Re: [Biofuel] methoxide solution - missing scale

2005-10-21 Thread lendzian_michael
Brian, so I guess you were never the cadillac-man type?

This is your situation.  You've got yourself a Caddy of a PH Tester.  
Enjoy.

Michael Lendzian
CINS Network Support Team
Columbus State University
CINS/Center for Commerce  Technology Room 105
706.569.3044 (help desk)


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Re: [Biofuel] methoxide solution - missing scale

2005-10-21 Thread Joe Street
I'd say that is a sweet deal!  Do you have a calibration solution to 
verify the probe is not screwed? I work in a university and I wouldn't 
be surprised at all to grab a fine instrument and find out someone had 
demoed the probe and not said a word.  It would be a good idea to verify 
it first. Don't be tempted to put that expensive probe in the biodiesel 
though or you may have to replace it!

Joe

Brian Rodgers wrote:

Holy cow!
I asked for it and I received a doozy.
The pH meter the university lent me is a bit of overkill I should
think. Tell me what you think.
Sitting here on my desk is a Texas Instruments TI-83 Plus Silver
edition.  I already figured out to turn it on and off, pretty good,
hey!
It has a manual on CD  five firewire ports and a fancy probe sitting
in its own bath.
AM I in for it with this thing? I mean, I want to do a good titration
but really???
Brian Rodgers

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Re: [Biofuel] methoxide solution - missing scale

2005-10-21 Thread David Howard
A pH meter using a Ti-83? I never heard of such a thing, not surprising,
I'll need to look into that. I've got a TI-83 Plus collecting dust at
the moment. Time to Google I guess. 
David 

-Original Message-
From: [EMAIL PROTECTED]
[mailto:[EMAIL PROTECTED] On Behalf Of Brian Rodgers
Sent: Thursday, October 20, 2005 6:33 PM
To: Biofuel@sustainablelists.org
Subject: Re: [Biofuel] methoxide solution - missing scale

Holy cow!
I asked for it and I received a doozy.
The pH meter the university lent me is a bit of overkill I should think.
Tell me what you think.
Sitting here on my desk is a Texas Instruments TI-83 Plus Silver
edition.  I already figured out to turn it on and off, pretty good, hey!
It has a manual on CD  five firewire ports and a fancy probe sitting in
its own bath.
AM I in for it with this thing? I mean, I want to do a good titration
but really???
Brian Rodgers

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Re: [Biofuel] methoxide solution - missing scale

2005-10-21 Thread Brian Rodgers
Thanks everyone for the replies.
Yes it is a Ti-83 with a Vernier LabPro attachment.
This is only the second time I have had it out of the box so I still
know little about how to use it.
Today I have two other projects I need to do while daylight is
burning. First I have harvested two dozen beautiful cedar posts from
our forest. In an attempt to get our ranch more sustainable I will be
making more products from our main resource, trees. I have been using
an old timey draw knife to debark the cedar posts. This is unheard of
around here, most of the ranchers now use steel posts. Steel posts are
imported to this part of the US and for all I know they all come from
China. The heck with that. Back when the ranchers did use wooden posts
here in the southwest unpeeled cedar posts were employed. Cedar is a
great  wood for posts as it has lasting qualities not found in other
wood found locally. We have found that the wood borers like to get
under the bark and begin to deteriorate the wood quickly, Thus cedar
lasts about ten tears in the ground. Anyway, we have been peeling the
posts which is tough because our cedar is quite bracnhy. I worked out
a rig for holding the posts while I use the small chainsaw to smooth
the sides. The drawknife then slips through the bark fairly easily.

The second part of my project today is tied nicely to the first, I
worked out a trade with a local organic gardener in posts for garlic
for planting. He has fantastic growth of garlic during the last five
years and he lives up in the mountains just like us. Boy howdy, I
guaranty you haven't tasted garlic this hot and spicy. So, we are
totally inspired to expand our garden next Spring to include a large
patch of garlic. Planting time for garlic is now, he says. He has
invited me to come to his place this afternoon and learn. I will bring
the posts which he needs to build a deer proof fence as a second line
of defense from the deer, on the way back we will stop be the local
purebred horse ranch where they give away manure which has no hay or
weed seed because they have rubber mats in the stalls for the fancy
horses.

It is our plan to mix the manure with wood chips from our forest and
begin a large scale compost pile for next Spring. Yep I am going to be
a regular farmer not just a tree farmer! How scatterbrained is this?
Sorry Keith. Just teasing.

This evening I will break out the book for the TI-83 and see how to
use it. In the kit there are several probes, the one I am interested i
is a pH sensor p# PH-BTA. Now that I look at this manual it has about
fifty sensors available, starting with a 3-axis
Accelerometer...Radiation monitor... Magnetic field sensor... Light
sensor.. O2 Gas sensor, pretty much a you name it, they got it.
Sincerely,
Brian Rodgers


On 10/21/05, David Howard [EMAIL PROTECTED] wrote:
 A pH meter using a Ti-83? I never heard of such a thing, not surprising,
 I'll need to look into that. I've got a TI-83 Plus collecting dust at
 the moment. Time to Google I guess.
 David

 -Original Message-
 From: [EMAIL PROTECTED]
 [mailto:[EMAIL PROTECTED] On Behalf Of Brian Rodgers
 Sent: Thursday, October 20, 2005 6:33 PM
 To: Biofuel@sustainablelists.org
 Subject: Re: [Biofuel] methoxide solution - missing scale

 Holy cow!
 I asked for it and I received a doozy.
 The pH meter the university lent me is a bit of overkill I should think.
 Tell me what you think.
 Sitting here on my desk is a Texas Instruments TI-83 Plus Silver
 edition.  I already figured out to turn it on and off, pretty good, hey!
 It has a manual on CD  five firewire ports and a fancy probe sitting in
 its own bath.
 AM I in for it with this thing? I mean, I want to do a good titration
 but really???
 Brian Rodgers

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Re: [Biofuel] methoxide solution - missing scale

2005-10-21 Thread David Howard
I found some sites selling the individual Vernier probes and sensors.
They are more than I expected them to be ($79 - pH Meter probe) but you
can get free software. Educational products have always been
unreasonably overpriced as far a I can tell. Competition must be next to
nil in the field.  
David 

-Original Message-
From: [EMAIL PROTECTED]
[mailto:[EMAIL PROTECTED] On Behalf Of Brian Rodgers
Sent: Friday, October 21, 2005 12:28 PM
To: Biofuel@sustainablelists.org
Subject: Re: [Biofuel] methoxide solution - missing scale

Thanks everyone for the replies.
Yes it is a Ti-83 with a Vernier LabPro attachment.
This is only the second time I have had it out of the box so I still
know little about how to use it.
Today I have two other projects I need to do while daylight is burning.
First I have harvested two dozen beautiful cedar posts from our forest.
In an attempt to get our ranch more sustainable I will be making more
products from our main resource, trees. I have been using an old timey
draw knife to debark the cedar posts. This is unheard of around here,
most of the ranchers now use steel posts. Steel posts are imported to
this part of the US and for all I know they all come from China. The
heck with that. Back when the ranchers did use wooden posts here in the
southwest unpeeled cedar posts were employed. Cedar is a great  wood for
posts as it has lasting qualities not found in other wood found locally.
We have found that the wood borers like to get under the bark and begin
to deteriorate the wood quickly, Thus cedar lasts about ten tears in the
ground. Anyway, we have been peeling the posts which is tough because
our cedar is quite bracnhy. I worked out a rig for holding the posts
while I use the small chainsaw to smooth the sides. The drawknife then
slips through the bark fairly easily.

The second part of my project today is tied nicely to the first, I
worked out a trade with a local organic gardener in posts for garlic for
planting. He has fantastic growth of garlic during the last five years
and he lives up in the mountains just like us. Boy howdy, I guaranty you
haven't tasted garlic this hot and spicy. So, we are totally inspired to
expand our garden next Spring to include a large patch of garlic.
Planting time for garlic is now, he says. He has invited me to come to
his place this afternoon and learn. I will bring the posts which he
needs to build a deer proof fence as a second line of defense from the
deer, on the way back we will stop be the local purebred horse ranch
where they give away manure which has no hay or weed seed because they
have rubber mats in the stalls for the fancy horses.

It is our plan to mix the manure with wood chips from our forest and
begin a large scale compost pile for next Spring. Yep I am going to be a
regular farmer not just a tree farmer! How scatterbrained is this?
Sorry Keith. Just teasing.

This evening I will break out the book for the TI-83 and see how to use
it. In the kit there are several probes, the one I am interested i is a
pH sensor p# PH-BTA. Now that I look at this manual it has about fifty
sensors available, starting with a 3-axis Accelerometer...Radiation
monitor... Magnetic field sensor... Light sensor.. O2 Gas sensor, pretty
much a you name it, they got it.
Sincerely,
Brian Rodgers


On 10/21/05, David Howard [EMAIL PROTECTED] wrote:
 A pH meter using a Ti-83? I never heard of such a thing, not 
 surprising, I'll need to look into that. I've got a TI-83 Plus 
 collecting dust at the moment. Time to Google I guess.
 David

 -Original Message-
 From: [EMAIL PROTECTED]
 [mailto:[EMAIL PROTECTED] On Behalf Of Brian 
 Rodgers
 Sent: Thursday, October 20, 2005 6:33 PM
 To: Biofuel@sustainablelists.org
 Subject: Re: [Biofuel] methoxide solution - missing scale

 Holy cow!
 I asked for it and I received a doozy.
 The pH meter the university lent me is a bit of overkill I should
think.
 Tell me what you think.
 Sitting here on my desk is a Texas Instruments TI-83 Plus Silver 
 edition.  I already figured out to turn it on and off, pretty good,
hey!
 It has a manual on CD  five firewire ports and a fancy probe sitting 
 in its own bath.
 AM I in for it with this thing? I mean, I want to do a good titration 
 but really???
 Brian Rodgers

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 or
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 http://journeytoforever.org/biofuel.html

 Search the combined Biofuel and Biofuels-biz list archives (50,000
 messages):
 http://www.mail-archive.com/biofuel@sustainablelists.org/


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Re: [Biofuel] methoxide solution - missing scale

2005-10-20 Thread Greg and April
And unions haven't caused problems?

Greg H.


- Original Message - 
From: Kenji James Fuse [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Wednesday, October 19, 2005 22:39
Subject: Re: [Biofuel] methoxide solution - missing scale


 Please don't shop at WarMart!
 Despite the problems with the labour movement, i think all of us
 progressives on this list would agree the hostility shown by WarMart
 against organized labour is downright unacceptable. At least up here in
 kanada

 ie, a Quebec WarMart store's employees voted this past summer to unionize,
 so the store simply closed down

 KF



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Re: [Biofuel] methoxide solution - missing scale

2005-10-20 Thread Brian Rodgers
Holy cow!
I asked for it and I received a doozy.
The pH meter the university lent me is a bit of overkill I should
think. Tell me what you think.
Sitting here on my desk is a Texas Instruments TI-83 Plus Silver
edition.  I already figured out to turn it on and off, pretty good,
hey!
It has a manual on CD  five firewire ports and a fancy probe sitting
in its own bath.
AM I in for it with this thing? I mean, I want to do a good titration
but really???
Brian Rodgers

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Re: [Biofuel] methoxide solution - missing scale

2005-10-19 Thread Keith Addison
Hello Brian

I knew I should have kept my mouth shut. Hehe
Sorry I am being silly again.
Keith you do have a great web site and now that you have explained the
layered information technique I will go back again and read it all
again. I actually knew there was a great depth to the JTF site because
every time I ask a question you quickly respond with a link to another
information pool I had overlooked. You are absolutely right, there is
a lot of info there and when combined with this email list it is all
coming together for me. I take full responsibility for my words and
more so for my actions. With this in mind, can I blame the skipping of
titration of the WVO, on my wife, the ex-science teacher?

:-) You'll have to ask her about that.

 I try not to bother you all with excerpts from my daily newsletter.

You're welcome, when you've posted them before I don't think it 
bothered anybody, probably enjoyed them, I enjoyed what I read (not 
all, sorry, it's difficult to keep up right now). You're being 
selective about it.

I use my writing as a catch all to keep friends and family informed of
what  we are doing. Having not posted most of my daily chronicle you
of course don't get to see the summations of what I have learned here.
Somehow I guess I am saying that all you see are the questions I post
as I am knee deep in this.For instance in my newsletter I made note of
all of our short comings many of which you noted that day.

Okay, that makes sense to me.

After rereading this morning's newsletter I don't believe there is
anything there that would shed any light on my thinking (or lack
thereof) on this topic. Thank goodness I didn't post my verbose
newsletter, right? Basically, I state that I have a lot of respect for
you and will listen and learn.

Thankyou! The Biofuel list is an info medium and so is your 
newsletter. I think media have a purpose and a function, you aim them 
at something and then you work them to have an effect. I've thought 
for a long time that local media, eg the local rag and the local 
radio station, and informal media like 'zines and so on, are more 
interesting and useful than the big national media, in a way at 
least. The Biofuel list is global but its target is local, and 
frankly I'm probably more impressed that it reaches your network via 
your newsletter than I would be if it hit the NY Times. Don't let it 
go to your head,keep being selective! LOL!

I know that precision is better and I
need to get prepared for this weekend's chem-lab.project. I will look
in a pet store for the Phenolphthalein. I have graduated syringes and
pipettes. A triple beam scale is on the way. I looked at the Salvation
Army next store and they have a blender for $15.00.

Better!

On another thread called White lye I see that my lye may be
questionale too. I followed the link
http://journeytoforever.org/biodiesel_make2.html#lye . I was wondering
what the dark colored particles in my lye were. After reading your
description I beleive I have aluminum in there.

Probably so if it's just drain-cleaner, lye on steroids.

So, I now have to find
a source for clean lye.

That's all I have time for Keith. I know this isn't much after your
wonderful letter.

:-) I'm glad you liked it.

I guess I want you to know that I do have something
going on.

Here's to a good wind behind your sails.

Thank you for your patience.

About information layering and comprehension and so on, I said most 
people seem to get it. We receive all this feedback all the time, 
quite a lot of it's from folks doing biofuels or biodiesel. But 
there's no way of extrapolating backwards from feedback to get a true 
picture of how people are using your information, even when website 
stats show you where they go at your site and how long they spend 
there. It's just a guess. The numbers are big though, so it's 
probably not such a bad guess. (Currently around half a million 
visitors a month, 1.5 million page views.)

For instance, a new list member just joined, via JtF, not a newbie. 
He's been making biodiesel for six months, he didn't have to ask 
anybody, he just started at the beginning, tripped up a couple of 
times with the first batches, did some re-reading, got it right, 
moved on to the two-stage methods and now he uses the Foolproof 
acid-base method.

We often hear this, I reckon he's fairly typical. I think most people 
do get it about accessing the information and most are able to use 
the biodiesel information as a course they can do by themselves, and 
they learn how to make good biodiesel, but we only ever hear about it 
from just a small proportion of them.

On the other hand some people are really hard to help, and I don't 
have any clear idea of how many of them there might be either. Take 
for example the leading candidate for this week's Vivian O'Blivion 
Commemoration Award for Achievement in Failing to Notice the 
Blindingly Obvious, who had definitely visited the biodiesel section 
of the JtF website, and sent this 

Re: [Biofuel] methoxide solution - missing scale

2005-10-19 Thread Brian Rodgers
Thank you so much Keith
The final line in your previous letter gave me a full blown laugh out
loud as I was getting ready for work.
 On the other hand some people are really hard to help, and I don't
 have any clear idea of how many of them there might be either. Take
 for example the leading candidate for this week's Vivian O'Blivion
 Commemoration Award for Achievement in Failing to Notice the
 Blindingly Obvious, who had definitely visited the biodiesel section
 of the JtF website, and sent this terse message:

 Need info on making biodiesel. Thanks.

 :-/

 Keith
I stopped by one of the small town hardware stores on my way to work
this morning. I was hunting for the 99% Isopropyl alcohol I had bought
there years ago. No luck they don't carry it any longer. They did have
other alcohols which I am unfamiliar with. methyl ester ketone? (sp) 
I have no idea what that is for. It was in the paint thinner section.
As was methyl ethyl  solvent. Unfortunately the ingredients said
contains less than 4% methanol, so again I have no idea if that would
be worth anything. I was after Isopropyl and they didn't have any,
bummer. I looked at their good collection of fiberglass reinforced PVC
tubing. My mind went on a quickie scavenger hunt of uses. Then I was
off to see if they had any Phenolphthalein. Nada nothing zilch.

I know I had a plan 'B' but, at this moment it does not come to me.
I need to get back to fixing PCs here.
As soon as time permits I will respond to your letter in full.
Sincerely,
Brian Rodgers

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Re: [Biofuel] methoxide solution - missing scale

2005-10-19 Thread Zeke Yewdall
 I stopped by one of the small town hardware stores on my way to work
 this morning. I was hunting for the 99% Isopropyl alcohol I had bought
 there years ago. No luck they don't carry it any longer. They did have
 other alcohols which I am unfamiliar with. methyl ester ketone? (sp)
 I have no idea what that is for. It was in the paint thinner section.
 As was methyl ethyl  solvent.

Methyl Ethyl Ketone is used as the hardening agent in fiberglass work.
 NASTY stuff.  Ketones aren't technically alcohols anyway, if I
remember my organic chemistry right.

Unfortunately the ingredients said
 contains less than 4% methanol, so again I have no idea if that would
 be worth anything. I was after Isopropyl and they didn't have any,
 bummer.

Try looking for rubbing alcohol in a pharmacy.  I believe this is
isopropyl alcohol.

I looked at their good collection of fiberglass reinforced PVC
 tubing. My mind went on a quickie scavenger hunt of uses. Then I was
 off to see if they had any Phenolphthalein. Nada nothing zilch.

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Re: [Biofuel] methoxide solution - missing scale

2005-10-19 Thread Brian Rodgers
Thanks Zeke
I was planning on going to the dreaded WalMart this afternoon as they
are the only store left in this small town. I will be looking for
denatured alcohol there.
Brian
On 10/19/05, Zeke Yewdall [EMAIL PROTECTED] wrote:
  I stopped by one of the small town hardware stores on my way to work
  this morning. I was hunting for the 99% Isopropyl alcohol I had bought
  there years ago. No luck they don't carry it any longer. They did have
  other alcohols which I am unfamiliar with. methyl ester ketone? (sp)
  I have no idea what that is for. It was in the paint thinner section.
  As was methyl ethyl  solvent.

 Methyl Ethyl Ketone is used as the hardening agent in fiberglass work.
  NASTY stuff.  Ketones aren't technically alcohols anyway, if I
 remember my organic chemistry right.

 Unfortunately the ingredients said
  contains less than 4% methanol, so again I have no idea if that would
  be worth anything. I was after Isopropyl and they didn't have any,
  bummer.

 Try looking for rubbing alcohol in a pharmacy.  I believe this is
 isopropyl alcohol.

 I looked at their good collection of fiberglass reinforced PVC
  tubing. My mind went on a quickie scavenger hunt of uses. Then I was
  off to see if they had any Phenolphthalein. Nada nothing zilch.

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Re: [Biofuel] methoxide solution - missing scale

2005-10-19 Thread Greg and April
HEET for diesels is almost pure ( 98% or so ) Isopropanol from what I
understand.

Greg H.


- Original Message - 
From: Zeke Yewdall [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Wednesday, October 19, 2005 12:12
Subject: Re: [Biofuel] methoxide solution - missing scale


  I stopped by one of the small town hardware stores on my way to work
  this morning. I was hunting for the 99% Isopropyl alcohol I had bought
  there years ago. No luck they don't carry it any longer. They did have
  other alcohols which I am unfamiliar with. methyl ester ketone? (sp)
  I have no idea what that is for. It was in the paint thinner section.
  As was methyl ethyl  solvent.

 Methyl Ethyl Ketone is used as the hardening agent in fiberglass work.
  NASTY stuff.  Ketones aren't technically alcohols anyway, if I
 remember my organic chemistry right.

 Unfortunately the ingredients said
  contains less than 4% methanol, so again I have no idea if that would
  be worth anything. I was after Isopropyl and they didn't have any,
  bummer.

 Try looking for rubbing alcohol in a pharmacy.  I believe this is
 isopropyl alcohol.

 I looked at their good collection of fiberglass reinforced PVC
  tubing. My mind went on a quickie scavenger hunt of uses. Then I was
  off to see if they had any Phenolphthalein. Nada nothing zilch.

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Re: [Biofuel] methoxide solution - missing scale

2005-10-19 Thread Kenji James Fuse
Please don't shop at WarMart!
Despite the problems with the labour movement, i think all of us
progressives on this list would agree the hostility shown by WarMart
against organized labour is downright unacceptable. At least up here in
kanada

ie, a Quebec WarMart store's employees voted this past summer to unionize,
so the store simply closed down

KF

On Wed, 19 Oct 2005, Brian Rodgers wrote:

 Thanks Zeke
 I was planning on going to the dreaded WalMart this afternoon as they
 are the only store left in this small town. I will be looking for
 denatured alcohol there.
 Brian
 On 10/19/05, Zeke Yewdall [EMAIL PROTECTED] wrote:
   I stopped by one of the small town hardware stores on my way to work
   this morning. I was hunting for the 99% Isopropyl alcohol I had bought
   there years ago. No luck they don't carry it any longer. They did have
   other alcohols which I am unfamiliar with. methyl ester ketone? (sp)
   I have no idea what that is for. It was in the paint thinner section.
   As was methyl ethyl  solvent.
 
  Methyl Ethyl Ketone is used as the hardening agent in fiberglass work.
   NASTY stuff.  Ketones aren't technically alcohols anyway, if I
  remember my organic chemistry right.
 
  Unfortunately the ingredients said
   contains less than 4% methanol, so again I have no idea if that would
   be worth anything. I was after Isopropyl and they didn't have any,
   bummer.
 
  Try looking for rubbing alcohol in a pharmacy.  I believe this is
  isopropyl alcohol.
 
  I looked at their good collection of fiberglass reinforced PVC
   tubing. My mind went on a quickie scavenger hunt of uses. Then I was
   off to see if they had any Phenolphthalein. Nada nothing zilch.
 
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Re: [Biofuel] methoxide solution - missing scale

2005-10-18 Thread Keith Addison
Hello again Brian

snip

Now Keith, please don't take this the wrong way (negative being wrong)
has it occurred to you that maybe the flow of the JTF web site gets a
little interrupted here and there? When was the last time you sat down
with a newbie and watched as each step is absorbed and asked questions
about comprehension? Again I don't mean to offend. For all I know you
use your web page to teach newbies all the time and I am an idiot.

Actually we do, and a whole bunch of people do it on their own 
without any more help from us, and others use it as a course to teach 
other people.

It's layered information. Here's a comment from a user a few days 
ago, not untypical, but he puts it well:

Your website is very well done.  I appreciate the layers of 
technical complexity.  You have progressively more technical 
information layered in an escalating and logical fashion.  I like 
the links as each new item is introduced, the user can click for 
more specific information on a topic and it opens in a new window. 
This eliminates the tediousness of having to constantly backtrack to 
where the new concept was introduced.

But, sorry about this, maybe not if you're scatterbrained about it. A 
guy complained once about all the new windows you end up with, I 
guess people either get it or they don't. Most people seem to get it, 
and like it. We get a lot of feedback, usually something like this: 
What an excellent site. Well done! I've got thousands of them.

I'm an info pro Brian, I've been doing this sort of stuff for ever. 
There's a lot of information design in the JtF website. Some people 
want to go about it as if they expect it all to fit on a single page 
like a story they can read, but the biodiesel section at JtF is about 
half as long as the Bible and it's not a story, it's technical 
information. Linear organisation like a book just doesn't work very 
well online with that kind of material. Some of the attempts I've 
seen fail to impress, trying to do it with footnotes and so on 
doesn't work well. You have to layer it.

Anyway, thankyou, I'm very aware of how the JtF website works and 
what the constraints are.

Best wishes

Keith


Sincerely Brian Rodgers


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Re: [Biofuel] methoxide solution - missing scale

2005-10-18 Thread Keith Addison
Hello Brian

I'm sorry I spelled your name wrong, people are always doing that to 
me so I should know better. (But it was late...)

Hello Keith
Thank you for the thoughtful and considerate review of my weekend's
fun in setting up our first mixer and solution of methoxide.

I didn't want it to be a putdown but I guess it was anyway.

  Wow, the Dark Ages are back! LOL!
How true, for me I don't know about Kurt.

In the biodiesel world it harks back to the good old days that 
weren't but it was fun anyway, with people posting photographs on the 
Web of their first batch of biod, leaning over open processors with 
sparking drill motors doing the stirring and so on. A little later 
they were wearing breathing masks while leaning over their open 
processors, before it got figured out (someone asked a chemicals 
company) that not only ordinary breathing masks but even organic 
vapour masks are useless against methanol fumes. And so on. Now we 
look back and shudder and wonder why nobody even got hurt, and what 
are all those guardian angels that must've worked so hard to save our 
asses doing with themselves these days, well-deserved early 
retirement I guess. Anyway we don't want to be going back there.

  Um. Look, I really don't want to put a damper on your enthusiasm so
  I'll try not to but I'm in wonderment at the way you're going about
  it.
Not to worry I can't be dis-enthused this easy.

:-) I didn't think you could.

  This just isn't what it's all about.
What is it all about?

Couple of things beyond the immediately obvious. I think the main 
point is the context. Depends how broad you want to make it, it can 
be as broad as you like, then shrink it down to the immediate level 
and see how much of it fits.

There's this, from an altogether different thread a couple of weeks 
back, three different people:

  Anyway, I am sorry if I have cause hate and discontent.

I think you're misunderstanding. Calling you into accountability for
accuracy does NOT imply hatred or discontent. Please be careful with
your facts in the future!

snip
No need to be careful just to inspire.

Yes there is. It takes both otherwise you'll mislead. Or you've come 
to the wrong place.

Which he then cheerfully admitted, no problem.

Arguably the opposite is more true, that if you're out to inspire 
people you should be much more careful, not less, you have to take a 
long view. And get your facts right.

With biodiesel, there are two ways of going about it. One focuses on 
encouraging newbies - make it as quick and easy as possible to get 
results the first time or they'll lose interest, quick results, never 
mind what results.

So for instance one guy (But I'm a professor! LOL!) uploaded his 
biodiesel how-to showing just that, Dark Ages stuff, him leaning over 
open processors and messing with methoxide with no gloves, no goggles 
and not even a useless breathing mask, just to show people how easy 
it really is, he said, and though he was using WVO he didn't say 
anything about titration because don't make it too complicated: 
KISS! Keep It Simple Stupid! But KISS is as KISS DOES (Don't 
Oversimplify Either, Stupid).

The next development or maybe the one after that was there's no need 
for titration with WVO, just use 6.25 grams, Mike Pelly says so. 
Indeed he does say so, but if you actually read it, what he says is 
that titration is the most important step, do it very carefully and 
then do it twice:

To determine the correct amount of lye required, a titration must be 
performed on the oil being transesterified. This is the most 
difficult step in the process, and the most critical -- make your 
titration as accurate as possible... It's a good idea to do this 
entire process more than once to ensure that your number is correct.
http://journeytoforever.org/biodiesel_mike.html
Biodiesel recipe from Mike Pelly: Journey to Forever

But a lot of people, even now, just use 6.25 grams. Maybe it'll even 
pass the wash-test if you bend the test too and use hot water or 
something, or more likely the wash-test gets sneered at as useless, 
it doesn't work - onward to super-gentle washing methods that will 
mask incomplete reactions loaded with emulsifiers and soap, and then 
it's stir-washing that doesn't work. And so on. There's a whole 
school of this iffy stuff. I've done dozens of trouble-free miles 
already!

But as you can see from the messages being posted here all the time, 
the wash-test isn't useless, titration is necessary, stir-washing 
does work, and diesels should do half a million trouble-free miles, 
not just dozens. Quality-control issues are important, with making 
biodiesel and with information, and also for the list, which has a 
distinct role and function and will achieve different goals otherwise.

Will people lose interest unless you lower the goalposts for them so 
they can score 100% first time? That's what advertising people and PR 
spin merchants and our lords and masters think, they even have us 

Re: [Biofuel] methoxide solution - missing scale

2005-10-18 Thread Paul S Cantrell
Dang, and all along I thought it was the Hokey Pokey...On 10/18/05, Keith Addison [EMAIL PROTECTED]
 wrote:  This just isn't what it's all about.What is it all about?
Couple of things beyond the immediately obvious. I think the mainpoint is the context. Depends how broad you want to make it, it canbe as broad as you like, then shrink it down to the immediate leveland see how much of it fits.
-- Thanks,PCHe's the kind of a guy who lights up a room just by flicking a switchHistory teaches us that men and nations behave wisely once they have exhausted all other alternatives. - Abba Eban
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Re: [Biofuel] methoxide solution - missing scale

2005-10-18 Thread Brian Rodgers
I knew I should have kept my mouth shut. Hehe
Sorry I am being silly again.
Keith you do have a great web site and now that you have explained the
layered information technique I will go back again and read it all
again. I actually knew there was a great depth to the JTF site because
every time I ask a question you quickly respond with a link to another
information pool I had overlooked. You are absolutely right, there is
a lot of info there and when combined with this email list it is all
coming together for me. I take full responsibility for my words and
more so for my actions. With this in mind, can I blame the skipping of
titration of the WVO, on my wife, the ex-science teacher?

 I try not to bother you all with excerpts from my daily newsletter.

I use my writing as a catch all to keep friends and family informed of
what  we are doing. Having not posted most of my daily chronicle you
of course don't get to see the summations of what I have learned here.
Somehow I guess I am saying that all you see are the questions I post
as I am knee deep in this.For instance in my newsletter I made note of
all of our short comings many of which you noted that day.

After rereading this morning's newsletter I don't believe there is
anything there that would shed any light on my thinking (or lack
thereof) on this topic. Thank goodness I didn't post my verbose
newsletter, right? Basically, I state that I have a lot of respect for
you and will listen and learn. I know that precision is better and I
need to get prepared for this weekend's chem-lab.project. I will look
in a pet store for the Phenolphthalein. I have graduated syringes and
pipettes. A triple beam scale is on the way. I looked at the Salvation
Army next store and they have a blender for $15.00.



On another thread called White lye I see that my lye may be
questionale too. I followed the link
http://journeytoforever.org/biodiesel_make2.html#lye . I was wondering
what the dark colored particles in my lye were. After reading your
description I beleive I have aluminum in there. So, I now have to find
a source for clean lye.

That's all I have time for Keith. I know this isn't much after your
wonderful letter. I guess I want you to know that I do have something
going on.
Thank you for your patience.
Your's truly,
Brian Rodgers

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Re: [Biofuel] methoxide solution - missing scale

2005-10-17 Thread Keith Addison
Hello Kurt, Brian

Wow, the Dark Ages are back! LOL!

Um. Look, I really don't want to put a damper on your enthusiasm so 
I'll try not to but I'm in wonderment at the way you're going about 
it. This just isn't what it's all about. I think you're missing the 
point. At least one, IMNSHO.

You've got it all going your way, great information resources, and a 
bunch of people here to discuss it with who've been doing it a long 
time. But!

There was a recent thread here or maybe two with a bunch of messages 
encouraging newbies having difficulty with the wash-test, saying how 
they'd also struggled but got there in the end and they're glad they 
persevered, they did it by removing the variables, checking their 
techniques, improving their practices. That's quite a strong contrast 
with this thread.

There are a lot of newbies here these days, by the way, much more 
than usual, hundreds of them just one or two steps behind you and 
watching how you're going about it, and what they're seeing from you 
now is how to get away with being sloppy. Here we are, at the Biofuel 
list, in the year Anno Domini 2005, after six years of this, being 
sloppy.

When you follow a planned step-by-step course into learning how to do 
something complex, in the early steps you'll probably be learning 
more than you're aware of, if the course is up to much. Since it's 
been developed in accordance with user-experience here it probably is 
up to much.

Why make small one-litre test batches anyway? So that you don't risk 
messing up right at the outset with a 150-litre first batch and end 
up facing a barrel of intractable and discouraging glop, right?

It's much more difficult to make one-litre test batches than 
150-litre batches. Kurt, do you think you're going to need the new 
0.1 gram scale to measure the lye for a 55-gal reactor batch? Sure 
you'll use it, but you won't need those tolerances. With a one-litre 
batch it gives you a margin of error of 2.9%, kind of wide, but with 
the bigger batch it would be accurate to within 0.01%, ridiculously 
narrow, no need. The smaller the batch, the bigger the error, the 
more accurate your measurements have to be.

A good reason to learn precise techniques doing small test batches, 
starting simple and adding one variable at a time, with quality 
checks not only of the fuel you make but of your procedures too, is 
that no matter how experienced you get, you never quite know what 
fiendishly cunning little challenges the next batch of WVO might be 
holding in store for you. The quality checks and test-batches aren't 
just for newbies, you do it with every batch. Many case-hardened 
biodiesel brewers do Poor man's titration bracket tests and quality 
checks with every batch, they've said so on the list. The more 
accurate and precise your measurements are the more your tests will 
tell you, and the less grief will fill your days.

You have to get a 'feel' for it, they say. Like when you tie your 
shoelaces, you just do it, you don't even have to look, your fingers 
do it for you, it's easy. Actually it's a complicated series of 
operations, tying your shoelaces, it wouldn't be so easy to program a 
computer to do it. I don't think you get a good feel for it by trying 
to take it by storm, deciding it's not going to kick *your* butt, so 
you hurl volleys of random test batches at it and hit a wall of 
emulsion. So in the end you buy accurate scales after all, like 
everyone was telling you. But now you're advising Brian how not to 
need one.

Now you've got the scales, but you also have the idea lodged in your 
head that you can measure half a gram of lye by volume in a beaker 
because you tried it and it worked. If you go teaching your fingers 
stuff like that you're going to find yourself tripping over your 
shoelaces a lot.

You already are. You abandoned one-litre batches in favour of 300 ml 
batches in the hopes of getting less moisture in the lye because you 
think smaller measurements will take less time (76% humidity isn't so 
much, it's higher than that here now). So you set yourself the task 
of measuring even smaller quantities without an accurate scale. For a 
300ml batch, 3.5g/litre of lye works out to 1.05 grams, and the 
volume would be 0.495 ml. You're measuring 0.495 ml of lye in a 
beaker? And it gave you some of your best results. But I think with 
these methods your best results are just as randomly chaotic as the 
worst ones. But you get it right by bending the wash-test your way. 
And then advise another newbie to do the same.

Brian, meanwhile, is starting in the wrong place and forgot he needs 
to weigh something or other, and forgot he needed a blender to mix it 
in too. Sheesh, Brain, how can you be so scatter-brained? Don't you 
even make notes? You're not just boiling an egg you know.

Why aren't you starting with virgin oil? But you want to start with 
WVO, why waste time, and you're going to titrate it. Only you don't 
have scales and you're going to use old 

Re: [Biofuel] methoxide solution - missing scale

2005-10-17 Thread Brian Rodgers
Hello Keith
Thank you for the thoughtful and considerate review of my weekend's
fun in setting up our first mixer and solution of methoxide.
 Wow, the Dark Ages are back! LOL!
How true, for me I don't know about Kurt.
 Um. Look, I really don't want to put a damper on your enthusiasm so
 I'll try not to but I'm in wonderment at the way you're going about
 it.
Not to worry I can't be dis-enthused this easy.
This just isn't what it's all about.
What is it all about?
I think you're missing the
 point. At least one, IMNSHO.

 You've got it all going your way, great information resources, and a
 bunch of people here to discuss it with who've been doing it a long
 time.
I agree.
 There was a recent thread here or maybe two with a bunch of messages
 encouraging newbies having difficulty with the wash-test, saying how
 they'd also struggled but got there in the end and they're glad they
 persevered, they did it by removing the variables, checking their
 techniques, improving their practices. That's quite a strong contrast
 with this thread.
Again, I can't speak for Kurt, my wife and I did what we could with
what we had on hand, short of driving another thirty miles to get what
we needed to do it right.
 There are a lot of newbies here these days, by the way, much more
 than usual, hundreds of them just one or two steps behind you and
 watching how you're going about it, and what they're seeing from you
 now is how to get away with being sloppy. Here we are, at the Biofuel
 list, in the year Anno Domini 2005, after six years of this, being
 sloppy.
Yes, I see your point. I have found that I need to keep my mouth
closed with the world view
topics on this list because I feel others know better than I. It
hadn't occurred to me that in this biodiesel process newbie thread
others would be reading of my inexperience and thinking that if this
knucklehead can do it then I should try doing this process sloppy as
well.
 When you follow a planned step-by-step course into learning how to do
 something complex, in the early steps you'll probably be learning
 more than you're aware of, if the course is up to much. Since it's
 been developed in accordance with user-experience here it probably is
 up to much.
Not sure what you are getting at with the last sentence.
 Why make small one-litre test batches anyway? So that you don't risk
 messing up right at the outset with a 150-litre first batch and end
 up facing a barrel of intractable and discouraging glop, right?
I still feel better having made a sloppy and possibly useless two
liter batch this weekend.
 It's much more difficult to make one-litre test batches than
 150-litre batches.
The only reason I did the two liter trial run is I needed to see first
hand what I was going to need, or more accurately what I could
scavenge and use and still get results.
 Kurt, do you think you're going to need the new
 0.1 gram scale to measure the lye for a 55-gal reactor batch? Sure
 you'll use it, but you won't need those tolerances. With a one-litre
 batch it gives you a margin of error of 2.9%, kind of wide, but with
 the bigger batch it would be accurate to within 0.01%, ridiculously
 narrow, no need. The smaller the batch, the bigger the error, the
 more accurate your measurements have to be.

 A good reason to learn precise techniques doing small test batches,
 starting simple and adding one variable at a time, with quality
 checks not only of the fuel you make but of your procedures too, is
 that no matter how experienced you get, you never quite know what
 fiendishly cunning little challenges the next batch of WVO might be
 holding in store for you. The quality checks and test-batches aren't
 just for newbies, you do it with every batch. Many case-hardened
 biodiesel brewers do Poor man's titration bracket tests and quality
 checks with every batch, they've said so on the list. The more
 accurate and precise your measurements are the more your tests will
 tell you, and the less grief will fill your days.

 You have to get a 'feel' for it, they say. Like when you tie your
 shoelaces, you just do it, you don't even have to look, your fingers
 do it for you, it's easy. Actually it's a complicated series of
 operations, tying your shoelaces, it wouldn't be so easy to program a
 computer to do it. I don't think you get a good feel for it by trying
 to take it by storm, deciding it's not going to kick *your* butt, so
 you hurl volleys of random test batches at it and hit a wall of
 emulsion. So in the end you buy accurate scales after all, like
 everyone was telling you. But now you're advising Brian how not to
 need one.

 Now you've got the scales, but you also have the idea lodged in your
 head that you can measure half a gram of lye by volume in a beaker
 because you tried it and it worked. If you go teaching your fingers
 stuff like that you're going to find yourself tripping over your
 shoelaces a lot.

 You already are. You abandoned one-litre batches in favour of 300 ml
 batches in 

Re: [Biofuel] methoxide solution - missing scale

2005-10-15 Thread Kurt Nolte
Hey Brian

I've run into problems with measuring lye myself, and ultimately
managed to work out a loose but somewhat workable way to measure out
the lye by volume. It produced some of my best results to date, too, so
I think I'm safe to share it with yas. 

Sodium Hydroxide has a density of 2.1 grams per cubic centimeter. Since
a cubic centimeter = a milliliter, you can use your beaker with mL
scale on it to measure out the lye volumetrically. For a test batch
with virgin oil it's going to be some incredibly small number; under
2ml, I believe. I was only doing a 300mL test batch, so I needed under
a milliliter of NaOH. 

Using the density of NaOH, convert your titrated grams into
milliliters, then measure them out volumetrically and add to your
methanol as per normal. I'd suggest erring on the side of caution when
measuring it out though; unless your beaker is graduated in .01mL
increments it might be hard to get a truly accurate volume. 

I decided when I tried it to err on the low side, as an incomplete
reaction I've read can be reprocessed but too much lye is worse news on
the washing step. 

In the end though, all these guys on the list are right; there's no
substitute for a good, accurate gram scale. Just picked on up myself,
in fact, measures out to .1 grams with a 500g capacity. 

Good luck to ya!

-K
On 10/15/05, Brian Rodgers [EMAIL PROTECTED] wrote:
Hi biodieselersI am here with my wife in our kitchen working on our first titration of WVO.We have determined through heating a sample of WVO that no water ispresent. We have found a soil test kit that has several types of
litmus paper. We did several tests of the litmus to determine if itwas still fairly accurate by testing a light solution of lye water,household water, distilled water and finally battery acid. We havecompared the litmus paper color change and are satisfied that we can
tell the difference in major pH scales. By the way, thisexperimentation is too much fun.We have several browser windows open to the archives and conversiontables for reference. It seems the first thing I forgot to collect for
this first test is a gram scale. We live 15 miles from town and ahopeful there is a way to measure the lye without making a specialtrip. Or, are we done for the day?We have a decent thermometer, 1 beaker with ml scale, two syringes
with cc scales, goggles, gloves and lots of excitement.Our question is this: Can we do this first step without the scale?What else are we forgetting if a trip to town is needed?Thanks for your help.
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Re: [Biofuel] methoxide solution - missing scale

2005-10-15 Thread Brian Rodgers
Great thanks Kurt
This is what we were looking for. We even attempted to find the
specific gravity of lye, but that didn't pan out. It was getting too
complicated for us. A trip to town would be simpler we figured.
On 10/15/05, Kurt Nolte [EMAIL PROTECTED] wrote:
 Hey Brian
  I've run into problems with measuring lye myself, and ultimately managed to
 work out a loose but somewhat workable way to measure out the lye by volume.
 It produced some of my best results to date, too, so I think I'm safe to
 share it with yas.

  Sodium Hydroxide has a density of 2.1 grams per cubic centimeter. Since a
 cubic centimeter = a milliliter, you can use your beaker with mL scale on it
 to measure out the lye volumetrically. For a test batch with virgin oil it's
 going to be some incredibly small number; under 2ml, I believe. I was only
 doing a 300mL test batch, so I needed under a milliliter of NaOH.

  Using the density of NaOH, convert your titrated grams into milliliters,
 then measure them out volumetrically and add to your methanol as per normal.
 I'd suggest erring on the side of caution when measuring it out though;
 unless your beaker is graduated in .01mL increments it might be hard to get
 a truly accurate volume.

  I decided when I tried it to err on the low side, as an incomplete reaction
 I've read can be reprocessed but too much lye is worse news on the washing
 step.
We will try this.
  In the end though, all these guys on the list are right; there's no
 substitute for a good, accurate gram scale.
I agree but you know how it is with the first step in a new process,
we want to see where it goes even if it does not work at all.
Experimenting in New Mexico,
Brian Rodgers

Just picked on up myself, in
 fact, measures out to .1 grams with a 500g capacity.

  Good luck to ya!

  -K

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Re: [Biofuel] methoxide solution - missing scale

2005-10-15 Thread Kurt Nolte
Not a problem, I encourage sharing experiences and tricks.

Like I said, I had some of my best results to date on test batches
using this method, a nice good clear yellow color top layer and a
smooth separation, and it's so far washed very nicely. At least you
don't also have to contend with 76% humidity, eh? ^.~

Good luck to ya man. Let me know how it works for you, I may ultimately
refine the process with an eye toward really low cost production. Or
automation; easier to stop at a volume than a weight, I think. 

-K
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Re: [Biofuel] methoxide solution - missing scale

2005-10-15 Thread Brian Rodgers
Yeah I too am getting into this sharing of information, although I
don't know squat worth sharing yet.

On 10/15/05, Kurt Nolte [EMAIL PROTECTED] wrote:
 Not a problem, I encourage sharing experiences and tricks.

  Like I said, I had some of my best results to date on test batches using
 this method, a nice good clear yellow color top layer and a smooth
 separation, and it's so far washed very nicely. At least you don't also have
 to contend with 76% humidity, eh? ^.~
Funny you should mention this... In the last half hour it began
pouring rain. I ran outside to get the firewood covered and now I am
soaked. Meanwhile my wife got a roaring fire going in our heavily
modified wood heater. It is now warming and drying us.

I do recall that that ambient humidity messes with the methoxide
mixing. Should I wait until the rain quits to continue with the
experiment?
Brian Rodgers

  Good luck to ya man. Let me know how it works for you, I may ultimately
 refine the process with an eye toward really low cost production. Or
 automation; easier to stop at a volume than a weight, I think.

  -K



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Re: [Biofuel] methoxide solution - missing scale

2005-10-15 Thread Kurt Nolte
On 10/15/05, Brian Rodgers [EMAIL PROTECTED] wrote:
I do recall that that ambient humidity messes with the methoxidemixing. Should I wait until the rain quits to continue with the
experiment?
Lye is hygroscopic; it absorbs water quite readily. 

Yeah, I'd suggest waiting for it to quit raining, as ambient humidity
increases will throw off your measurement of lye on both a mass and
volumetric basis because of absorption into the pellets or grains. 

Now if the humidity in your house is still low, you could always
quickly measure it out and put it in a sealed container with your
methanol, then hustle outside to mix it; I use Mason jars to mix my
methoxide in for test batches. 

-K
 
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Re: [Biofuel] methoxide solution - missing scale

2005-10-15 Thread Brian Rodgers
Ok very cool I just might try it now and close everything up tight
while working.
Brian Rodgers


On 10/15/05, Kurt Nolte [EMAIL PROTECTED] wrote:


 On 10/15/05, Brian Rodgers [EMAIL PROTECTED] wrote:

  I do recall that that ambient humidity messes with the methoxide
  mixing. Should I wait until the rain quits to continue with the
  experiment?

  Lye is hygroscopic; it absorbs water quite readily.

  Yeah, I'd suggest waiting for it to quit raining, as ambient humidity
 increases will throw off your measurement of lye on both a mass and
 volumetric basis because of absorption into the pellets or grains.

  Now if the humidity in your house is still low, you could always quickly
 measure it out and put it in a sealed container with your methanol, then
 hustle outside to mix it; I use Mason jars to mix my methoxide in for test
 batches.

  -K

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Re: [Biofuel] methoxide solution - missing scale

2005-10-15 Thread Kurt Nolte
On 10/15/05, Brian Rodgers [EMAIL PROTECTED] wrote:
Ok very cool I just might try it now and close everything up tightwhile working.Brian Rodgers

Best of luck to ya, once more. And now I need to get back to work before they decided I'm not earning my pay. ;p

-Kurt
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Re: [Biofuel] methoxide solution - missing scale

2005-10-15 Thread Brian Rodgers
The rain has stopped and the skies are clearing

Tomorrow is another day.
Thanks for all your help.
Brian Rodgers

On 10/15/05, Kurt Nolte [EMAIL PROTECTED] wrote:
 On 10/15/05, Brian Rodgers [EMAIL PROTECTED] wrote:
  Ok very cool I just might try it now and close everything up tight
  while working.
  Brian Rodgers
 

  Best of luck to ya, once more. And now I need to get back to work before
 they decided I'm not earning my pay. ;p

  -Kurt

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