you probably got an air bubble in the grease, it's easy  enough to do. 
remove the heatsink, wipe off the old grease and try again.  one method
i've used, is to put a smooth line of grease on one edge of the chip,
put the heat sink at an angle about where it goes touching that edge,
and then rotate it on squeezing the grease towards the far side as you
rotate the heat sink on.  also of course make sure all of the clamps are
on.  a cooler heat sink is a sure sign of trouble, you know the chip is
getting hot, and that heat needs to be moved to the heatsink so it can
be dissipated.  also remember to use the grease sparingly, with my trick
you should press/squeeze hard enough to press out most of it as you
rotate the heatsink on, you can remove the excess with a q-tip etc. but
it shouldn't be a problem if some is on the edges.  you should see a
little squeeze out on the 3 edges other than the one you applied it to. 
now you see why the film is so much easier in manufacturing.  definitely
check the temp immediately after you power it up again and if it's
remotely that hot shut it down immediately before you cook the chip,
100c is too hot and you risk permanent damage to the chip, which in some
cases will also make it hotter.  are you sure you got grease on the
processor?  at least on some machines the cache or bus interface chips
also touch the heatsink, you'll want to grease them all.

"Eric B. Richard son" wrote:
--------- 
> Okay, I did that, and the sensor is reading even hotter in the XLR8
> Mach Speed Control now.
> 
> Could there be something else going on? The thermal sensor is reading
> 100C, ie hot enough to boil water, but the metal casing in the box
> right above the heat sink is room temp. I don't feel any heat,
> nothing. My iBook gets a whole lot hotter. I don't get it. And as
> yet, there seems to be no effect on computing. In fact, it is reading
> this when the only program running is the XLR8 MSC.
--------

-- 
So, in the middle of concern over corporate honesty, and the honesty of
Dick Cheney and Haliburton, the DOD gives Haliburton a $10 million
dollar contract to build prisoner cells for quantanamo bay, something
they've never done before, and hardly related to the oil equipment
business, now that's leadership by example, bad example.

-- 
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