On Aug 3, 2007, at 4:40 PM, Michel Jullian wrote:

Hi Horace,

----- Original Message -----
From: "Horace Heffner" <[EMAIL PROTECTED]>
Sent: Friday, August 03, 2007 3:28 AM

On Aug 2, 2007, at 3:05 AM, Michel Jullian wrote:


1/ Fill the cell container e.g. a test tube made of the right
dielectric material (e.g. a clear plastic e.g. polycarbonate...
e.g. CR-39 !) with the electrolyte we will be using for normal
operation (that for PdD codeposition)

Some polycarbonate characteristics:

http://www.3d-cam.com/materials/polycarbonate.asp

Good resource, let me quote the most relevant data:

For direct electroplating:

"Electrical Resistivity 1E+14-1E+17 ohm-cm"
say 1E+17 ohm-cm = 1E+15 ohm-m (highest value = worst case)

For cathode electron density enhancement:

"Dielectric Constant 2.9-3.2"
say 3  (a typical value for plastics, 3 times that of vacuum or air)
"Dielectric Strength 399-1780 kV/in"
that's 15.7 to 70 kV/mm (quite good, 5 to 20 times that of air, the test tube you mention below must be at least 1mm thick so it will probably stand 25kV across its wall as projected)

So the maximum surface electron density on the cathode backside will be 3x5=15 to 3*20=60 times that achievable by using air as a dielectric, very nice.

Really good thermal properties, not so good on conductivity.  I seem
to recall CETI had a process for plating plastic beads, by chemically
treating the surface first, but I don't know if that could be made to
work with polycarbonates.

I see Cole-Parmer sells some very nice polycarbonate test tubes at
$27.00 for a 10 pack.

http://www.coleparmer.com/catalog/product_view.asp?sku=0632932

It seems an excellent choice indeed:

"Specifications:
Capacity (mL)15
Dimensions 16.1 mm OD x 114.3 mm H"
(cylinder of diameter 16.1mm and length 114.3-8=106.3mm terminated by half sphere of diameter 16.1mm)

The above data should allow us to:

1/ Find external volume of test tube (cylinder+half sphere)
2/ Subtract capacity to find volume of polycarbonate
3/ Find area of outer surface of test tube (cylinder+half sphere)
4/ Deduce thickness t of polycarbonate (volume / area)
5/ Find electrical resistance of tube wall (from area, thickness and resistivity see http://en.wikipedia.org/wiki/Resistivity )
6/ Find leakage current at 25 kV (Ohm's law)
7/ Find how long it would take at this current to electroplate a useful thickness say one micron of PdD (Faraday's law), if too long some other way will have to be found.

The above are easy. I expect it will take some chemical processing of the plastic. James Patterson sulfonated his plastic beads before plating them chemically I think. If I recall the process was spelled out in detail in one of his patents. Such treating will change the insulating and dielectric characteristics though.

Also, I am not convinced there will not be charge neutralization at the metal-plastic boundary. This can happen via formation of neutral hydrogen. The expected high density charge on the metal side of the dielectric can be neutralized by hydrogen desorbing and taking up the excess electrons there. One of the problems with the Patterson beads and follow-on bead versions was metal film separation. That will only be made worse by a strong field and surface charge from the dielectric.


8/ Find the average electron density in the cathode at 25kV polarization (parallel plate capacitor equations)

Here it gets difficult. This is at minimum a multi-body Shrödinger equation computation based on various assumptions about surface loading and immediate subsurface loading. I don't know the capability actually exists.


9/ Deduce the factor by which the device will enhance the natural DD fusion rate in PdD (natural = that for an electron density equal to the proton density)
10/ Deduce the resulting fusion power

This is never never land. Only experiment is a reasonable approach to this.


How shall we proceed, you do the maths and I check them?

I'm not comfortable with the basic approach yet. I need time to think but have many other things happening at the moment. This is definitely very interesting though.

Are you thinking of doing an experiment? I definitely don't have the resources here in my home to handle the chemicals involved. I also have other unrelated experiments in the queue I am trying to get to. I think more talking is the way to go for now. At least it is inexpensive, and it might save a lot of time and money. I might be a bit slow to respond though.


Horace Heffner
http://www.mtaonline.net/~hheffner/



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