Used to be, I am out of touch, that less than 100°F and 100% SOC was a
recipe for significant battery degradation. Not say they haven't solved
this, but 5 year old cells would not be very good in this respect.

On Wed, Jul 8, 2020 at 8:06 PM Bill Dube via EV <[email protected]> wrote:

> I don't think that LiFePO4 has made any remarkable gains in specific
> energy.
>
> What LiFePO4 does have is spectacular cycle life. If manufactured with
> some degree of care, you get 15,000+, 100% SOC, 1C cycles @ 25 Celsius
> from LiFePO4 without going below 50% of the original capacity. They just
> keep going and going.... You have to seal the case well enough to keep
> air and water out, and use paste, separators, etc. that are also
> reasonably free of water and air on the inside.
>
> Thus, a "million mile" battery has always be possible to make with
> LiFePO4 cells. You just have to be motivated to use quality cells, and
> to actually build it. You also need to be motivated to drive the car
> that many miles. :-)
>
> 200 miles per charge, times 15,000 charge cycles = 3,000,000 miles. Even
> at 5000 cycles, that run-of-the-mill LiFePO4 cells achieve, this gets
> you a million miles.
>
> Bill D.
>
>
> On 7/7/2020 7:43 PM, EVDL Administrator via EV wrote:
> > While I was looking for other information a couple of days ago, I ran
> across
> > something on the web that surprised me.  I didn't follow up at the time
> and
> > now I've lost track of where it was, but maybe someone else here knows
> > something about it.
> >
> > The post or article I saw claimed that Tesla's supposedly-upcoming much-
> > discussed "million mile battery" is lithium iron phosphate chemistry.
> >
> > LiFePO4 was something of an EV holy grail 15-20 years ago.  Valence was
> > offering their Saphion phosphate-based lithium modules around 2002.  A123
> > was also an early LiFePO4 booster.  Both claimed long cycle life and
> > improved safety, and A123s were also known for ferocious specific power.
> >
> > When the cheap and cheerful Chinese low-power versions from Thundersky,
> > CALB, and others started to appear in the States, a lot of them went
> into EV
> > conversions.  You can find discussions about this in the EVDL archive
> around
> > 2006-2009.
> >
> > If memory serves, the main downside to LiFePO4 was specific energy.  It
> just
> > wasn't as good as what cobalt and manganese based chemistries offered.
> >
> > I also seem to recall some kind of patent-related LiFePO4 problem.  This
> may
> > have been the reason that hobbyists jumped on the cheap and cheerful
> Chinese
> > LiFePO4 cells from Thundersky, CALB, and the like.  Again dredging up
> from
> > memory, I think that hose companies somehow (allegedly) made an end run
> > around the patent and licensing concerns.
> >
> > Now, if I'm not mistaken, Tesla's development partner in the "million
> mile
> > battery" is a Chinese firm.  That's ... uh ... interesting.
> >
> > So has the EV world rehabilitated lithium iron phosphate's reputation?
> Has
> > its specific energy problem been solved?  What about licensing and
> patents?
> >
> > David Roden, EVDL moderator & general lackey
> >
> > To reach me, don't reply to this message; I won't get it.  Use my
> > offlist address here : http://evdl.org/help/index.html#supt
> >
> > = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = =
> >       A developed country is not a place where the poor have cars.
> >       It's where the rich use public transportation.
> >
> >                                      -- Gustavo Petro
> > = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = =
> >
> > _______________________________________________
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> >
>
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>
>

-- 
Michael E. Ross
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