"James Osbourne, Holmes" wrote:

> I think it is a bit more complex:  some are absorbed;

Right.

> some are reflected;

Right.

>
> some are refracted and the angles of reflection vary with wavelength;

True, this is lumped together with reflected as scattering, and is ultimately
what is termed Tyndall effect.

> some
> are absorbed and re-emitted at a different wavelength.

I am not aware of any being absorbed and re-emitted, except for the energy from
the light creates heat and the silver will have the black body radiation
associated with the temperature. Normally absorbed and re-emitted is considered
fluorescence, and I don't think silver behaves this way.  Do you have any cites
or references on this?

> All of this changes
> with particle size and concentration of particles.

It changes with particle size, as I have quoted previously, the Tyndall
increases to the third power with the size.  The increase in Tyndall and
absorption are both linear with concentration (provided the concentration does
not reach a point where aggregation occurs)..

> Some devices take
> advantage of this behavior to determine particle size based on the changes
> between the light in and light out.

Yes, I have used this myself.  Using the Hack scanning spectrophotometer, I scan
a specimen and can get a crude idea of the particle size distribution from the
absorption spectrum from infrared to uv.  If I could obtain some samples with
defined and narrow particle size ranges to calibrate from, I  think I could do a
very good job of using this technique to profile particle size of CS samples,
but have not been able to source any such standards.

Marshall


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