The critical information comes from the Java console:

urlImage=jar:
http://www.saintmarys.edu/~pbays/Jmol/JmolApplet.jar!/jmol75x29x8.gif

[this tells us where the Jar file is located]

FileManager.getAtomSetCollectionFromFile(Acyclic/M5/R.pdb)
FileManager opening
http://www.saintmarys.edu/~pbays/Programs/Stereochemistry/Acyclic/M5/R.pdb

[this tells us where the file is located .. no problem with this load.]



So what are those two values on the Mac?
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