Re: CS>Adding peroxide to CS
From: Paul Holloway
Date: Thu, 19 Aug 2004 01:19:18
http://escribe.com/health/thesilverlist/m72654.html

  > Peroxide you  buy  at the drug store or  Walmart  usually contains
  > phenacetin as a stabilizer.

  > Some people  like to avoid phenacetin, as it is toxic,  though the
  > small quantities in peroxide may not cause a problem.

  > It was  used as a painkiller, but was taken off the market  due to
  > toxicity. If this concerns you, you can buy food grade peroxide at
  > some health food stores, or online.

  > Paul H

  Dear Paul,

  Thank you  very  much for posting this  information!  I  checked the
  toxicity, but  it is at such a low concentration (<  0.05%)  that it
  should have little effect:

    http://www.uiowa.edu/~chemsafe/MSDS/HydrogenPeroxide.htm

  The reason  I am so pleased with your post is you  have  explained a
  nagging problem I was having with adding H2O2 to cs. Normally, I use
  about 1/2 teaspoon per litre, which is about 40 parts per billion of
  H2O2.

  Here are the calculations:

    1/2 tsp H2O2 = 1.23 milliliters

  But, H2O2 used is 3% concentration, so the actual amount of H2O2 is

    1.23 milliliters * 0.03 = 0.0369 milliliters H2O2

  Now, 1 ppm = 1 milliliter per litre

  So 0.0369 milliliters = 0.0369 ppm, or ~40 parts per billion

  The problem is the amount of silver oxide in typical cs may be  5 to
  10 percent of the total. So if you have 20ppm ionic, you may  have 1
  to 2 ppm of oxides.

  However, the  40 ppb H2O2 can clear up a yellow  solution overnight,
  and keep  it clear. This means the H2O2 acts as a  catalyst,  and is
  not consumed in the reaction.

  My problem  is  what  keeps the H2O2  from  disassociating?  And you
  supplied the answer: phenacetin!

  Thanks Very Much!

Best Wishes,

Mike Monett


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