As far as I know, Semiletoc and Shakhova observed methane releases but
there is as yet no evidence of increases in methane release:

http://dotearth.blogs.nytimes.com/2011/12/27/leaders-of-arctic-methane-project-clarify-climate-concerns/

The best piece I have read on likely climate effects of methane releases is:

http://www.realclimate.org/index.php/archives/2012/01/much-ado-about-methane/


On Tue, Feb 21, 2012 at 10:04 AM, Stephen Salter <[email protected]> wrote:

> **
> Ken
>
> I understand that methane concentrations are now about 1.8 parts per
> million, still much less than those of CO2 but that methane accounts for
> about one third of the warming of CO2.  Would things change if there were
> sudden large increases in the rate of methane release as suggested by
> Semiletov and Shakhova?
>
> Stephen
>
>
> Emeritus Professor of Engineering Design
> Institute for Energy Systems
> School of Engineering
> Mayfield Road
> University of Edinburgh EH9  3JL
> Scotland
> Tel +44 131 650 5704
> Mobile 07795 203 195www.see.ed.ac.uk/~shs <http://www.see.ed.ac.uk/%7Eshs>
>
>
> On 21/02/2012 17:17, Ken Caldeira wrote:
>
> The higher climate sensitivities (e.g. approaching 10 C per CO2 doubling)
> are highly unlikely for this century and, if such sensitivities are real
> (which I also deem unlikely), likely they would be the product of feedbacks
> occurring on timescales of thousands of years (e.g. ice sheets).
>
> The climate models include most of the feedbacks that occur on the time
> scale of a century or less, and therefore likely reflect the sensitivity
> that is most relevant to most people living this century (e.g., about 3 C
> per CO2 doubling).
>
> I could believe that Earth System Sensitivity (millennial scale) is twice
> that of Charney Sensitivity (decadal scale).
>
> -------------
>
> At higher CO2 levels, due to diminished ocean CO2 uptake, each CO2
> emissions contributes more to atmospheric CO2 increase, but each increment
> of increase has less of a radiative effect. These two effects largely
> cancel each other but not of course precisely.  There was a paper that went
> into this more carefully but I cannot put my finger on it, having looked
> for it.
>
> At the highest CO2 levels, you are of course right that essentially all of
> the CO2 is partitioned into the atmosphere, but the radiative effect will
> be small, so the tendency is towards decreasing radiative forcing with each
> emission. But, before the radiative forcing from each emission becomes
> negligible, we will be living inside of a toaster.
>
> For an approximation that is close enough for policy purposes, you are not
> far off if you assume that each CO2 emission this century produces another
> increment of warming, where this warming takes a few decades to manifest
> itself. The imperfection of the chemistry/physics cancellation might be
> something like a 20% error this century (although I have not recently gone
> through the numbers and cannot fully attest to this).
>
>
> On Tue, Feb 21, 2012 at 7:35 AM, Robert Chris <[email protected]>wrote:
>
>> Ken
>>
>> Thanks for replying to my email.  You were right.  The Google Group
>> worked much quicker than I'd anticipated.
>>
>> There's quite a lot of technical material here for a humble social
>> scientist to digest.  On a quick scan the message I get is that the
>> forcing is logarithmic but climate sensitivity is linear because of
>> compensating feedbacks in the climate system.  Although it does seem
>> to me that if the forcing is logarithmic there must come a point where
>> the absorptive capacity of the GHGs is so small that incremental
>> emissions will not produce any more global warming.  Moreover, there
>> must be a point where the oceans are also largely saturated and take
>> up little more CO2.  However, the point where climate sensitivity does
>> reduce to close to zero, might not be reached before we're all fried
>> and the oceans are nigh on dead.  If that brief extrapolation makes
>> sense, has anyone attempted to estimate where those limits might be?
>>
>> What has jumped out at me from these replies is the Wasdell paper.  He
>> is highlighting the distinction between the Charney and ESS approaches
>> to the quantification of climate sensitivity.  This is not an academic
>> peer-reviewed paper although he does refer to several but if he is
>> correct that climate sensitivity now looks like it might be closer to
>> 10degC rather than 3degC, that should send alarm bells ringing that I
>> certainly don't hear.  Is that because ESS is not yet sufficiently
>> robust for it to replace Charney; simply because the material has yet
>> to be published, or because even though CS might be three times higher
>> than previously thought, the time lag before the equilibrium is
>> reached is such that things won't warm up that much faster in the
>> short term and therefore no one's too concerned about it yet?
>>
>> But if ESS does provide a more accurate valuation of CS and it is
>> about 10degC, what policy implications might that have for the timing
>> of geoengineering deployments?
>>
>> Robert Chris
>>
>>
>>
>> On Feb 20, 9:48 pm, Ken Caldeira <[email protected]>
>> wrote:
>> > The attached papers are relevant.
>> >
>>  > On Mon, Feb 20, 2012 at 11:32 AM, David Mitchell <
>> [email protected]>wrote:
>>  >
>> >
>> >
>> >
>> >
>> >
>> >
>> > > From paleoclimate data with a geologic time-scale, climate
>> sensitivity may
>> > > be ~ 2.7 times larger than the Charney value of ~ 3 deg. C ( climate
>> > > feedback factor 0.75 deg. C/W m2; characteristic of the fast
>> feedbacks in
>> > > GCMs) based on a recent paper from Jeff Kiehl:
>> > >  Kiehl, J., 2011: Lessons from Earth's Past. Science, Vol. 331, 14
>> Jan.,
>> > > 158-159, DOI: 10.1126/science.1199380.
>> >
>> > > David Wasdell has written about climate sensitivity featuring the
>> work of
>> > > Kiehl and others (see attached) but I don't know whether that
>> document ever
>> > > got published.  Wadham's paper discusses some of the arguments Mike
>> has
>> > > made.
>> >
>> > > These papers do not indicate or suggest that climate sensitivity may
>> save
>> > > us from global warming.
>> >
>> > > David Mitchell
>> >
>> > > On 2/20/2012 8:57 AM, Mike MacCracken wrote:
>> >
>> > >> Just to be clear--
>> >
>> > >> The radiative forcing due to CO2 increases is logarithmic--that is,
>> the
>> > >> radiative forcing going from 300 to 600 ppm is the same as going
>> from 600
>> > >> to
>> > >> 1200 ppm. Thus, the forcing due to the rising CO2 concentration does
>> > >> decrease on a per ppm basis.
>> >
>> > >> However, forcing is not sensitivity, and like Tom Wigley, I recall
>> papers
>> > >> that have done a good bit of testing of plausible changes in
>> concentration
>> > >> and the sensitivity (that is, the temperature change for a doubling
>> of the
>> > >> CO2 concentration) is, near as it can be estimated, pretty linear. At
>> > >> lower
>> > >> temperatures one may have more snow/ice albedo feedback, but at
>> higher
>> > >> temperatures one has more water vapor and, very likely, carbon cycle
>> > >> feedback (carbon cycle feedback including thawing permafrost and
>> releasing
>> > >> CO2/CH4, out-gassing of CO2 from warmer ocean, higher airborne
>> fraction as
>> > >> ocean overturning slows, etc.). Given the warmth of the Cretaceous,
>> it is
>> > >> hard to be sanguine about adding more and more CO2 to the
>> atmosphere. And
>> > >> given the heat of Venus, which absorbs less solar per square meter
>> than
>> > >> the
>> > >> Earth even though closer to the Sun, it seems really difficult to
>> argue
>> > >> that
>> > >> adding greenhouse gases to an atmosphere leads to a plateau in the
>> > >> response.
>> >
>> > >> Mike MacCracken
>> >
>>  > >> On 2/20/12 7:38 AM, "Tom Wigley"<[email protected]>  wrote:
>> >
>> > >>  Sensitivity is the equilibrium change in global-mean temperature per
>> > >>> unit of radiative forcing. Linearity has been demonstrated up to
>> much
>> > >>> higher forcings than will ever be reached by even the most
>> pessimistic
>> > >>> scenarios.
>> >
>> > >>> Early IPCC reports might cover this. I recall work by Kiehl on this
>> back
>> > >>> in the mid 1980s -- too far back to recall the reference.
>> >
>> > >>> Tom.
>> >
>> > >>> +++++++++++++++++
>> >
>> > >>> On 2/20/2012 5:28 AM, Robert Chris wrote:
>> >
>> > >>>> I am engaged in discussion with a modestly prominent climate
>> skeptic
>> > >>>> who argues that global warming isn't a problem because as CO2
>> > >>>> concentrations rise climate sensitivity reduces.  I recall coming
>> > >>>> across this notion before but I don't know how much peer-reviewed
>> work
>> > >>>> has been done on it.  I'd appreciate some help with references to
>> peer-
>> > >>>> reviewed papers that address the idea that climate sensitivity may
>> be
>> > >>>> logarithmic rather than linear so that as atmospheric CO2
>> > >>>> concentrations rise the effective climate sensitivity reduces and
>> > >>>> discuss the likely levels at which this reduction becomes
>> significant
>> > >>>> in terms of reducing the GWP of CO2.
>> >
>> > >>>> -----------------------------
>> > >>>> Robert Chris
>> > >>>> The Open University
>>  > >>>> [email protected]
>> >
>> > > --
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>> > > *googlegroups.com <geoengineering%[email protected]>.
>> > > For more options, visit this group athttp://groups.google.com/**
>> > > group/geoengineering?hl=en<
>> http://groups.google.com/group/geoengineering?hl=en>
>> > > .
>> >
>> >
>> >
>> >  Reisinger_et_al_ERL2011.pdf
>> > 570KViewDownload
>> >
>> >  Caldeira_Kasting_Nature1993.pdf
>> > 417KViewDownload
>> >
>> >  Pagani_et_al_Science2006.pdf
>> > 291KViewDownload
>> >
>> >  Matthews_et_al_Nature2009.pdf
>> > 496KViewDownload
>> >
>> >  Matthews_Caldeira_GRL2008.pdf
>> > 716KViewDownload
>>
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