At 12:08 AM 4/10/2012, Eric Walker wrote:
On Mon, Apr 9, 2012 at 9:48 AM, Abd ul-Rahman Lomax <<mailto:[email protected]>[email protected]> wrote:
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W-L theory allows for a farrago of proposed reactions, so one can pick and choose for a large and complex field, to find a reaction that might explain a particular result. And that the required reaction series might be way-silly-improbable is ignored. Essentially, there will be, if W-L theory of neutron formation is correct, there will be N neutrons being formed. It is proposed that these have a very high absorption rate, so N transmutations will be caused. But this is N/T, where T is the total number of possible targets. (Roughly.) A transmuted element becomes just another target, and would presumably be exposed to the same neutron flux. The probability of a second reaction in the "cycle" would be the square of N/T.  That would be, for all intents and purposes, close to zero.


Can you further explain this calculation? Â Are you assuming a low flux, where N/T << 1? Â You're also thinking that T is large and includes the Palladium atoms in the lattice?

Yes, N/T << 1. If not so, then we'd be seeing far stronger evidence of reactions: transmutation products, heat, and (if not for the magic "heavy electron patches") radiation.

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The intermediate product would be left. Â If neutrons are being created in significant numbers, we would expect to see specific results that are not observed, and gammas are only one aspect of this.


I think you mentioned a great deal of heat as being another missing observable in addition to gamma radiation. Â Just to make sure I understand your position -- you're relying on branching ratios and reactions that are known from previous experience with fusion?

No, not at all. Where did you get that idea? Heat is not missing, except when we look at what would be required to generate the observed levels of helium following the W-L pathways. The third missing observable is the levels of transmuted elements that would be present as intermediate products, or as end products if the helium is produced by alpha emission.

(Which then leaves another problem, hot alphas, which would create other observable effects.)

 I have no reason to doubt this approach, I'm just trying to understand.  What are the other missing observables in addition to heat and gamma rays?
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Looking through some of the other slides, what Larsen is doing is searching through experimental records, finding anomalies that W-L theory *might* explain. There is an absence of quantitative analysis.


I think Jed had a nice thread about the merits of qualitative analysis not too long ago, but point taken.

It's crucial. I know of only one *partial* theory that actually makes quantitative predictions, beyond Preparata's expectation of helium, and it's not ready for publication.

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There is an absence of clear experimental prediction.


A good indicator of wishy-washy thinking.
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This is pure ad-hoc speculation, and all it can do, scientifically, is to suggest avenues for exploration.


Arriving at new avenues for exploration doesn't seem all that bad a result, but we should strive for better.

The problem is that it hasn't really been developed to the point where specific experiment is being suggested.


Just to make sure I understand your position -- you don't like neutron flux because you don't find sufficient evidence for it and you find strong evidence against it.

I don't find *any* evidence for it. W-L theory is a speculation. The basis of the speculation is this: if there is an unknown nuclear reaction, what is it? So people make things up. Most of these made-up theories are not considered plausible. However, we cannot rule any of them out completely, except where they make clear predictions.

Speculation that surface conditions on metal hydrides might create a previously-unobserved effect, making neutrons, fine. But then what do neutrons do in that enviroment? Neutron behavior is well-known and predictable. And what we'd expect these neutrons to do just doesn't happen. The missing gammas are a big part of it. To explain them, a *new* previously unobserved effect is required: gamma suppression, and not just a partial shielding, complete shielding. Beyond that, where are the copious transmutation products (other than helium) required to explain the observed heat? And if helium is being produced by the "cycle" that W-L proposes, where are all the required intermediate products?

This is what I understand: W-L theory proposes that neutrons are formed within a "patch." The neutrons have a short path, because of their very low momentum. They all are absorbed. The elemental composition of the patch, as to the most common elements, can be known. The patch cannot be very small, or gammas would escape from neutrons travelling to the edge or beyond. Given a composition, the transmutation products should be predictable, and then the heat generation per the total mix, with, then, each element of the mix having a specific Q with respect to overall heat.

My understanding of the experimental history is that no transmutation products correlate well with heat except for helium, and helium must account for at least half of the heat, if not all of it. (I may be understating the case!)

There is no experimental evidence, certainly no confirmed experimental evidence, that points to W-L theory.

 For there to be sufficient flux to have a "carbon cycle" and so on would entail effects that aren't seen experimentally, such as high levels of heat.  You don't see a strict requirement for a D+D -> He reaction, but you see compelling reason not to give serious consideration to alpha decay.

No. In fact, a prototheory which I consider is quite possibly related to what is actually happening does, like W-L theory, posit helium generation from Be-8, which decays to two alphas, i.e., two helium nuclei. The difference is that the Be-8 is formed through a predicted (using known quantum field theory) from the Bose-Einstein condensation of two deuterium molecules, i.e, four deuterium atoms (with their electrons). The theory is incomplete because we don't know that the precursor condition, used in the calculation, a tetrahedral symmetric arrangement of the four atoms (which represents a close approach, due to interatomic repulsive forces which would, in a free liquid or gas phase, dissociate the molecules), would actually form with enough frequency, nor do we understand how the resulting energy would be released. Some specific speculative predictions have been made, of photon emissions at certain specific frequencies, representing Be-8 nuclear transitions, but ... these would be extremely difficult to observe.

In any case, that is "alpha decay." For a long time I considered that "d-d fusion" could be almost completely ruled out, for lots of obvious reasons. Multibody fusion remained on the table. However, I'm now seeing a level of unpublished evidence that the reaction might indeed be the fusion of two deuterons, and this is going to require much futher investigation. That would still leave a huge mystery. We'll see.

Bottom line, we do not seem to have sufficent experimental evidence to develop a strong theory of cold fusion. We know these things:

1. Levels of heat are developed such that expert chemists say, this is not chemistry. 2. Helium is being produced at levels "commensurate with" the heat, such that it appears that some kind of deuterium fusion is involved. That is, the fuel is deuterium (in the FPHE), and the ash is helium. Mostly. There are other reactions, but all at levels far below those implied by the helium found. When the helium evidence is considered in conjunction with the heat evidence, a nuclear origin of the heat becomes the default hypothesis. 3. There is little radiation of any observable kind. (There are enough reports of tritium, X-rays, and various transmutation products that these likely exist, but they are not clearly correlated with the heat and are likely rare branches or consequential reactions. The Hagelstein limit of 20 KeV for charged particle emission from the reactions applies to the bulk, not to rare effects.)

There is more that is "known." I put "known" in parentheses because some evidence may be misleading, may be due to particular conditions in the experiments on which it was based.

Regarding transmutations, such as that of Barium into Samarium reported in Iwamura et al. [1], you either find evidence for them to be unreliable and ultimately untenable, or, alternatively, something that arises by a process other than neutron flux.

Have I misunderstood anything?

I think so. I'm going to point out that the Iwamura reports are not of the Fleischmann-Pons Heat Effect, per se. We might assume that nuclear transmutations in an Iwamura experiment are due to the same reaction, but that's absolutely not clear. There may be more than one LENR.

Transmutations are known from FPHE experiments. Some transmutation reports may be unreliable, but helium is a transmuted element, and so is tritium. Tritium reports are sufficiently well established to consider them reliable, but tritium levels are not clearly associated, quantitiatively, with excess heat.

There are some problems associated with the identification of transmutation products, and until there is adequate confirmation of results like those of Iwamura, it's dangerous to base much on them. Iwamura's results are certainly interesting and worthy of replication, and there have been replication attempts, some of which appear to have failed (or, in a recent case, just published in the CMNS journal, there was an apparent transmutation product that was identified as being, instead, a molecular ion with similar weight). It's a complicated story that I'm not going to research and write about here.

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