On Nov 27, 3:11 am, "Raymond W. Arritt"
<[EMAIL PROTECTED]> wrote:
> Alastair wrote:
> > I (and Newton) say that warming is caused by absorption.  After WWII
> > they found that the lines were narrower at high altitude, but the
> > radiation has all been absorbed well before it reaches that height.
> > In fact it is nearly all absorbed in the first 30m.  John Tyndall
> > reckoned that 10% was absorbed in the within the first 6 feet.
>
> What happens to the energy that corresponds to the absorbed radiation?
> Since energy cannot be created or destroyed (leaving relativistic
> effects aside here), do the lowest few tens of meters continue to heat
> indefinitely?

The simple answer is yes. You can see this most obviously on Venus
where the surface heated up until it melted. What happened then was
that clouds formed and cut off the initiating solar radiation.  On
Earth the most of the surface is already molten, and the average cloud
cover has makes the incoming solar radiation match the outgoing
longwave radiation. On Mars conditions are different and dust storm
form long before the surface melts.  These intermittent dust storms
provide the cooling to Mars that on Earth happens due to "permanent"
by water clouds.

Of course everyone thinks that it is the thick CO2 atmosphere that
gives Venus its runaway greenhouse, but the with the standard model
the maximum surface temperature is twice the effective temperature.
For Venus that is widely exceeded. This is a known problem; see Goody
and Walker's Atmospheres 1972.

On Earth, this would solve the Faint Young Sun problem. See this link
for a description of it.
http://arjournals.annualreviews.org/doi/abs/10.1146/annurev.aa.32.090194.000503
Of course convection is also acting, and that is claimed to save the
model, there is very little convection on Venus or Mars.

> > There are two things happening.  There is the greenhouse warming at
> > the surface of the atmosphere, and there is OLR at the top of the
> > atmosphere. The OLR has to balance the ISR but it cannot change
> > because it is coming from the mesosphere which does not respond to the
> > surface temperature. (I am leaving a lot out, but you should be able
> > to see the picture.)
>
> Where does the OLR come from, if (as you state) all the outgoing
> radiation from the surface is absorbed in the lowest few tens of meters?

A good point!  My previous description was an over simplification.
Greenhouse gases both absorb and emit.  Both are quantum mechanical
effects and so are not simple but I will try to explain without
writing a text book. So I will ignore water vapour which complicates
things by condensing.

In the middle atmosphere all the CO2 molecules are at the same
temperature so on average they are all radiating with the same
strength. And thus you have a situation where Kirchoff's Law is obeyed
and absorption equals emission.  At the TOA there are no molecules in
space radiating in so there is a net loss of radiation out to space
and this is where OLR is generated. (Of course you knew that already.)

At the base of the atmosphere, the surface radiates blackbody
radiation, and the intensity in the CO2 bands depends on the surface
temperature through Planck's blackbody function B(T).  Einstein showed
that the greenhouse gas will also emit radiation according to B(T) so
it would seem that once the air equals the surface temperature then
all absorption will cease.  So de Saussure's hot box should not work.
http://www.solarcooking.org/saussure.htm

But the T for the CO2 vibrational emission is the vibrational
temperature not the kinetic temperature. Tvib is much lower than T for
CO2 because its vibrations are "frozen out". So it is all of the net
radiation which is absorbed in the first 30 m, not all of the all
outgoing radiation :-)

HTH,

Cheers, Alastair.

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