8
 inches or so in the tank.  I never had to worry about it, though, as my
 fuel farm never had any water in it.

 For the appropriate flexible joint, I suppose you could check with your
 local tank and lift supplier.


 AP




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Re: [biofuel] A question about lignine

2004-02-29 Thread Pieter Koole

x-charset ISO-8859-1Great !
Thanks a lot.
You say it is all organic material. Doesn't the sulfuric acid do any harm,
or is that all used by breaking down the cellulose ?

You asked : Why not ?
Well, for the same reason as why we don't find any information about
producing nuclear power or other poluting methods on your site. Aren't we
more or less idealists ?

Met vriendelijke groeten,
Pieter Koole

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- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, February 28, 2004 2:56 PM
Subject: Re: [biofuel] A question about lignine


 Thanks Ken,
 I hope I don't insult anybody, but as far as I remember I found the way
to
 make ethanol out of sawdust on journeytoforever.

 Fuel From Sawdust
 http://journeytoforever.org/biofuel_library.html#sawdust

 If the process produces poison material, why would it be on this site ?

 Why not?

 Compost it, Pieter. It's all organic stuff, it'll break down
 harmlessly in a properly made hot compost pile.

 http://journeytoforever.org/compost.html
 Composting: Journey to Forever

 Best

 Keith


 Met vriendelijke groeten,
 Pieter Koole
 
 
 - Original Message -
 From: Ken Provost [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Saturday, February 28, 2004 4:03 AM
 Subject: Re: [biofuel] A question about lignine
 
 
   on 2/27/04 10:48 AM, Pieter Koole at [EMAIL PROTECTED] wrote:
  
Hi all,
I am making ethanol on a very very small
scale ( experimenting a bit ) from
newspapers etc.
What is the best thing to do with the
black stuff ( lignine isn't it ? ). Is
it poison ? Can I use it somehow?
  
  
  
   In general, any organic mixture that's BLACK
   is toxic, probly carcinogenic. Blackness is
   caused by multiple aromatic fused rings --
   polycyclic aromatic hydrocarbons, of which
   graphite is the extreme version. Do a Google
   search on polycyclic aromatic hydrocarbons.
  
  
  
Is there a way to re-use the sulphuric
acid (98%)
  
  
  
   I don't think so
  
  
  
Does anyone know whether
alcohol can be dried by
electrolysis ?
  
  
  
   I've never heard of it -- doesn't mean it's
   not possible somehow, but I doubt it  -K



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/x-charset


Re: [biofuel] A question about lignine

2004-02-29 Thread Pieter Koole

x-charset ISO-8859-1This is a very interesting process.
Don't worry, I am not going to produce or sell ethanol, but just want to use
my old newspapers and some waste wood for producing ethanol to run my
lawnmower and outboard motor on.
What carbonate slurry ( found on the site ) should I use and how should I
use it ? Is that the way to dry the alcohol, and if it is, how dry can I get
it ?
How do both recover processes work ? ( for sulphuric acid and the carbonate
? ).
Thanks a lot for the answers.

Met vriendelijke groeten,
Pieter Koole


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- Original Message -
From: Fred Enga [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, February 28, 2004 6:39 PM
Subject: RE: [biofuel] A question about lignine


 Hello All.

 The lignin by product of the acid hydrolysis is not a poison.  We produce
 ethanol from wood residue using the Gaian process of concentrated
sulphuric
 acid hydrolysis.  The Lignin is the carbon skeleton of the wood and has
 similar properties to Charcoal. In some processes a lignin sulphate
compound
 is formed, but not in this process - that's more associated with the Kraft
 and sulphite paper industry.  These versions of lignin find uses in the
 manufacture of resins, other forms of lignin are used as binders for road
 surfacing.

 In our process we find the best use to be as a fuel, in fact we power our
 complete process using the combustion of the lignin produced in the
 hydrolysis stage, with a significant energy production over our
requirements
 that we can produce electricity with the surplus steam.

 Concerning the reuse of the sulphuric acid, we recover and reuse, after
 reconcentrating it.  Unfortunately we use a simulated moving bed
 chromatography process which is not 'suitable' for home use.  The older
was
 is to sacrifice the acid by neutralising it with lime which give a gypsum
 by-product which has little to no further use.

 For those who want a little more info on ethanol production from wood
 residue, there is a fairly detailed process review on our website
 www.gaianbioenergy.com

 Hope this helps

 Regards

 Fred Enga

 -Original Message-
 From: Pieter Koole
 Sent: February 27, 2004 7:27 PM
 To: biofuel@yahoogroups.com
 Subject: Re: [biofuel] A question about lignine


 Thanks Ken,
 I hope I don't insult anybody, but as far as I remember I found the way to
 make ethanol out of sawdust on journeytoforever.
 If the process produces poison material, why would it be on this site ?

 Met vriendelijke groeten,
 Pieter Koole


 The information contained in this message (including attachments) is
 confidential, and is intended for the addressee(s)
 only.  If you have received this message in error please delete it and
 notify the originator immediately.  The unauthorized use, disclosure,
 copying or alteration of this message is strictly forbidden. We will not
be
 liable for direct, special, indirect or
 consequential damages arising from alteration of the contents of this
 message by a third party or in case of electronic communications as a
result
 of any virus being passed on.


 - Original Message -
 From: Ken Provost [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Saturday, February 28, 2004 4:03 AM
 Subject: Re: [biofuel] A question about lignine


  on 2/27/04 10:48 AM, Pieter Koole at [EMAIL PROTECTED] wrote:
 
   Hi all,
   I am making ethanol on a very very small
   scale ( experimenting a bit ) from
   newspapers etc.
   What is the best thing to do with the
   black stuff ( lignine isn't it ? ). Is
   it poison ? Can I use it somehow?
 
 
 
  In general, any organic mixture that's BLACK
  is toxic, probly carcinogenic. Blackness is
  caused by multiple aromatic fused rings --
  polycyclic aromatic hydrocarbons, of which
  graphite is the extreme version. Do a Google
  search on polycyclic aromatic hydrocarbons.
 
 
 
   Is there a way to re-use the sulphuric
   acid (98%)
 
 
 
  I don't think so
 
 
 
   Does anyone know whether
   alcohol can be dried by
   electrolysis ?
 
 
 
  I've never heard of it -- doesn't mean it's
  not possible somehow, but I doubt it  -K
 




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Biofuel at Journey

[biofuel] A question about lignine

2004-02-28 Thread Pieter Koole

x-charset ISO-8859-1Hi all,
I am making ethanol on a very very small scale ( experimenting a bit ) from
newspapers etc.
What is the best thing to do with the black stuff ( lignine isn't it ? ). Is
it poison ? Can I use it somehow ?
Is there a way to re-use the sulphuric acid (98%) I used in the proces ?
I think I have asked the next question before : Does anyone know whether
alcohol can be dried by electrolysis ?

Met vriendelijke groeten,
Pieter Koole
Struiken 3
5993 NA Maasbree
077 - 465 1533
06 - 1339 1428
[EMAIL PROTECTED]


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- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, February 26, 2004 3:31 PM
Subject: Re: [biofuel] Amount of Glycerol in SVO


 Hello Tomas, how goes? Still freezing or are there signs of spring
 yet? Last time you said it was nice - minus 3C! (That's not nice!)

 Hello All,
 
 Can some one say how much glycerol there is in SVO (rapeseed, sunflower,
 coco). Is the amount always constant 20 % or is it depending on the
oil.

 It's about 7-8%. The amount of the by-product cocktail - glycerine
 + FFA (soap) + excess methanol + catalyst - varies according to the
 oil used and its condition and the process used and processing. More
 info here:

 How much glycerine? Why isn't it solid
 http://journeytoforever.org/biodiesel_make2.html#howmuchglyc

 By the way, we were talking about additives:

 Thanks Keith,
 
 I will immediately look into Wintron XC30 this sounds promissing. Thanks
 again this news group is a gold mine of info for biodieselers.
 
 The weather is back to nice -3ˆÁ.
 
 Best regards
 
 Tomas

 Wintron solved it for us, we had no trouble at all. Our WVO
 biodiesel's okay to about -5 deg C or so and it was often colder than
 that here, but not much colder than about -10 deg C. We used a 0.5%
 concentration, and for colder temps we'd just have used more, up to
 about 1%. It's still freezing at night but I guess the worst of it's
 over. Wintron's a very good product. Really serious winter cold might
 need different solutions, but for most people this will be fine.
 They've been testing a new formulation which they say works even
 better, and that will be available for next winter. More info on
 Biodiesel in winter here:

 http://journeytoforever.org/biodiesel_winter.html
 Biodiesel in winter: Journey to Forever

 Best wishes

 Keith


 Tomas




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Re: [biofuel] A question about lignine

2004-02-28 Thread Pieter Koole

x-charset ISO-8859-1Thanks Ken,
I hope I don't insult anybody, but as far as I remember I found the way to
make ethanol out of sawdust on journeytoforever.
If the process produces poison material, why would it be on this site ?

Met vriendelijke groeten,
Pieter Koole


The information contained in this message (including attachments) is
confidential, and is intended for the addressee(s)
only.  If you have received this message in error please delete it and
notify the originator immediately.  The unauthorized use, disclosure,
copying or alteration of this message is strictly forbidden. We will not be
liable for direct, special, indirect or
consequential damages arising from alteration of the contents of this
message by a third party or in case of electronic communications as a result
of any virus being passed on.


- Original Message -
From: Ken Provost [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, February 28, 2004 4:03 AM
Subject: Re: [biofuel] A question about lignine


 on 2/27/04 10:48 AM, Pieter Koole at [EMAIL PROTECTED] wrote:

  Hi all,
  I am making ethanol on a very very small
  scale ( experimenting a bit ) from
  newspapers etc.
  What is the best thing to do with the
  black stuff ( lignine isn't it ? ). Is
  it poison ? Can I use it somehow?



 In general, any organic mixture that's BLACK
 is toxic, probly carcinogenic. Blackness is
 caused by multiple aromatic fused rings --
 polycyclic aromatic hydrocarbons, of which
 graphite is the extreme version. Do a Google
 search on polycyclic aromatic hydrocarbons.



  Is there a way to re-use the sulphuric
  acid (98%)



 I don't think so



  Does anyone know whether
  alcohol can be dried by
  electrolysis ?



 I've never heard of it -- doesn't mean it's
 not possible somehow, but I doubt it  -K



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 http://journeytoforever.org/biofuel.html

 Biofuels list archives:
 http://infoarchive.net/sgroup/biofuel/

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Re: [biofuel] Is it really free???

2004-02-27 Thread Pieter Koole

It is free in a way, that you will feel free when you make your own fuel,
not depending on oilprices and so on, but of course that is not what you
mean.
Well, it is not completely free, but very cheap indead. Over here, my costs
are about  0,10 per liter biodiesel for the chemicals I need.

Met vriendelijke groeten,
Pieter Koole
Netherlands

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- Original Message -
From: bearforu2 [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, February 26, 2004 8:30 PM
Subject: [biofuel] Is it really free???


 People talk that it they can run there car for free on biofuel, but
 when you have to buy use toxic chemicals like lye etc, and spend
 hours to make just a small amount, is it really free? I am a
 supporter of biofuel, but i have not made 100% biodiesel.These are
 questions that people ask me and i would like to see what your
 answers are.




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Re: [biofuel] Biodiesel Quality?

2004-02-25 Thread Pieter Koole

x-charset ISO-8859-1Questions are never dumb.

Met vriendelijke groeten,
Pieter Koole


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- Original Message -
From: [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Tuesday, February 24, 2004 5:53 PM
Subject: Re: [biofuel] Biodiesel Quality?


 Hi again,

 Another dumb question.  Is this heating a needed step and if it is how
long
 should it be heated for?
 There's no need to heat the finished fuel to this high of a temp to dry
it.
 Approximately 120*F  (~46*C) is more than sufficient to get any
microscopic
 water to settle out before putting the fuel in the tank.

 If it seperates like you say I am good to go before heating or after?

 Thanks again

 Rick M
 Brownstown, Mi


 The simplest home test for fuel acceptability is to put equal parts fuel
and
 water in a closed container and agitate radically for a few seconds. If
the
 fuel and water separate immediately with no emulsion other than a thin
 interface film you're good to go.

 Todd Swearingen


 [Non-text portions of this message have been removed]




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Re: [biofuel] Biodiesel Quality?

2004-02-24 Thread Pieter Koole

x-charset ISO-8859-1Why heat it ?

Met vriendelijke groeten,
Pieter Koole
Netherlands

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- Original Message -
From: pinky 22in [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Tuesday, February 24, 2004 10:18 AM
Subject: Re: [biofuel] Biodiesel Quality?


 hi
  what  you did is right your biodiesel will be of good
 quality..  butb4 using the biodiesel, heat it for 110
 degree celsius  and thn use it.-vidhya
 --- [EMAIL PROTECTED] wrote:

 -
 Hi all,

 I just made my second large batch of Biodiesel.  (10
 gallon)  I have made 8
 different blender batches,  the first 3 I screwed up
 the amount of lye. (the
 scale was way off)  The next 5 came out great, (I
 think)  I have gotten great
 seperation on every good batch that I have made.  2
 very distinct layers with
 the top layer being the same color top to bottom and
 the bottom layer much
 darker and on the bottom.  I mix it for 1 hour then
 let it sit over night and draw
 off the good stuff from the top and put it in the
 washer.  I wash it with 1/2
 the amount of water for 6 to 7 hours and let it sit
 over night and repeat this
 3 times.  My last wash water is just about clear and
 the ph is about 6.

 Having told you this, is there anything to do to test
 the quality of my fuel.
  It looks good in the jug.  I have one batch that has
 been done for a couple
 of weeks and it looks the same now as it did when I
 got done washing it.

 I am ready to put it in a fuel tank and run a gen set
 but just want to be
 sure I am not going to mess any thing up.

 Thanks

 Rick M
 Brownstown, Mi.


 [Non-text portions of this message have been removed]




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Re: [biofuel] WVO wick

2004-02-18 Thread Pieter Koole

x-charset ISO-8859-1On which board ?
How did he do it, and most important : Did it work at all ?

Met vriendelijke groeten,
Pieter Koole
Netherlands

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- Original Message -
From: northlandwood [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Tuesday, February 17, 2004 11:59 PM
Subject: [biofuel] WVO wick


 Has anyone tried or had luck burning WVO with a wick?

 On another board I read that a guy built a burner based around a
 wick method.

 Thanks




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[biofuel] A question about alcohol drying

2004-02-15 Thread Pieter Koole

x-charset ISO-8859-1Hi Aleks,
Studiing the Fool Proof method - which was to be expected after our last
mails - I read that mixing alcohol and H2SO4 is a way to dry alcohol.
How dry can I get home made ethanol this way ?
How should I do it ?

Met vriendelijke groeten,
Pieter Koole

The information contained in this message (including attachments) is
confidential, and is intended for the addressee(s)
only.  If you have received this message in error please delete it and
notify the originator immediately.  The unauthorized use, disclosure,
copying or alteration of this message is strictly forbidden. We will not be
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of any virus being passed on.


- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, February 14, 2004 8:26 AM
Subject: Re: [biofuel] Foolproof method


 Dag Pieter

 Maar...

 Hi all,
 Maybe a stupid question, and with all respect to Aleks, but I am making
BD
 now for allmost two years, using the single base methode, without
titration,
 just use 150 liter methanol and 4.5 kg NaOH per 1000 liter used vegatable
 oil. Let it sit for at least a week and very slowly drain(?) what is the
 right word ? it from the top through a fine filter. I have never whashed
the
 BD.
 I have driven over 140.000 km now without any problems.
 What would be the main reason to change to the fool proof method ?
 I am very willing to learn, so I hope nobody reads this as if the fool
proof
 method would not be better. I just do not know why it would be better.

 But you HAVE had your problems, haven't you? If not with your
 Citroen, yet. You couldn't manage to separate the glycerine and FFA
 in your by-product, despite a lot of help and advice here, and that's
 dead easy - as I said at the time, it indicated something else was
 wrong. Then you described your process (using less lye than now -
 only the basic amount for virgin oil, though you use WVO):

 I use 3.5 grams of lye and 150 ml methanol in the process and do not
 titrate.
 The mixing takes two or three hours, just to make sure that the whole
 reaction has taken place.
 Temperature is 15ˆžC or a bit more.
 The oil I use is WVO ( soya ), which has been used for one or two days to
 bake fish in.
 After processing, I let it stand for a week or more. I don't wash the BD
(
 not that I recommend this way of working, but in my case it works OK ).
 The pH of the BD is just over 7.

 Plus that you don't separate the by-product, just leave it there and
 draw biodiesel off the top, and that you measure pH with litmus
 paper, not the best way.

 I commented: Not enough lye for WVO and 25ml excess methanol (12.5%
 stoich for soy) is unlikely to be enough, especially at such low
 temps for only three hours.

 I suggested you do a wash test:

  Have you ever tried washing your biodiesel? I'd be interested to know
  what happens. Will you try this? Put 150 ml of your biodiesel in a
  half-litre glass jar, add 150 ml of water (preferably distilled water
  if you have it, or just tap water if not), screw the lid on tight,
  and shake it up and down violently for 10 seconds or more. Tell us
  what happens next.

 This is what happened next - you wrote:

  Surprised about what happened : 3 layers. The top layer must be BD
 ( same color as it always is ), and than a rather thick layer of
 white flaky stuf, and a layer of troubled water. pH of the BD layer
 is still just over 7 (measured with litmus paper ).

 I wasn't surprised - well, a little surprised that it separated at
 all, and I'd guess it only did that because you let it settle for so
 long.  ... you now have a visible measure of the extent to which the
 whole reaction has taken place, or perhaps hasn't. That white layer
 should be at most very thin, hardly more than a slick.

 I suggested various things you could try next to improve your
 process/product, but didn't try to push you into titration and using
 the right amounts of lye and methanol, heating, and washing: Other
 people using different oils and in different circumstances might not
 get it to work so well, but that's not your problem, and you didn't
 recommend it.

 But you didn't respond, and now it seems you are recommending it. And
 questioning why anyone would prefer to use the Foolproof acid-base
 process. The acid-base process is probably the best method available
 because it gives consistently high-quality results, even with
 poor-quality oils, with lower amounts of inputs and producing less
 by-products.

 But from the above I can only assume that you aren't very interested
 in the best quality but only in poor-quality fuel, poorly made, as
 long as it doesn't seem to damage your engine. Yet.

 You didn't succeed when you tried the Foolproof method. It's not for
 novices, we and others always recommend starting

Re: [biofuel] Foolproof method

2004-02-14 Thread Pieter Koole

x-charset ISO-8859-1I am very sorry if I suggested to put other people off 
the methods you
recommend.
Perhaps it is allso caused by not using the right terms ( I am not from an
English speaking country ).
Again, very sorry and as said in another mail, I will try it again and do it
exactly as you advise.
Keep you informed.

Met vriendelijke groeten,
Pieter Koole
Netherlands.

The information contained in this message (including attachments) is
confidential, and is intended for the addressee(s)
only.  If you have received this message in error please delete it and
notify the originator immediately.  The unauthorized use, disclosure,
copying or alteration of this message is strictly forbidden. We will not be
liable for direct, special, indirect or
consequential damages arising from alteration of the contents of this
message by a third party or in case of electronic communications as a result
of any virus being passed on.


- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, February 14, 2004 8:26 AM
Subject: Re: [biofuel] Foolproof method


 Dag Pieter

 Maar...

 Hi all,
 Maybe a stupid question, and with all respect to Aleks, but I am making
BD
 now for allmost two years, using the single base methode, without
titration,
 just use 150 liter methanol and 4.5 kg NaOH per 1000 liter used vegatable
 oil. Let it sit for at least a week and very slowly drain(?) what is the
 right word ? it from the top through a fine filter. I have never whashed
the
 BD.
 I have driven over 140.000 km now without any problems.
 What would be the main reason to change to the fool proof method ?
 I am very willing to learn, so I hope nobody reads this as if the fool
proof
 method would not be better. I just do not know why it would be better.

 But you HAVE had your problems, haven't you? If not with your
 Citroen, yet. You couldn't manage to separate the glycerine and FFA
 in your by-product, despite a lot of help and advice here, and that's
 dead easy - as I said at the time, it indicated something else was
 wrong. Then you described your process (using less lye than now -
 only the basic amount for virgin oil, though you use WVO):

 I use 3.5 grams of lye and 150 ml methanol in the process and do not
 titrate.
 The mixing takes two or three hours, just to make sure that the whole
 reaction has taken place.
 Temperature is 15ˆžC or a bit more.
 The oil I use is WVO ( soya ), which has been used for one or two days to
 bake fish in.
 After processing, I let it stand for a week or more. I don't wash the BD
(
 not that I recommend this way of working, but in my case it works OK ).
 The pH of the BD is just over 7.

 Plus that you don't separate the by-product, just leave it there and
 draw biodiesel off the top, and that you measure pH with litmus
 paper, not the best way.

 I commented: Not enough lye for WVO and 25ml excess methanol (12.5%
 stoich for soy) is unlikely to be enough, especially at such low
 temps for only three hours.

 I suggested you do a wash test:

  Have you ever tried washing your biodiesel? I'd be interested to know
  what happens. Will you try this? Put 150 ml of your biodiesel in a
  half-litre glass jar, add 150 ml of water (preferably distilled water
  if you have it, or just tap water if not), screw the lid on tight,
  and shake it up and down violently for 10 seconds or more. Tell us
  what happens next.

 This is what happened next - you wrote:

  Surprised about what happened : 3 layers. The top layer must be BD
 ( same color as it always is ), and than a rather thick layer of
 white flaky stuf, and a layer of troubled water. pH of the BD layer
 is still just over 7 (measured with litmus paper ).

 I wasn't surprised - well, a little surprised that it separated at
 all, and I'd guess it only did that because you let it settle for so
 long.  ... you now have a visible measure of the extent to which the
 whole reaction has taken place, or perhaps hasn't. That white layer
 should be at most very thin, hardly more than a slick.

 I suggested various things you could try next to improve your
 process/product, but didn't try to push you into titration and using
 the right amounts of lye and methanol, heating, and washing: Other
 people using different oils and in different circumstances might not
 get it to work so well, but that's not your problem, and you didn't
 recommend it.

 But you didn't respond, and now it seems you are recommending it. And
 questioning why anyone would prefer to use the Foolproof acid-base
 process. The acid-base process is probably the best method available
 because it gives consistently high-quality results, even with
 poor-quality oils, with lower amounts of inputs and producing less
 by-products.

 But from the above I can only assume that you aren't very interested
 in the best quality but only in poor-quality fuel, poorly made, as
 long as it doesn't seem to damage your engine. Yet.

 You didn't succeed when you

Re: [biofuel] Foolproof method

2004-02-13 Thread Pieter Koole

x-charset ISO-8859-1Hi all,
Maybe a stupid question, and with all respect to Aleks, but I am making BD
now for allmost two years, using the single base methode, without titration,
just use 150 liter methanol and 4.5 kg NaOH per 1000 liter used vegatable
oil. Let it sit for at least a week and very slowly drain(?) what is the
right word ? it from the top through a fine filter. I have never whashed the
BD.
I have driven over 140.000 km now without any problems.
What would be the main reason to change to the fool proof method ?
I am very willing to learn, so I hope nobody reads this as if the fool proof
method would not be better. I just do not know why it would be better.


Met vriendelijke groeten,
Pieter Koole
Netherlands.

The information contained in this message (including attachments) is
confidential, and is intended for the addressee(s)
only.  If you have received this message in error please delete it and
notify the originator immediately.  The unauthorized use, disclosure,
copying or alteration of this message is strictly forbidden. We will not be
liable for direct, special, indirect or
consequential damages arising from alteration of the contents of this
message by a third party or in case of electronic communications as a result
of any virus being passed on.


- Original Message -
From: Scott Alexander [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, February 12, 2004 11:44 PM
Subject: [biofuel] Foolproof method


 I wanted to try Alek's foolproof method, but the couple of sites that
 I've found via the Internet for sulfuric acid and phosphoric acid make
 them seem quite expensive.  Presumably that means that I'm looking in
 the wrong place.  Where should I go to get these at reasonable prices?

 Thanks,
 Scott




 Biofuel at Journey to Forever:
 http://journeytoforever.org/biofuel.html

 Biofuels list archives:
 http://archive.nnytech.net/index.php?list=biofuel

 Please do NOT send Unsubscribe messages to the list address.
 To unsubscribe, send an email to:
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/x-charset


Re: [biofuel] Foolproof method

2004-02-13 Thread Pieter Koole

Hi Todd,
What prices are you mentioning ??
In Holland I pay  0,80 per liter acid, which can be sulfuric acid (98%) or
posphoric acid (80%).
I think you should try to find an industrie where they use a lot of this
stuf and buy some from them.

Met vriendelijke groeten,
Pieter Koole
Netherlands

The information contained in this message (including attachments) is
confidential, and is intended for the addressee(s)
only.  If you have received this message in error please delete it and
notify the originator immediately.  The unauthorized use, disclosure,
copying or alteration of this message is strictly forbidden. We will not be
liable for direct, special, indirect or
consequential damages arising from alteration of the contents of this
message by a third party or in case of electronic communications as a result
of any virus being passed on.


- Original Message -
From: Appal Energy [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, February 13, 2004 5:32 AM
Subject: Re: [biofuel] Foolproof method


 Try a warehouse for commercial/municipal pool/water treatment. You should
be
 able to get either for less than $20 a gallon, more like $12 for sulfuric
 and $18 for phosphoric.

 If all else fails, contact Aqua Science in Columbus, Ohio, 614-252-5000
and
 ask if they know of any industrial supply house(s) in the
 Philadelphia-Baltimore area. There have to be several.

 Todd Swearingen

 - Original Message -
 From: Scott Alexander [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Thursday, February 12, 2004 5:44 PM
 Subject: [biofuel] Foolproof method


  I wanted to try Alek's foolproof method, but the couple of sites that
  I've found via the Internet for sulfuric acid and phosphoric acid make
  them seem quite expensive.  Presumably that means that I'm looking in
  the wrong place.  Where should I go to get these at reasonable prices?
 
  Thanks,
  Scott
 
 
 
 
  Biofuel at Journey to Forever:
  http://journeytoforever.org/biofuel.html
 
  Biofuels list archives:
  http://archive.nnytech.net/index.php?list=biofuel
 
  Please do NOT send Unsubscribe messages to the list address.
  To unsubscribe, send an email to:
  [EMAIL PROTECTED]
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 To unsubscribe, send an email to:
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