In a message dated 9/12/00 7:05:21 AM EST, [email protected] writes:

<< Subj:     Re: CS>Re: Generating "Sputtered" HVAC CS
 Date:  9/12/00 7:05:21 AM EST
 From:  [email protected] (Ivan Anderson)
 Reply-to:  [email protected]
 To:    [email protected]
 
 
 ----- Original Message -----
 From: <[email protected]>
 
 > Ivan: That old chestnut, Ivan? It can be demonstrated,
 thermodynamically,
 > kinetically, and impirically that silver ain't goin to oxidize under
 these
 > conditions. Let's go down the impirical road, for example. If I choose
 to, I
 > can deposite the silver from the molten ball DIRECTLY to the side of
 the
 > Pyrex container which holds the water bath. I've done this,
 inadvertantly, on
 > more than one occasion. The deposited silver has a mirror finish. So
 where is
 > the oxide?
 
 Roger I don't know, maybe there isn't any oxide formation, or perhaps
 the deposited silver has some oxide content, or perhaps the slow cooling
 on the side of the vessel aided in oxide decomposition.

Ivan: OK How about doing the following: If deposited silver has dissolved 
oxide and you're right that it experiences slow cooling on the side of the 
vessel then it should separate as a separate oxide phase which should be 
observable under the microscope. I will check for this possibility by 
re-depositing the silver on a microscope slide.
 
 >  You may also find that a pulsed DC supply would give you superior
 results.
 >
 > Ivan: Superior to what? I form no nitrates/nitrites. I don't even need
 to
 > monitor them (but I still do for added safety), unlike other HVAC CS
 methods.
 > My product is as potent at 1 PPM as it is at 5 PPM, and many people
 who have
 > used it report  excellent results.
 >
 > Roger
 
 I wasn't really thinking of the formation of other compounds Roger, just
 noting that the physical stability of the arc would probably benefit
 from having a shielding gas,
 which could easily be provided by using a TIG or MIG welding torch to
 carry your free electrode.

Ivan: I'm not a welder so would you please give me some background about a 
TIG and MIG welding torch.

The ability to strike and maintain an arc in an inert atmosphere is far, far 
easier than in free air.

Ivan: My arc is very stabile as long as the distance between the tip of the 
silver and the water is less that an inch or so (actually, this max distance 
depends on how far I'm into the run) AND the conductivity of the water does 
not get too high. As more and more CS is deposited into the water, 
conductivity continues to rise so I must continue to raise the height of the 
electrode (it's not much of an inconvenienve since the entire run takes 
several hours) above the water to compensate. I terminate the run when the 
electrode must be so high to compensate for the relatively high water 
conductivity, to produce arc instability. I don't consider this relationship 
to be a practical problem because I still can generate 30-60 PPM which is 
much much greater than the concentration I use (I like to use 1-3 PPM CS 
concentration, and consider anything above that to be wasteful). In any case, 
would a DC arc help to continue the run if I wanted to make a super potent 
HVAC CS?
 
 I must try a DC arc and see what sort of results can be achieved.
 
Ivan: Good. It took as while, but we finally made you curious enough to "have 
a go". With your welding experience and more formal biochem training, your 
observations and suggestions will be quite valuable. Roger
 
  


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